{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,15]],"date-time":"2026-01-15T13:55:41Z","timestamp":1768485341979,"version":"3.49.0"},"reference-count":57,"publisher":"American Chemical Society (ACS)","issue":"46","license":[{"start":{"date-parts":[[2022,11,10]],"date-time":"2022-11-10T00:00:00Z","timestamp":1668038400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2022,11,10]],"date-time":"2022-11-10T00:00:00Z","timestamp":1668038400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2022,11,10]],"date-time":"2022-11-10T00:00:00Z","timestamp":1668038400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100000196","name":"Canada Foundation for Innovation","doi-asserted-by":"publisher","award":["JELF 33977"],"award-info":[{"award-number":["JELF 33977"]}],"id":[{"id":"10.13039\/501100000196","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004381","name":"Western University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004381","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100013020","name":"Compute Canada","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100013020","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100020088","name":"Solvay","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100020088","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["RGPIN-2018-04240"],"award-info":[{"award-number":["RGPIN-2018-04240"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["RGPIN-2021-04377"],"award-info":[{"award-number":["RGPIN-2021-04377"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003400","name":"Ministry of Research and Innovation","doi-asserted-by":"publisher","award":["ER14-10-147"],"award-info":[{"award-number":["ER14-10-147"]}],"id":[{"id":"10.13039\/501100003400","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2022,11,21]]},"DOI":"10.1021\/acs.inorgchem.2c03216","type":"journal-article","created":{"date-parts":[[2022,11,10]],"date-time":"2022-11-10T17:09:09Z","timestamp":1668100149000},"page":"18719-18728","source":"Crossref","is-referenced-by-count":11,"title":["Heterocyclic Phosphenium Cations and Their Divergent Coordination Chemistry"],"prefix":"10.1021","volume":"61","author":[{"given":"Alexander E. R.","family":"Watson","sequence":"first","affiliation":[{"name":"Department of Chemistry and the Centre for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, London, Ontario N6A 5B7, Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0229-2188","authenticated-orcid":true,"given":"Michael J.","family":"Grant","sequence":"additional","affiliation":[{"name":"Department of Chemistry and the Centre for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, London, Ontario N6A 5B7, Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Paul D.","family":"Boyle","sequence":"additional","affiliation":[{"name":"Department of Chemistry and the Centre for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, London, Ontario N6A 5B7, Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2727-7635","authenticated-orcid":true,"given":"Paul J.","family":"Ragogna","sequence":"additional","affiliation":[{"name":"Department of Chemistry and the Centre for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, London, Ontario N6A 5B7, Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0349-7780","authenticated-orcid":true,"given":"Joe B.","family":"Gilroy","sequence":"additional","affiliation":[{"name":"Department of Chemistry and the Centre for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, London, Ontario N6A 5B7, Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2022,11,10]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1021\/cr010424r"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.07.014"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2011.12.012"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/cr100216y"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/cr00069a002"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/ic50116a050"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1038\/nature13384"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/ic202581v"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b09754"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1039\/b801684d"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/cr078381n"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b03235"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/om400868w"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/om100595a"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1039\/b301333b"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1021\/ic0351444"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1039\/B607549E"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2009.01.022"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/cr040179m"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1039\/C6TC00590J"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201406535"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1007\/s11705-014-1445-7"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1039\/C1SC00658D"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2612"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201900383"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1039\/D0NJ04547K"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.202200131"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1055\/s-1977-24435"},{"key":"ref29\/cit29","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.; Nakatsuji, H.; Li, X.; Caricato, M.; Marenich, A. V.; Bloino, J.; Janesko, B. G.; Gomperts, R.; Mennucci, B.; Hratchian, H. P.; Ortiz, J. V.; Izmaylov, A. F.; Sonnenberg, J. L.; Williams-Young, D.; Ding, F.; Lipparini, F.; Egidi, F.; Goings, J.; Peng, B.; Petrone, A.; Henderson, T.; Ranasinghe, D.; Zakrzewski, V. G.; Gao, J.; Rega, N.; Zheng, G.; Liang, W.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Throssell, K.; Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M. J.; Heyd, J. J.; Brothers, E. N.; Kudin, K. N.; Staroverov, V. N.; Keith, T. A.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A. P.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Millam, J. M.; Klene, M.; Adamo, C.; Cammi, R.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Farkas, O.; Foresman, J. B.; Fox, D. J. Gaussian 16, Revision B.01; Gaussian Inc.: Wallingford, CT, 2016."},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1063\/1.479571"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1063\/1.478401"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.23266"},{"key":"ref33\/cit33","unstructured":"Bruker-AXS. SAINT\nVersion 2013.8. 2013."},{"key":"ref34\/cit34","unstructured":"Bruker-AXS. SADABS\nVersion 2012.1. 2012."},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024929"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889807067908"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1039\/p19840002109"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.08.007"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1039\/C9CP05049C"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs35531d"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2015.07.002"},{"key":"ref44\/cit44","doi-asserted-by":"crossref","first-page":"107","DOI":"10.1016\/S0065-3055(03)50002-8","volume":"50","author":"Nakazawa H.","year":"2004","journal-title":"Adv. Organomet. Chem."},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00262"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2008.09.004"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200900133"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303686"},{"key":"ref49\/cit49","volume-title":"CRC Handbook of Chemistry and Physics","author":"Haynes W. M.","year":"2015","edition":"96"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199303991"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/ic026090l"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1107\/S1600536802000077"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1021\/om060466b"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1021\/ic0488738"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2007.03.045"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1139\/cjc-2017-0647"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2008.12.047"}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.2c03216","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.2c03216","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,26]],"date-time":"2023-04-26T10:54:22Z","timestamp":1682506462000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.inorgchem.2c03216"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11,10]]},"references-count":57,"journal-issue":{"issue":"46","published-print":{"date-parts":[[2022,11,21]]}},"alternative-id":["10.1021\/acs.inorgchem.2c03216"],"URL":"https:\/\/doi.org\/10.1021\/acs.inorgchem.2c03216","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,11,10]]}}}