{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T08:30:49Z","timestamp":1787041849559,"version":"build-2736575974"},"reference-count":51,"publisher":"American Chemical Society (ACS)","issue":"23","license":[{"start":{"date-parts":[[2020,9,24]],"date-time":"2020-09-24T00:00:00Z","timestamp":1600905600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2020,9,24]],"date-time":"2020-09-24T00:00:00Z","timestamp":1600905600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2020,9,24]],"date-time":"2020-09-24T00:00:00Z","timestamp":1600905600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100006151","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE-SC0008885"],"award-info":[{"award-number":["DE-SC0008885"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004826","name":"Natural Science Foundation of Beijing Municipality","doi-asserted-by":"publisher","award":["3202034"],"award-info":[{"award-number":["3202034"]}],"id":[{"id":"10.13039\/501100004826","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004739","name":"Youth Innovation Promotion Association of the Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["2016128"],"award-info":[{"award-number":["2016128"]}],"id":[{"id":"10.13039\/501100004739","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51721005"],"award-info":[{"award-number":["51721005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U1832131"],"award-info":[{"award-number":["U1832131"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2020,12,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The substitution of chemically similar elements in a given crystal structure is an effective way to enhance physical properties, but the understanding on such improvements is usually impeded because the substitutions are random, and the roles of the different atoms cannot be distinguished by crystallographic symmetry. Herein, we provide a detailed crystallographic analysis and property measurements for the continuous solid solutions LuGexSn2\u2013x (0 &amp;lt; x &amp;lt; 2). The results show that there is no apparent change of the global symmetry, with the end-members LuGe2 and LuSn2, as well as the intermediate LuGexSn2\u2013x compositions adopting the ZrSi2 type structure (space group Cmcm, Pearson index oC12). Yet, the refinements of the crystal structures from single-crystal X-ray diffraction data show that Ge\u2013Sn atom substitutions are not random, but occur preferentially at the zigzag chain. The patterned distribution of two group 14 elements leads to a significant variation in chemical bonding and charge ordering within the other structural fragment, the 2D square nets, thereby resulting in tuned electron transport. The enhancement is greater than that for the typical Bloch\u2013Gruneisen model and more akin to that for the parallel-resistor model. Magnetization measurements on single crystals show bulk superconductivity in all LuGexSn2\u2013x samples with shielding fractions as high as 90%. Specific heat data confirm the effect to originate from residual metallic tin in the material, indicating that Sn atom substitutions in the 2D square nets cause disruptions of the hypervalent bonding and local anisotropy, which ultimately leads to vanishing of the superconducting state in the end-member LuGe2. This work sheds light on how the complexity in chemical interactions by two different carbon congeners leads to changes in the physical properties and how they can be correlated with the induced charge distribution. These studies also provide a general approach to modulation of charge density and. thus, of emerging physical properties in other classes of intermetallic systems based on the main-group elements of groups 13 to 15.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.0c01062","type":"journal-article","created":{"date-parts":[[2020,9,24]],"date-time":"2020-09-24T12:24:27Z","timestamp":1600950267000},"page":"16853-16864","source":"Crossref","is-referenced-by-count":8,"title":["One Structure, Two Elements\ue5f8LuGe2 Superconductor vs Ordinary Metallic Conductor LuSn2.\nA Case Study on How Site-Selective Germanium for Tin Atom Substitution\nLeads to Modulating of the Charge Distribution"],"prefix":"10.1021","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9372-7510","authenticated-orcid":true,"given":"Jiliang","family":"Zhang","sequence":"first","affiliation":[{"name":"University of Delaware , , , ,","place":["Newark, Delaware, United States, 19716"]},{"name":"Korea University , , ,","place":["Seoul, Republic of Korea, 02841"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fazhu","family":"Ding","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences , , ,","place":["Beijing, People\u2019s Republic of China, 100190"]},{"name":"University of Chinese Academy of Sciences , ,","place":["Beijing, People\u2019s\nRepublic of China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jey-Jau","family":"Lee","sequence":"additional","affiliation":[{"name":"National Synchrotron Radiation Research Center , ,","place":["Hsinchu, Taiwan, Republic\nof China, 30076"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangcun","family":"Shan","sequence":"additional","affiliation":[{"name":"Beihang University , , ,","place":["Beijing, People\u2019s Republic of China, 100083"]},{"name":"Saarland University , , ,","place":["Saarbru\u0308cken, Germany, 66123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0780-4787","authenticated-orcid":true,"given":"Svilen","family":"Bobev","sequence":"additional","affiliation":[{"name":"University of Delaware , , , ,","place":["Newark, Delaware, United States, 19716"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,9,24]]},"reference":[{"key":"2026081720261728600_cit1","doi-asserted-by":"publisher","first-page":"12924","DOI":"10.1038\/ncomms12924","article-title":"Observation of unusual topological surface states in\nhalf-Heusler compounds LnPtBi (Ln = Lu, Y)","volume":"7","author":"Liu","year":"2016","journal-title":"Nat. Commun."},{"key":"2026081720261728600_cit2","doi-asserted-by":"publisher","first-page":"386","DOI":"10.1016\/0375-9601(80)90849-X","article-title":"Superconductivity\nof rare earth-iron silicides","volume":"75","author":"Braun","year":"1980","journal-title":"Phys. Lett. A"},{"key":"2026081720261728600_cit3","doi-asserted-by":"publisher","first-page":"157001","DOI":"10.1103\/PhysRevLett.100.157001","article-title":"Specific-heat evidence for two-gap superconductivity\nin the ternary-iron silicide Lu2Fe3Si5","volume":"100","author":"Nakajima","year":"2008","journal-title":"Phys. Rev. Lett."},{"key":"2026081720261728600_cit4","doi-asserted-by":"publisher","first-page":"052511","DOI":"10.1103\/PhysRevB.70.052511","article-title":"Superconductivity\nin LuGe2","volume":"70","author":"Chung","year":"2004","journal-title":"Phys. Rev. B: Condens.\nMatter Mater. Phys."},{"key":"2026081720261728600_cit5","doi-asserted-by":"publisher","first-page":"10295","DOI":"10.1021\/acs.inorgchem.8b01510","article-title":"Lutetium Trigermanide LuGe3: High-Pressure\nSynthesis, Superconductivity, and Chemical Bonding","volume":"57","author":"Hu\u0308bner","year":"2018","journal-title":"Inorg. Chem."},{"key":"2026081720261728600_cit6","doi-asserted-by":"publisher","first-page":"25","DOI":"10.1016\/j.physc.2005.04.021","article-title":"Superconductivity\nin YGe3","volume":"424","author":"Wei","year":"2005","journal-title":"Phys. C"},{"key":"2026081720261728600_cit7","doi-asserted-by":"publisher","first-page":"2488","DOI":"10.1021\/cm504658h","article-title":"Superconductivity in\nSingle Crystals of Lu3T4Ge13\u2011x (T = Co, Rh,\nOs) and Y3T4Ge13\u2011x (T = Ir, Rh, Os)","volume":"27","author":"Rai","year":"2015","journal-title":"Chem. Mater."},{"key":"2026081720261728600_cit8","doi-asserted-by":"publisher","first-page":"2151","DOI":"10.1021\/cm7033799","article-title":"Structure and properties of a new\nfamily of nearly equiatomic rare-earth metal-tin-germanides RESn1+xGe1\u2011x (RE = Y, Gd-Tm): an unusual example of site preferences between\nelements from the same group","volume":"20","author":"Tobash","year":"2008","journal-title":"Chem. Mater."},{"key":"2026081720261728600_cit9","doi-asserted-by":"publisher","first-page":"6","DOI":"10.1016\/j.jmmm.2013.03.033","article-title":"Thermodynamic and transport properties\nof RSn2 (R = Tb-Tm, Lu,\nY) single crystals","volume":"341","author":"Zhao","year":"2013","journal-title":"J. Magn. Magn. Mater."},{"key":"2026081720261728600_cit10","doi-asserted-by":"publisher","first-page":"948","DOI":"10.1063\/1.351771","article-title":"Epitaxial\nlutetium silicide - growth, characterization and electrical properties","volume":"72","author":"Travlos","year":"1992","journal-title":"J. Appl. Phys."},{"key":"2026081720261728600_cit11","first-page":"2245","article-title":"Synthesis,\nCrystal Structure and Band Structure of LuSn2","volume":"27","author":"Yue","year":"2011","journal-title":"Chin. J. Inorg. Chem."},{"key":"2026081720261728600_cit12","first-page":"78","article-title":"Lutetium-germanium\nphase diagram","volume":"5","author":"Eremenko","year":"1987","journal-title":"Dokl. Acad. Nauk USSR, Ser. A"},{"key":"2026081720261728600_cit13","volume-title":"SAINT","year":"2003"},{"key":"2026081720261728600_cit14","volume-title":"SADABS","year":"2003"},{"key":"2026081720261728600_cit15","volume-title":"SHELXTL","year":"2003"},{"key":"2026081720261728600_cit16","doi-asserted-by":"publisher","first-page":"184","DOI":"10.1017\/S088571561300002X","article-title":"Dysnomia,\na computer program for maximum-entropy method (MEM) analysis and its\nperformance in the MEM-based pattern fitting","volume":"28","author":"Momma","year":"2013","journal-title":"Powder Diffr."},{"key":"2026081720261728600_cit17","doi-asserted-by":"publisher","first-page":"653","DOI":"10.1107\/S0021889808012016","article-title":"VESTA: a three-dimensional visualization\nsystem for electronic and structural analysis","volume":"41","author":"Momma","year":"2008","journal-title":"J. Appl. Crystallogr."},{"key":"2026081720261728600_cit18","doi-asserted-by":"publisher","first-page":"2745","DOI":"10.1088\/0953-8984\/14\/11\/302","article-title":"The SIESTA\nmethod for ab-initio order-N materials simulation","volume":"14","author":"Soler","year":"2002","journal-title":"J. Phys.: Condens. Matter"},{"key":"2026081720261728600_cit19","doi-asserted-by":"publisher","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","article-title":"Generalized\ngradient approximation made simple","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev.\nLett."},{"key":"2026081720261728600_cit20","doi-asserted-by":"publisher","first-page":"124","DOI":"10.1021\/ja00235a021","article-title":"Square nets of main-group elements in solid-state materials","volume":"109","author":"Tremel","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"2026081720261728600_cit21","doi-asserted-by":"publisher","first-page":"246","DOI":"10.1524\/zkri.2000.215.4.246","article-title":"Contribution to the\ncrystal chemistry of rare earth chalcogenides. I. The compounds with\nlayer structures LnX2","volume":"215","author":"Bottcher","year":"2000","journal-title":"Z. Kristallogr. - Cryst. Mater."},{"key":"2026081720261728600_cit22","doi-asserted-by":"publisher","first-page":"3901","DOI":"10.1021\/ic102077k","article-title":"High-pressure synthesis and superconductivity of a\nnew binary lanthanum germanide LaGe3 with triangular Ge3\ncluster units","volume":"50","author":"Fukuoka","year":"2011","journal-title":"Inorg. Chem."},{"key":"2026081720261728600_cit23","doi-asserted-by":"publisher","first-page":"722","DOI":"10.1021\/ic501002j","article-title":"Structural\nModulations in the Rare-Earth Metal Digermanides REAl1\u2011xGe2 (RE = Gd-Tm, Lu, Y; 0.8 &lt; x &lt; 0.9). Correlations between Long- and Short-Range\nVacancy Ordering","volume":"54","author":"Zhang","year":"2015","journal-title":"Inorg. Chem."},{"key":"2026081720261728600_cit24","doi-asserted-by":"publisher","first-page":"9253","DOI":"10.1039\/C7DT01977G","article-title":"On the structures of the rare-earth\nmetal germanides from the series REAl1\u2011xGe3 (RE = Nd, Sm, Gd, Tb, Dy, Ho; 0.6 &lt; x &lt; 0.9). A tale of vacancies at the Al sites and the\nconcomitant structural modulations","volume":"46","author":"Zhang","year":"2017","journal-title":"Dalton Trans."},{"key":"2026081720261728600_cit25","volume-title":"The Nature of the Chemical Bond","author":"Pauling","year":"1960","edition":"3"},{"key":"2026081720261728600_cit26","doi-asserted-by":"publisher","first-page":"1575","DOI":"10.1016\/j.jssc.2007.03.003","article-title":"Synthesis, structure and electronic structure of a new polymorph\nof CaGe2","volume":"180","author":"Tobash","year":"2007","journal-title":"J. Solid State Chem."},{"key":"2026081720261728600_cit27","doi-asserted-by":"publisher","first-page":"7286","DOI":"10.1021\/ic060913f","article-title":"Vacancy ordering in SmGe2\u2011x and GdGe2\u2011x (x = 0.33): Structure and properties of two\nSm3Ge5 polymorphs and of Gd3Ge5","volume":"45","author":"Tobash","year":"2006","journal-title":"Inorg. Chem."},{"key":"2026081720261728600_cit28","doi-asserted-by":"publisher","first-page":"953","DOI":"10.1021\/ic3021645","article-title":"Synthesis, Structural Characterization, and Physical Properties of\nthe Early Rare-Earth Metal Digermanides REGe2\u2011x (x \u223c 1\/4) RE = La-Nd, Sm. A Case Study\nof Commensurately and Incommensurately Modulated Structures","volume":"52","author":"Zhang","year":"2013","journal-title":"Inorg. Chem."},{"key":"2026081720261728600_cit29","volume-title":"Pearson\u2019s\nHandbook of Crystallographic Data for Intermetallic Phases","author":"Villars","year":"1991","edition":"2"},{"key":"2026081720261728600_cit30","doi-asserted-by":"publisher","first-page":"075415","DOI":"10.1103\/PhysRevB.75.075415","article-title":"Predictions for the\nformation of atomic chains in mechanically controllable break-junction\nexperiments","volume":"75","author":"Ferna\u0301ndez-Seivane","year":"2007","journal-title":"Phys. Rev. B: Condens. Matter Mater.\nPhys."},{"key":"2026081720261728600_cit31","doi-asserted-by":"publisher","first-page":"2805","DOI":"10.1103\/PhysRevLett.83.2805","article-title":"Nonmonotonic temperature-dependent resistance in low\ndensity 2D hole gases","volume":"83","author":"Mills","year":"1999","journal-title":"Phys. Rev. Lett."},{"key":"2026081720261728600_cit32","doi-asserted-by":"publisher","first-page":"1085","DOI":"10.1103\/RevModPhys.75.1085","article-title":"Colloquium:\nSaturation of electrical resistivity","volume":"75","author":"Gunnarsson","year":"2003","journal-title":"Rev. Mod.\nPhys."},{"key":"2026081720261728600_cit33","doi-asserted-by":"publisher","first-page":"024512","DOI":"10.1103\/PhysRevB.73.024512","article-title":"Superconductivity mediated by a soft\nphonon mode: Specific heat, resistivity, thermal expansion, and magnetization\nof YB6","volume":"73","author":"Lortz","year":"2006","journal-title":"Phys. Rev. B: Condens. Matter\nMater. Phys."},{"key":"2026081720261728600_cit34","doi-asserted-by":"publisher","first-page":"134505","DOI":"10.1103\/PhysRevB.97.134505","article-title":"Pressure effect\non the superconducting and the normal state of \u03b2-Bi2Pd","volume":"97","author":"Prista\u0301s","year":"2018","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"2026081720261728600_cit35","doi-asserted-by":"publisher","first-page":"782","DOI":"10.1103\/PhysRevLett.38.782","article-title":"Simple model for characterizing the electrical resistivity\nin A15 superconductors","volume":"38","author":"Wiesmann","year":"1977","journal-title":"Phys. Rev. Lett."},{"key":"2026081720261728600_cit36","doi-asserted-by":"publisher","first-page":"203","DOI":"10.1103\/RevModPhys.50.203","article-title":"Electrons in glass","volume":"50","author":"Mott","year":"1978","journal-title":"Rev. Mod. Phys."},{"key":"2026081720261728600_cit37","volume-title":"Electronic Transport\nTheories From Weakly to Stongly Correlated Materials","author":"Singh","year":"2017"},{"key":"2026081720261728600_cit38","doi-asserted-by":"publisher","first-page":"045136","DOI":"10.1103\/PhysRevB.90.045136","article-title":"High-pressure effect\non the superconductivity of YB6","volume":"90","author":"Gaba\u0301ni","year":"2014","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"2026081720261728600_cit39","doi-asserted-by":"publisher","first-page":"5041","DOI":"10.1021\/acs.inorgchem.7b00031","article-title":"Hypervalent bismuthides La3MBi5 (M = Ti, Zr, Hf) and related antimonides: absence of superconductivity","volume":"56","author":"Murakami","year":"2017","journal-title":"Inorg. Chem."},{"key":"2026081720261728600_cit40","doi-asserted-by":"publisher","first-page":"586","DOI":"10.1016\/j.jssc.2012.07.031","article-title":"New rare-earth metal germanides with\nbismuth substitution. Synthesis, structural variations, and magnetism\nof the RE\u00ad[BixGe1\u2011x]2 (RE = Y, Pr, Nd, Sm, Gd-Tm, Lu) compounds","volume":"196","author":"Zhang","year":"2012","journal-title":"J. Solid State Chem."},{"key":"2026081720261728600_cit41","doi-asserted-by":"publisher","first-page":"2164","DOI":"10.1021\/acs.chemmater.9b00258","article-title":"Importance of specific\nheat characterization when reporting new superconductors: an example\nof superconductivity in LiGa2Rh","volume":"31","author":"Carnicom","year":"2019","journal-title":"Chem. Mater."},{"key":"2026081720261728600_cit42","volume-title":"Superconductivity\nOf Metals And Alloys","author":"De Gennes","year":"1999"},{"key":"2026081720261728600_cit43","doi-asserted-by":"publisher","first-page":"367","DOI":"10.1038\/nmat2179","article-title":"Bulk superconductivity\nat 38 K in a molecular system","volume":"7","author":"Ganin","year":"2008","journal-title":"Nat. Mater."},{"key":"2026081720261728600_cit44","doi-asserted-by":"publisher","first-page":"484","DOI":"10.1021\/acs.inorgchem.9b02746","article-title":"Pressure-Induced Structural Phase Transition and Superconductivity\nin NaSn5","volume":"59","author":"Hao","year":"2020","journal-title":"Inorg. Chem."},{"key":"2026081720261728600_cit45","doi-asserted-by":"publisher","first-page":"2881","DOI":"10.1021\/ja00164a006","article-title":"Ge-Ge bonding in the\nhigh-pressure modification of lithium germanide: a near-Zintl phase","volume":"112","author":"Sherwood","year":"1990","journal-title":"J. Am. Chem. Soc."},{"key":"2026081720261728600_cit46","doi-asserted-by":"publisher","first-page":"1479","DOI":"10.1088\/0034-4885\/68\/6\/R04","article-title":"Recent developments\nin magnetocaloric materials","volume":"68","author":"Gschneidner","year":"2005","journal-title":"Rep. Prog. Phys."},{"key":"2026081720261728600_cit47","doi-asserted-by":"publisher","first-page":"382203","DOI":"10.1088\/0953-8984\/21\/38\/382203","article-title":"Superconductivity up to 30 K in the\nvicinity of the quantum critical point in BaFe2(As1\u2011xPx)2","volume":"21","author":"Jiang","year":"2009","journal-title":"J. Phys.: Condens. Matter"},{"key":"2026081720261728600_cit48","doi-asserted-by":"publisher","first-page":"107003","DOI":"10.1103\/PhysRevLett.105.107003","article-title":"Unconventional\nsuperconductivity and antiferromagnetic quantum critical behavior\nin the isovalent-doped BaFe2(As1\u2011xPx)2","volume":"105","author":"Nakai","year":"2010","journal-title":"Phys. Rev. Lett."},{"key":"2026081720261728600_cit49","doi-asserted-by":"publisher","first-page":"16017","DOI":"10.1038\/natrevmats.2016.17","article-title":"High-temperature superconductivity in iron pnictides\nand chalcogenides","volume":"1","author":"Si","year":"2016","journal-title":"Nat. Rev. Mater."},{"key":"2026081720261728600_cit50","doi-asserted-by":"publisher","first-page":"176","DOI":"10.1038\/s41563-019-0564-4","article-title":"Targeted\nchemical pressure yields tuneable millimetre-wave dielectric","volume":"19","author":"Dawley","year":"2020","journal-title":"Nat. Mater."},{"key":"2026081720261728600_cit51","doi-asserted-by":"publisher","first-page":"11170","DOI":"10.1021\/jacs.8b06187","article-title":"Chemical Pressure-Induced Anion Order-Disorder\nTransition in LnHO Enabled by Hydride Size Flexibility","volume":"140","author":"Yamashita","year":"2018","journal-title":"J. Am. Chem. Soc."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.0c01062","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/59\/23\/16853\/9110740\/ic0c01062.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/59\/23\/16853\/9110740\/ic0c01062.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T08:18:02Z","timestamp":1787041082000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/inocaj\/article\/59\/23\/16853\/860742\/One-Structure-Two-Elements-amp-xe5f8-LuGe2"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,9,24]]},"references-count":51,"journal-issue":{"issue":"23","published-online":{"date-parts":[[2020,9,24]]},"published-print":{"date-parts":[[2020,12,7]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.inorgchem.0c01062","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,9,24]]}}}