{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T12:34:12Z","timestamp":1786365252601,"version":"build-2736575974"},"reference-count":42,"publisher":"American Chemical Society (ACS)","issue":"31","license":[{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100022957","name":"Double Thousand Plan of Jiangxi Province","doi-asserted-by":"publisher","award":["jxsq2019104001"],"award-info":[{"award-number":["jxsq2019104001"]}],"id":[{"id":"10.13039\/100022957","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100022957","name":"Double Thousand Plan of Jiangxi Province","doi-asserted-by":"publisher","award":["jxsq2020101058"],"award-info":[{"award-number":["jxsq2020101058"]}],"id":[{"id":"10.13039\/100022957","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010857","name":"Jiangxi Provincial Department of Science and Technology","doi-asserted-by":"publisher","award":["QNJG2020007"],"award-info":[{"award-number":["QNJG2020007"]}],"id":[{"id":"10.13039\/501100010857","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010857","name":"Jiangxi Provincial Department of Science and Technology","doi-asserted-by":"publisher","award":["ZBG20230418009"],"award-info":[{"award-number":["ZBG20230418009"]}],"id":[{"id":"10.13039\/501100010857","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010857","name":"Jiangxi Provincial Department of Science and Technology","doi-asserted-by":"publisher","award":["ZBG20230418030"],"award-info":[{"award-number":["ZBG20230418030"]}],"id":[{"id":"10.13039\/501100010857","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22362024"],"award-info":[{"award-number":["22362024"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004479","name":"Natural Science Foundation of Jiangxi Province","doi-asserted-by":"publisher","award":["20252BAC240673"],"award-info":[{"award-number":["20252BAC240673"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>In recent years, metal halide perovskite materials have emerged as potential tools for photocatalytic redox reactions owing to their low cost, tunable band gaps, and other excellent optoelectronic properties. However, their applications are limited by poor stability. Here, we prepared a novel CsPbBr3\/SBA-15 photocatalyst, in which CsPbBr3 nanocrystals (CsPbBr3 NCs) were in situ grown and confined in mesoporous SBA-15. The CsPbBr3\/SBA-15 catalyst demonstrated remarkable reactivity, with turnover number (TON) and turnover frequency (TOF) reaching as high as 9604.8 and 1600.8 h\u20131 in the \u03b1-alkylation of aldehydes, respectively. To the best of our knowledge, these values are the highest ever achieved in a batch reaction system. Moreover, the CsPbBr3 NCs confined in SBA-15 exhibited excellent stability, which survived in a water environment for more than 8 months. Overall, these results demonstrate the successful construction of a highly efficient and stable CsPbBr3\/SBA-15 photocatalyst, offering a promising and robust platform for organic synthesis toward photocatalytic C\u2013C bond formation.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c02071","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:21:02Z","timestamp":1785849662000},"page":"17967-17976","source":"Crossref","is-referenced-by-count":0,"title":["Stable CsPbBr3 Nanocrystals Confined in\nSBA-15 for Photocatalytic C\u2013C Coupling Reactions under Visible\nLight Irradiation"],"prefix":"10.1021","volume":"65","author":[{"given":"Jianyao","family":"Kou","sequence":"first","affiliation":[{"name":"Nanchang University , , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Ji","sequence":"additional","affiliation":[{"name":"Nanchang University , , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Cao","sequence":"additional","affiliation":[{"name":"Nanchang University , , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chun","family":"Li","sequence":"additional","affiliation":[{"name":"Nanchang University , , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingxuan","family":"Xu","sequence":"additional","affiliation":[{"name":"Nanchang University , , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6012-8100","authenticated-orcid":true,"given":"Yuxing","family":"Huang","sequence":"additional","affiliation":[{"name":"Nanchang University , , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7681-819X","authenticated-orcid":true,"given":"Zhuo","family":"Xin","sequence":"additional","affiliation":[{"name":"Nanchang University , , , ,","place":["Nanchang, Jiangxi, China, 330031"]},{"name":"Nanchang University , , , ,","place":["Nanchang, Jiangxi, China, 330031"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,30]]},"reference":[{"issue":"2","key":"2026081008110003300_cit1","doi-asserted-by":"publisher","first-page":"1543","DOI":"10.1021\/acs.chemrev.1c00403","article-title":"Visible light-induced transition\nmetal catalysis","volume":"122","author":"Cheung","year":"2022","journal-title":"Chem. 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Commun."},{"key":"2026081008110003300_cit10","doi-asserted-by":"publisher","first-page":"22563","DOI":"10.1002\/anie.202007520","article-title":"Stereoselective C-C\noxidative coupling reactions photocatalyzed by\nzwitterionic ligand capped CsPbBr3 perovskite quantum dots","volume":"59","author":"Yuan","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"issue":"2","key":"2026081008110003300_cit11","doi-asserted-by":"publisher","first-page":"733","DOI":"10.1021\/jacs.8b08720","article-title":"Lead-halide perovskites\nfor photocatalytic \u03b1-alkylation of aldehydes","volume":"141","author":"Zhu","year":"2019","journal-title":"J. Am. Chem. Soc."},{"issue":"1","key":"2026081008110003300_cit12","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-10634-x","article-title":"Lead halide\nperovskites for photocatalytic organic synthesis","volume":"10","author":"Zhu","year":"2019","journal-title":"Nat. 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Phys."},{"issue":"13","key":"2026081008110003300_cit14","doi-asserted-by":"publisher","first-page":"2057","DOI":"10.1002\/cssc.201800679","article-title":"A CsPbBr3\/TiO2 composite for\nvisible-light-driven photocatalytic\nbenzyl alcohol oxidation","volume":"11","author":"Schu\u0308nemann","year":"2018","journal-title":"ChemSusChem"},{"issue":"4","key":"2026081008110003300_cit15","doi-asserted-by":"publisher","first-page":"1107","DOI":"10.1021\/acsenergylett.0c00058","article-title":"Solar-driven metal halide perovskite photocatalysis:\ndesign, stability, and performance","volume":"5","author":"Huang","year":"2020","journal-title":"ACS Energy\nLett."},{"issue":"2","key":"2026081008110003300_cit16","doi-asserted-by":"publisher","first-page":"1039","DOI":"10.1039\/D5CS00230C","article-title":"Recent advances in\nstable halide\nperovskite nanocrystals for optoelectronic devices, biological imaging,\nand X-Ray detection","volume":"55","author":"Zhu","year":"2026","journal-title":"Chem. 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Mater."},{"key":"2026081008110003300_cit23","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121375","article-title":"Space-confined growth of lead-free\nhalide perovskite Cs3Bi2Br9 in MCM-41\nmolecular sieve as an efficient photocatalyst for CO2 reduction\nat the gas-solid condition under visible light","volume":"310","author":"Cui","year":"2022","journal-title":"Appl. Catal., B"},{"issue":"51","key":"2026081008110003300_cit24","doi-asserted-by":"publisher","first-page":"28128","DOI":"10.1021\/acsami.5b10373","article-title":"Emulsion synthesis of size-tunable CH3NH3PbBr3 quantum dots: an alternative route toward\nefficient light-emitting\ndiodes","volume":"7","author":"Huang","year":"2015","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026081008110003300_cit25","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.153948","article-title":"Merits of\nthe CeLaCuO ternary oxide\nas promoter of the Ni\/SBA-15 catalyst for the dry reforming of methane\nreaction","volume":"496","author":"Hussien","year":"2024","journal-title":"Chem. Eng. J."},{"issue":"11","key":"2026081008110003300_cit26","doi-asserted-by":"publisher","first-page":"6601","DOI":"10.1039\/D4GC00568F","article-title":"In situ growth of an\nultrathin Cu\/g-C3N4 coating\nover SBA-15 for catalytic wet air oxidation of pollutants under extremely\nmild conditions","volume":"26","author":"Yuan","year":"2024","journal-title":"Green Chem."},{"key":"2026081008110003300_cit27","doi-asserted-by":"publisher","first-page":"744","DOI":"10.1016\/j.jcis.2022.08.171","article-title":"Efficient adsorption and reduction\nof Cr(VI) from aqueous solution by santa barbara amorphous-15 (SBA-15)\nsupported Fe\/Ni bimetallic nanoparticles","volume":"629","author":"Xing","year":"2023","journal-title":"J.\nColloid Interface Sci."},{"issue":"16","key":"2026081008110003300_cit28","doi-asserted-by":"publisher","first-page":"6266","DOI":"10.1021\/acs.chemmater.3c00732","article-title":"Stable orthorhombic CsPbBr3 light emitters:\nencapsulation-assisted in situ synthesis","volume":"35","author":"Park","year":"2023","journal-title":"Chem.\nMater."},{"issue":"23","key":"2026081008110003300_cit29","doi-asserted-by":"publisher","first-page":"7236","DOI":"10.1021\/jacs.6b03134","article-title":"Synthesis of composition tunable\nand highly luminescent cesium lead halide nanowires through anion-exchange\nreactions","volume":"138","author":"Zhang","year":"2016","journal-title":"J. Am. Chem. Soc."},{"issue":"11","key":"2026081008110003300_cit30","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202002130","article-title":"Confined synthesis\nof stable and\nuniform CsPbBr3 nanocrystals with high quantum yield up\nto 90% by high temperature solid-state reaction","volume":"9","author":"Zhang","year":"2021","journal-title":"Adv. Opt. Mater."},{"key":"2026081008110003300_cit31","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2024.102817","article-title":"Cycloaddition of limonene epoxide and CO2 over Zn\/SBA-15 catalysts for limonene carbonate synthesis","volume":"83","author":"Mosquera","year":"2024","journal-title":"J. CO2 Util."},{"key":"2026081008110003300_cit32","doi-asserted-by":"publisher","first-page":"5788","DOI":"10.1002\/anie.201915034","article-title":"A supported bismuth halide perovskite photocatalyst\nfor selective aliphatic and aromatic C-H bond activation","volume":"59","author":"Dai","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"issue":"13","key":"2026081008110003300_cit33","doi-asserted-by":"publisher","first-page":"2925","DOI":"10.1039\/C6GC03558B","article-title":"Organic sponge photocatalysis","volume":"19","author":"Li","year":"2017","journal-title":"Green Chem."},{"key":"2026081008110003300_cit34","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2020.105671","article-title":"Enhanced photocatalytic degradation\nand H2\/H2O2 production performance\nof S-pCN\/WO2.72 S-Scheme heterojunction with appropriate\nsurface oxygen vacancies","volume":"81","author":"Li","year":"2021","journal-title":"Nano Energy"},{"key":"2026081008110003300_cit35","doi-asserted-by":"publisher","first-page":"334","DOI":"10.1016\/j.apcatb.2018.12.065","article-title":"Covalent organic framework\nas an efficient, metal-free, heterogeneous photocatalyst for organic\ntransformations under visible light","volume":"245","author":"Li","year":"2019","journal-title":"Appl. Catal.,\nB"},{"issue":"5898","key":"2026081008110003300_cit36","doi-asserted-by":"publisher","first-page":"77","DOI":"10.1126\/science.1161976","article-title":"Merging\nphotoredox catalysis with organocatalysis:\nthe direct asymmetric alkylation of aldehydes","volume":"322","author":"Nicewicz","year":"2008","journal-title":"Science"},{"issue":"3","key":"2026081008110003300_cit37","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202102334","article-title":"Lead-free Cs2AgSbCl6 double perovskite nanocrystals for effective visible-light\nphotocatalytic C-C coupling reactions","volume":"15","author":"Guo","year":"2022","journal-title":"ChemSusChem"},{"issue":"36","key":"2026081008110003300_cit38","doi-asserted-by":"publisher","first-page":"9613","DOI":"10.1002\/anie.201405118","article-title":"Light-driven\norganocatalysis using inexpensive, nontoxic\nBi2O3 as the photocatalyst","volume":"53","author":"Riente","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"issue":"17","key":"2026081008110003300_cit39","doi-asserted-by":"publisher","first-page":"4062","DOI":"10.1002\/anie.201108721","article-title":"Visible-light-promoted\nstereoselective alkylation by\ncombining heterogeneous photocatalysis with organocatalysis","volume":"51","author":"Cherevatskaya","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"issue":"10","key":"2026081008110003300_cit40","doi-asserted-by":"publisher","first-page":"6361","DOI":"10.1039\/D0TA12267J","article-title":"[Fe(Bpy)3]2+-based porous organic polymers with boosted\nphotocatalytic activity\nfor recyclable organic transformations","volume":"9","author":"Liu","year":"2021","journal-title":"J. Mater.\nChem. A"},{"issue":"1","key":"2026081008110003300_cit41","doi-asserted-by":"publisher","first-page":"90","DOI":"10.1021\/acsmacrolett.9b00872","article-title":"Porous Ru(Bpy)32+-linked polymers\nfor recyclable photocatalysis of enantioselective alkylation of aldehydes","volume":"9","author":"Luo","year":"2020","journal-title":"ACS Macro Lett."},{"issue":"36","key":"2026081008110003300_cit42","doi-asserted-by":"publisher","first-page":"18401","DOI":"10.1021\/acs.inorgchem.5c02942","article-title":"Octahedral Cs2AgBiBr6 double perovskite microcrystals\nfor C-C coupling reactions under visible-light irradiation","volume":"64","author":"Ji","year":"2025","journal-title":"Inorg. 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