{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,16]],"date-time":"2026-05-16T08:14:05Z","timestamp":1778919245962,"version":"3.51.4"},"reference-count":60,"publisher":"American Chemical Society (ACS)","issue":"18","license":[{"start":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T00:00:00Z","timestamp":1777334400000},"content-version":"unspecified","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP25620020"],"award-info":[{"award-number":["JP25620020"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Inorg. Chem."],"published-print":{"date-parts":[[2026,5,11]]},"DOI":"10.1021\/acs.inorgchem.6c00544","type":"journal-article","created":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T16:57:38Z","timestamp":1777395458000},"page":"10087-10095","source":"Crossref","is-referenced-by-count":0,"title":["1,3-Disilabicyclo[1.1.0]butane and \u03b7\n                    <sup>2<\/sup>\n                    -Silene Nickel Complex Derived from a Bromosilene"],"prefix":"10.1021","volume":"65","author":[{"given":"Shunya","family":"Honda","sequence":"first","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7832-912X","authenticated-orcid":true,"given":"Shintaro","family":"Ishida","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8556-5785","authenticated-orcid":true,"given":"Takeaki","family":"Iwamoto","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2026,4,28]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01348a011"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1021\/ar960252y"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(03)00104-8"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2007.07.005"},{"key":"ref2\/cit2d","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200801968"},{"key":"ref2\/cit2e","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc42595a"},{"key":"ref3\/cit3a","doi-asserted-by":"crossref","first-page":"619","DOI":"10.1016\/B978-0-12-801981-8.00010-1","volume-title":"Organosilicon Compounds. Theory and Experiment (Synthesis)","author":"Mizuhata Y.","year":"2017"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.2183\/pjab.99.027"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1021\/ja2014746"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209281"},{"key":"ref4\/cit4c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304594"},{"key":"ref4\/cit4d","doi-asserted-by":"publisher","DOI":"10.1021\/ja404045f"},{"key":"ref4\/cit4e","doi-asserted-by":"publisher","DOI":"10.1021\/ja4072139"},{"key":"ref4\/cit4f","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402868"},{"key":"ref4\/cit4g","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c09040"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800973"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1021\/ja308777v"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201603640"},{"key":"ref5\/cit5d","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201901772"},{"key":"ref5\/cit5e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201910336"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2011.196"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06960"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.0c00368"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1246\/cl.200968"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2018.00114"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.20090338"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1021\/ja011658v"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.1c00284"},{"key":"ref12\/cit12c","doi-asserted-by":"publisher","DOI":"10.1016\/j.mencom.2022.01.012"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198703641"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1021\/ic00273a022"},{"key":"ref13\/cit13c","doi-asserted-by":"publisher","DOI":"10.1021\/j100345a009"},{"key":"ref13\/cit13d","doi-asserted-by":"publisher","DOI":"10.1002\/poc.4019"},{"key":"ref14\/cit14","doi-asserted-by":"crossref","unstructured":"Kaftory, M.; Kapon, M.; Botoshansky, M.\n                      The Chemistry of Organic Silicon Compounds\n                      ; Rappoport, Z.; Apeloig, Y., Eds. Wiley: Chichester, 1998; Vol. 2, pp 181\u2013265.","DOI":"10.1002\/0470857250.ch5"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT01009A"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20494"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/cr00005a013"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1016\/0166-1280(88)80281-1"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/ja00544a007"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200353048"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2015.11.007"},{"key":"ref22\/cit22a","first-page":"C71","volume":"18","author":"Dewar M. J. S.","year":"1951","journal-title":"Bull. Soc. Chim. Fr."},{"key":"ref22\/cit22b","doi-asserted-by":"publisher","DOI":"10.1039\/jr9530002939"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/ct400687b"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410637"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.4c00825"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1039\/p19930000117"},{"key":"ref27\/cit27","unstructured":"Sheldrick, G. M.\n                      SADABS, Empirical Absorption Correction Program\n                      ; University of G\u00f6ttingen: G\u00f6ttingen, Germany, 1996."},{"key":"ref28\/cit28","unstructured":"Sheldrick, G. M.\n                      SHELXL-2019, Program for the Refinement of Crystal Structures\n                      ; University of G\u00f6ttingen: G\u00f6ttingen, Germany, 2019."},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.5940\/jcrsj.51.218"},{"key":"ref30\/cit30","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, Jr. J. A.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, \u00d6.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J.\n                      Gaussian 09, Revision D.01\n                      ; Gaussian, Inc.: Wallingford CT, 2009."},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1039\/c3cp44063j"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2003.12.030"},{"key":"ref33\/cit33","unstructured":"Maeda, S.; Harabuchi, Y.; Osada, Y.; Taketsugu, T.; Morokuma, K.; Ohno, K. GRRM14. https:\/\/iqce.jp\/GRRM\/index_e.shtml. (accessed on 24 December 2025)."},{"key":"ref34\/cit34a","doi-asserted-by":"publisher","DOI":"10.1063\/1.452288"},{"key":"ref34\/cit34b","doi-asserted-by":"publisher","DOI":"10.1080\/00268978800101811"},{"key":"ref35\/cit35a","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.22885"},{"key":"ref35\/cit35b","doi-asserted-by":"publisher","DOI":"10.1063\/5.0216272"},{"key":"ref36\/cit36","unstructured":"Knizia, G. IBOview. http:\/\/www.iboview.org\/. (accessed 24th, December 2025)."},{"key":"ref37\/cit37","unstructured":"Keith, T. A.\n                      AIMAll (Version 19.10.12)\n                      ; TK Gristmill Software: Overland Park KS, USA, 2019 (aim.tkgristmill.com)."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.6c00544","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.6c00544","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,5,16]],"date-time":"2026-05-16T07:52:09Z","timestamp":1778917929000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.inorgchem.6c00544"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,4,28]]},"references-count":60,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2026,5,11]]}},"alternative-id":["10.1021\/acs.inorgchem.6c00544"],"URL":"https:\/\/doi.org\/10.1021\/acs.inorgchem.6c00544","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,4,28]]}}}