{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T13:59:03Z","timestamp":1791295143690,"version":"4.1.0"},"reference-count":39,"publisher":"American Chemical Society (ACS)","issue":"39","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"publisher","award":["2024N0059"],"award-info":[{"award-number":["2024N0059"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22494633"],"award-info":[{"award-number":["22494633"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22571304"],"award-info":[{"award-number":["22571304"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52522008"],"award-info":[{"award-number":["52522008"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005090","name":"Beijing Nova Program","doi-asserted-by":"publisher","award":["2024072"],"award-info":[{"award-number":["2024072"]}],"id":[{"id":"10.13039\/501100005090","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005090","name":"Beijing Nova Program","doi-asserted-by":"publisher","award":["20250484956"],"award-info":[{"award-number":["20250484956"]}],"id":[{"id":"10.13039\/501100005090","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The simultaneous capture of carbon dioxide (CO2) and carbon monoxide (CO) from complex industrial gases represents a critical challenge. Designing framework sorbents that combine selective molecular recognition with stability is essential. Herein, a series of anthracene-based metal\u2013organic frameworks (MOFs), M-ABHBs (M = Co, Mg, Mn, and Ni), were successfully synthesized. By regulating metal centers, which leads to different interactions between gases (CO2\/CO\/N2) and metal\u2013ligand pairs in the framework, excellent CO adsorption selectivity has been discovered. Notably, Mg\/Mn-ABHBs allow efficient binary CO2\/N2 separation, and Co\/Ni-ABHBs enable benchmark ternary CO2\/CO\/N2 separation by increasing the adsorption affinity toward CO. This unique phenomenon is rare among adsorbents. Such behaviors enable a stepwise separation strategy to selectively capture CO2 and CO from ternary mixtures. Co-ABHB exhibits high selectivity of CO\/N2 (13.1), while Mg-ABHB shows high selectivity of CO2\/N2 (66.6) and CO2\/CO (5.8). In situ DRIFTS and theoretical calculations indicate that the former is the result of the strong interactions of Co-CO in the cavities of Co-ABHB, while Mg sites strongly capture only CO2, not CO. Breakthrough tests show that from a CO2\/CO\/N2 mixture, M-ABHBs demonstrated excellent separation performance. This work offers a design strategy for efficient carbon capture under complex industrial gas conditions.<\/jats:p>","DOI":"10.1021\/acs.est.6c08945","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T15:07:06Z","timestamp":1790089626000},"page":"27696-27704","source":"Crossref","is-referenced-by-count":0,"title":["Metal\u2013Organic\nFrameworks with Tunable Metal\nNode for Selective Capture and Separation of CO2 and CO\nfrom Ternary Blast Furnace Gas Mixtures"],"prefix":"10.1021","volume":"60","author":[{"given":"Na","family":"Geng","sequence":"first","affiliation":[{"name":"Institute of Process Engineering, Chinese Academy of Sciences , , ,","place":["Beijing, P. R. China, 100190"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, P. R. China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6040-6219","authenticated-orcid":true,"given":"Jia-Jia","family":"Zheng","sequence":"additional","affiliation":[{"name":"National Center for Nanoscience and Technology, Chinese Academy of Sciences , , ,","place":["Beijing, P. R. China, 100190"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyu","family":"Zhang","sequence":"additional","affiliation":[{"name":"Tongji University , , ,","place":["Shanghai, P. R. China, 200092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7904-5003","authenticated-orcid":true,"given":"Ken-ichi","family":"Otake","sequence":"additional","affiliation":[{"name":"Kyoto University , , Yoshida Ushinomiya-cho, Sakyo-ku, ,","place":["Kyoto, Japan, 6068501"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6956-9543","authenticated-orcid":true,"given":"Susumu","family":"Kitagawa","sequence":"additional","affiliation":[{"name":"Kyoto University , , Yoshida Ushinomiya-cho, Sakyo-ku, ,","place":["Kyoto, Japan, 6068501"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7648-306X","authenticated-orcid":true,"given":"Yifan","family":"Gu","sequence":"additional","affiliation":[{"name":"Tongji University , , ,","place":["Shanghai, P. R. China, 200092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongjian","family":"Huang","sequence":"additional","affiliation":[{"name":"HBIS Group Co., Ltd. , ,","place":["Hebei, P. R. China, 050023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming-Shui","family":"Yao","sequence":"additional","affiliation":[{"name":"Institute of Process Engineering, Chinese Academy of Sciences , , ,","place":["Beijing, P. R. China, 100190"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, P. R. China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8584-6210","authenticated-orcid":true,"given":"Yangyang","family":"Guo","sequence":"additional","affiliation":[{"name":"Institute of Process Engineering, Chinese Academy of Sciences , , ,","place":["Beijing, P. R. China, 100190"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, P. R. China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-8230-0337","authenticated-orcid":true,"given":"Tingyu","family":"Zhu","sequence":"additional","affiliation":[{"name":"Institute of Process Engineering, Chinese Academy of Sciences , , ,","place":["Beijing, P. R. China, 100190"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, P. R. 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Mater."}],"container-title":["Environmental Science &amp;\nTechnology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.est.6c08945","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/esthag\/article-pdf\/60\/39\/27696\/68601962\/acs.est.6c08945.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/esthag\/article-pdf\/60\/39\/27696\/68601962\/acs.est.6c08945.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T13:30:03Z","timestamp":1791293403000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/esthag\/article\/60\/39\/27696\/5435457\/Metal-Organic-Frameworks-with-Tunable-Metal-Node"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,22]]},"references-count":39,"journal-issue":{"issue":"39","published-online":{"date-parts":[[2026,9,22]]},"published-print":{"date-parts":[[2026,10,6]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.est.6c08945","relation":{},"ISSN":["0013-936X","1520-5851"],"issn-type":[{"value":"0013-936X","type":"print"},{"value":"1520-5851","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,22]]}}}