{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,17]],"date-time":"2025-09-17T15:38:15Z","timestamp":1758123495442,"version":"3.37.3"},"reference-count":97,"publisher":"American Chemical Society (ACS)","issue":"32","license":[{"start":{"date-parts":[[2024,7,27]],"date-time":"2024-07-27T00:00:00Z","timestamp":1722038400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2024,7,27]],"date-time":"2024-07-27T00:00:00Z","timestamp":1722038400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2024,7,27]],"date-time":"2024-07-27T00:00:00Z","timestamp":1722038400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["WE 5627\/4-1","WE 5627\/4-2","WE 5627\/7-1"],"award-info":[{"award-number":["WE 5627\/4-1","WE 5627\/4-2","WE 5627\/7-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2024,8,12]]},"DOI":"10.1021\/acs.inorgchem.4c02882","type":"journal-article","created":{"date-parts":[[2024,7,27]],"date-time":"2024-07-27T13:22:05Z","timestamp":1722086525000},"page":"15236-15246","source":"Crossref","is-referenced-by-count":1,"title":["Divergent Interaction of (Iso)nitriles with a Linear Iron(I) Silylamide\u2500A Combined Structural, Spectroscopic, and Computational Study"],"prefix":"10.1021","volume":"63","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9963-8391","authenticated-orcid":true,"given":"C. Gunnar","family":"Werncke","sequence":"first","affiliation":[{"name":"Chemistry Department, Philipps-University Marburg, Hans-Meerwein-Stra\u00dfe 4, D-35043 Marburg, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Igor","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Chemistry Department, Philipps-University Marburg, Hans-Meerwein-Stra\u00dfe 4, D-35043 Marburg, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kilian","family":"Wei\u00dfer","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Humboldt-University Berlin, Brook-Taylor-Str. 2, D-13089 Berlin, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0751-1386","authenticated-orcid":true,"given":"Christian","family":"Limberg","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Humboldt-University Berlin, Brook-Taylor-Str. 2, D-13089 Berlin, Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2024,7,27]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1039\/B715027J"},{"volume-title":"Encyclopedia of Inorganic and Bioinorganic Chemistry","year":"2022","author":"Werncke C. G.","key":"ref2\/cit2"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1021\/cr2004647"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00216E"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1039\/C0DT01247E"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214941"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00381"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201607243"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT01543E"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c00214"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201408802"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201503980"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1630"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/ic402013n"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC05166E"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT05002C"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202004852"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404577"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404577"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202103841"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC01088G"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC04196G"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202100336"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202103096"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.3390\/inorganics7100117"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC04451J"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c00365"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c03724"},{"key":"ref29\/cit29","first-page":"C79","volume":"18","author":"Dewar M.","year":"1951","journal-title":"Bull. Soc. Chem. Fr"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1039\/jr9530002939"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC08968C"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00121"},{"volume-title":"Comprehensive Organometallic Chemistry, IV","year":"2021","author":"Werncke C. G.","key":"ref33\/cit33"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300254"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC03043K"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1021\/ja1012382"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC07863J"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/ic052110i"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200603746"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.2c00151"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c01595"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.9b00834"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1021\/ja0204933"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/om049700t"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1021\/om0008474"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2024.02.015"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC02516G"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100787"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(02)01264-0"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1021\/ja408589p"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b03127"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b09445"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202201699"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460879"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1021\/ic300368z"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1021\/ja063604x"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1021\/ic061704y"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1039\/b100117p"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b02504"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT03924E"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19610940442"},{"key":"ref62\/cit62","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201030"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1039\/c002778b"},{"key":"ref64\/cit64","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200901990"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1021\/om00094a001"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC00171G"},{"key":"ref67\/cit67","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201607899"},{"key":"ref68\/cit68","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC03463D"},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1139\/v05-023"},{"key":"ref70\/cit70","doi-asserted-by":"publisher","DOI":"10.1021\/om00140a012"},{"key":"ref71\/cit71","doi-asserted-by":"publisher","DOI":"10.1021\/ic401677j"},{"key":"ref72\/cit72","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201202211"},{"key":"ref73\/cit73","doi-asserted-by":"publisher","DOI":"10.1021\/ic050321h"},{"key":"ref74\/cit74","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b02540"},{"key":"ref75\/cit75","doi-asserted-by":"publisher","DOI":"10.1021\/ja710669w"},{"key":"ref76\/cit76","doi-asserted-by":"publisher","DOI":"10.1021\/ic301240u"},{"key":"ref77\/cit77","doi-asserted-by":"publisher","DOI":"10.1021\/ar00084a005"},{"key":"ref78\/cit78","doi-asserted-by":"publisher","DOI":"10.1021\/jo00406a020"},{"key":"ref79\/cit79","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.19660490312"},{"key":"ref80\/cit80","doi-asserted-by":"publisher","DOI":"10.1021\/ar00027a003"},{"key":"ref81\/cit81","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.1c00365"},{"key":"ref82\/cit82","doi-asserted-by":"publisher","DOI":"10.1246\/cl.150688"},{"key":"ref83\/cit83","doi-asserted-by":"publisher","DOI":"10.1021\/ic00283a022"},{"key":"ref84\/cit84","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.1606"},{"key":"ref85\/cit85","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.1327"},{"key":"ref86\/cit86","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.81"},{"key":"ref87\/cit87","doi-asserted-by":"publisher","DOI":"10.1063\/5.0004608"},{"key":"ref88\/cit88","doi-asserted-by":"publisher","DOI":"10.1063\/1.472933"},{"key":"ref89\/cit89","doi-asserted-by":"publisher","DOI":"10.1063\/1.478522"},{"key":"ref90\/cit90","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.91.146401"},{"key":"ref91\/cit91","doi-asserted-by":"publisher","DOI":"10.1063\/1.1626543"},{"key":"ref92\/cit92","doi-asserted-by":"publisher","DOI":"10.1063\/1.476576"},{"key":"ref93\/cit93","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"ref94\/cit94","doi-asserted-by":"publisher","DOI":"10.1063\/1.5090222"},{"key":"ref95\/cit95","doi-asserted-by":"publisher","DOI":"10.1039\/b515623h"},{"key":"ref96\/cit96","doi-asserted-by":"publisher","DOI":"10.1016\/0301-0104(80)80045-0"},{"key":"ref97\/cit97","doi-asserted-by":"publisher","DOI":"10.1063\/1.1361246"}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.4c02882","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.4c02882","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,8,12]],"date-time":"2024-08-12T08:17:44Z","timestamp":1723450664000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.inorgchem.4c02882"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,7,27]]},"references-count":97,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2024,8,12]]}},"alternative-id":["10.1021\/acs.inorgchem.4c02882"],"URL":"https:\/\/doi.org\/10.1021\/acs.inorgchem.4c02882","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"type":"print","value":"0020-1669"},{"type":"electronic","value":"1520-510X"}],"subject":[],"published":{"date-parts":[[2024,7,27]]}}}