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A novel strategy for the construction of both thermally stable and mechanically insensitive energetic materials using a multi-aminotriazole system is now described. Using this methodology, two series of energetic materials were created on the basis of a duo of triazoles, 5-amino-3-(3,4-diamino-1,2,4-triazol-5-yl)-1H-1,2,4-triazole (TT), and a trio of triazoles, 4,5-di\u00ad(3,4-diamino-1,2,4-triazol-5-yl)-2H-1,2,3-triazole (TTT). Their nitrogen-rich salts were also synthesized. Compound TT exhibits an excellent onset decomposition temperature (Td = 341 \u00b0C), which is superior to that of the conventional heat-resistant explosive hexanitrostilbene (HNS) (Td = 318 \u00b0C). The nitrogen-rich salt 4,5-di\u00ad(3,4-diamino-1,2,4-triazol-5-yl)-2H-1,2,3-triazolium 3,4,5-trinitropyrazol-1-ide (TTT-1) exhibits both remarkable detonation properties and low sensitivities (Dv = 8715 m s\u20131; P = 32.6 GPa; IS &amp;gt; 40 J; FS &amp;gt; 360 N), which are superior to those of the traditional explosive LLM-105 (Dv = 8639 m s\u20131; P = 31.7 GPa; IS = 20 J; FS = 360 N). Therefore, this methodology of building a multi-aminotriazole system could effectively assist in the design of thermally stable and mechanically insensitive energetic materials in future exploration.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.0c03014","type":"journal-article","created":{"date-parts":[[2020,11,16]],"date-time":"2020-11-16T21:31:18Z","timestamp":1605562278000},"page":"17766-17774","source":"Crossref","is-referenced-by-count":59,"title":["A Duo and a Trio of Triazoles as Very Thermostable\nand Insensitive Energetic Materials"],"prefix":"10.1021","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9549-9195","authenticated-orcid":true,"given":"Yongxing","family":"Tang","sequence":"first","affiliation":[{"name":"Nanjing University of Science and Technology , ,","place":["Nanjing, China, 210094"]},{"name":"University of Idaho , , , ,","place":["Moscow, Idaho, United States, 83844-2343"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaoyang","family":"Yin","sequence":"additional","affiliation":[{"name":"Nanjing University of Science and Technology , ,","place":["Nanjing, China, 210094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8643-5694","authenticated-orcid":true,"given":"Ajay Kumar","family":"Chinnam","sequence":"additional","affiliation":[{"name":"University of Idaho , , , ,","place":["Moscow, Idaho, United States, 83844-2343"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2760-769X","authenticated-orcid":true,"given":"Richard J.","family":"Staples","sequence":"additional","affiliation":[{"name":"Michigan State University , , , ,","place":["East Lansing, Michigan, United States, 48825"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8622-4897","authenticated-orcid":true,"given":"Jean\u2019ne M.","family":"Shreeve","sequence":"additional","affiliation":[{"name":"University of Idaho , , , ,","place":["Moscow, Idaho, United States, 83844-2343"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,11,16]]},"reference":[{"key":"2026081720275615300_cit1","doi-asserted-by":"publisher","first-page":"16132","DOI":"10.1002\/anie.201609267","article-title":"Synthesis and Investigation of Advanced\nEnergetic Materials Based on Bispyrazolylmethanes","volume":"55","author":"Fischer","year":"2016","journal-title":"Angew. 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