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Syntheses","author":"White C.","year":"2007"},{"key":"ref23\/cit23","doi-asserted-by":"crossref","unstructured":"Eliel, E. L.; Wilen, S. H.; Mander, L. N. Stereochemistry of Organic Compounds; Wiley: New York, 1994, p. 159.","DOI":"10.1002\/9780470147306"},{"key":"ref24\/cit24","unstructured":"Racemic and enantiopure\ncrystals of compounds 1 and 2 are isolated\ntogether and mixed. However, fortunately, its morphology and size\nallow their separation and individualized study. Indeed, single crystals\nof rac-1 and rac-2 are needle-shaped and both enantiomers of each of the two\ncompounds crystallize in large parallelepipeds of up to about 10 mg\nin weight. Therefore, it is easy to manually separate racemic crystals\nfrom enantiopure crystals. For one of the enantiomers of each compound,\nthe CD spectrum of exactly the crystal whose molecular structure was\ndetermined by X-ray diffraction was measured and taken as reference\n(see Supporting Information). A small portion\n(about 1 mg) was cut from a large enantiopure crystal (about 4\u201310\nmg) and its CD spectrum was measured. By comparison with the above\nmentioned CD reference spectrum, the configuration was assigned to\nthe remaining crystal (approximately 3\u20139 mg). By repeating\nthe operation, samples of several tens of milligrams of each of the\nfour enantiomers, RRh-1, SRh-1, RIr-2 and SIr-2, can be obtained. Their CD spectra are shown in the Supporting Information."},{"key":"ref25\/cit25a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.196603851"},{"key":"ref25\/cit25b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198205671"},{"key":"ref25\/cit25c","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)80382-4"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1039\/p298700000s1"},{"key":"ref27\/cit27","unstructured":"The previously reported\nGibbs free energy profile of the hydrogen exchange at 3[21] calculated at the level M06\/def2tzvp\/\/B3PW91-GD3BJ\/def2svp\nis substantially identical to that given in Figure 6. Nonetheless, it is worth a mention that\nwe were unable to identify the intermediate IRh\u00b7H2O, but a PES scan showed that water should approach\nthe FLP IRh forming an OH\u00b7\u00b7\u00b7N\nhydrogen bond in the first place, followed by the coordination of\noxygen to rhodium, finally affording the hydroxo derivative IIRh."},{"key":"ref28\/cit28","unstructured":"N(2) adopts an almost\nplanar geometry both in 8a [\u03a3\u00b0N(2) = 357(6)\u00b0]\nand 8b [\u03a3\u00b0N(2) = 353(6)\u00b0] reasonably\nas a consequence of some degree of delocalization of the lone pair\nat nitrogen N(2) either on the adjacent aromatic ring as well as on\nthe CN3 core of the guanidine moiety."},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/om200089m"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201202936"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT04168A"}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.2c01902","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.2c01902","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,27]],"date-time":"2023-04-27T08:16:24Z","timestamp":1682583384000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.inorgchem.2c01902"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,8,10]]},"references-count":141,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2022,8,22]]}},"alternative-id":["10.1021\/acs.inorgchem.2c01902"],"URL":"https:\/\/doi.org\/10.1021\/acs.inorgchem.2c01902","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,8,10]]}}}