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Here we show that phenol can be efficiently oxidized in oxic FeS suspension at circumneutral pH value. We found that hydroxyl radicals (\u2022OH) were the predominant reactive oxidant and that a higher O2 content accelerated phenol degradation. Phenol oxidation depended on \u2022OH production and utilization efficiency, i.e., phenol degraded per \u2022OH produced. Low FeS contents (\u22641 g\/L) produced less \u2022OH but higher utilization efficiency, while high contents produced more \u2022OH but lower utilization efficiency. Consequently, the most favorable conditions for phenol oxidation occurred during the long-term interaction between dissolved O2 and low levels of FeS (i.e., \u22641 g\/L). Mo\u0308ssbauer spectroscopy suggests that FeS oxidation to lepidocrocite initially produced an intermediate Fe\u00ad(II) phase that could be explained by the apparent preferential oxidation of structural S\u00ad(\u2212II) relative to Fe\u00ad(II), rendering a higher initial \u2022OH yield upon unit of Fe\u00ad(II) oxidation. Trichloroethylene can be also oxidized under similar conditions. Our results demonstrate that oxidative degradation of organic contaminants during the oxygenation of FeS can be a significant but currently underestimated pathway in both natural and engineered systems.<\/jats:p>","DOI":"10.1021\/acs.est.9b07012","type":"journal-article","created":{"date-parts":[[2020,3,6]],"date-time":"2020-03-06T17:24:58Z","timestamp":1583515498000},"page":"4091-4101","source":"Crossref","is-referenced-by-count":152,"title":["Oxidative\nDegradation of Organic Contaminants by FeS\nin the Presence of O2"],"prefix":"10.1021","volume":"54","author":[{"given":"Dong","family":"Cheng","sequence":"first","affiliation":[{"name":"China University of Geosciences , , No. 68 Jincheng Street, East Lake High-Tech Development Zone , , ,","place":["Wuhan, Hubei, PR\nChina, 430078"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0472-9056","authenticated-orcid":true,"given":"Anke","family":"Neumann","sequence":"additional","affiliation":[{"name":"Newcastle University , , ,","place":["Newcastle upon Tyne, United Kingdom, NE1\n7RU"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6119-1646","authenticated-orcid":true,"given":"Songhu","family":"Yuan","sequence":"additional","affiliation":[{"name":"China University of Geosciences , , No. 68 Jincheng Street, East Lake High-Tech Development Zone , , ,","place":["Wuhan, Hubei, PR\nChina, 430078"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7256-177X","authenticated-orcid":true,"given":"Wenjuan","family":"Liao","sequence":"additional","affiliation":[{"name":"China University of Geosciences , , No. 68 Jincheng Street, East Lake High-Tech Development Zone , , ,","place":["Wuhan, Hubei, PR\nChina, 430078"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ao","family":"Qian","sequence":"additional","affiliation":[{"name":"China University of Geosciences , , No. 68 Jincheng Street, East Lake High-Tech Development Zone , , ,","place":["Wuhan, Hubei, PR\nChina, 430078"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,3,6]]},"reference":[{"key":"2026081715272940100_cit1","doi-asserted-by":"publisher","first-page":"514","DOI":"10.1021\/cr0503658","article-title":"Chemistry of iron\nsulfides","volume":"107","author":"Rickard","year":"2007","journal-title":"Chem.\nRev."},{"key":"2026081715272940100_cit2","doi-asserted-by":"publisher","first-page":"141","DOI":"10.1016\/j.marchem.2005.08.004","article-title":"Acid volatile sulfide\n(AVS)","volume":"97","author":"Rickard","year":"2005","journal-title":"Mar. 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