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Herein, we report on the novel synthesis, solid-state isolation, and pseudocapacitor studies of an atomically precise neutral redox-active Ag4 nanocluster [((Cy-cAI)P(Dipp))4Ag4] (2), supported by the unique bulky \u03bc2-phosphide ligands. Cyclic voltammetry (CV) studies on 2 revealed a possible quasi-reversible one-electron reduction, suggesting in situ generation of the corresponding radical anion 2\u00b7\u2013, which was further supported by the electron paramagnetic resonance (EPR) spectroscopy and Mulliken spin density calculations. The unprecedented effort to fabricate an electrode by depositing 2 on a solid support, investigating the pseudocapacitive behavior in a 1 M NaClO4 electrolyte by employing a three-electrode cell arrangement, was successful. The corresponding CV profiles exhibited a quasi-rectangular profile with redox peaks, signifying a combination of electric double-layer capacitive (EDLC) and pseudocapacitive effects with the highest specific capacitance value of 168.9 F g\u20131 (185.8 mF cm\u20132) at a 2 mV s\u20131 scan rate.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c02414","type":"journal-article","created":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T14:07:22Z","timestamp":1784297242000},"page":"17657-17668","source":"Crossref","is-referenced-by-count":2,"title":["Isolation of a Bridging Phosphide-Supported Redox-Active\nNeutral Ag4-Nanocluster as a Molecular Energy Storage\nMaterial"],"prefix":"10.1021","volume":"65","author":[{"given":"Nivedya K.","family":"Vikas","sequence":"first","affiliation":[{"name":"Indian Institute of Science Education and Research (IISER) Tirupati , , , ,","place":["Tirupati, Andhra Pradesh, India, 517619"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mayur","family":"Thosare","sequence":"additional","affiliation":[{"name":"Visvesvaraya National Institute of Technology , , , ,","place":["Nagpur, Maharashtra, India, 440010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-9154-7102","authenticated-orcid":true,"given":"Sayed Imroz","family":"Hossain","sequence":"additional","affiliation":[{"name":"Indian Institute of Science Education and Research (IISER) Tirupati , , , ,","place":["Tirupati, Andhra Pradesh, India, 517619"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Akshara","family":"Purushothaman","sequence":"additional","affiliation":[{"name":"Indian Institute of Science Education and Research (IISER) Tirupati , , , ,","place":["Tirupati, Andhra Pradesh, India, 517619"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8570-3121","authenticated-orcid":true,"given":"Asutosh","family":"Patra","sequence":"additional","affiliation":[{"name":"Indian Institute of Science Education and Research (IISER) Tirupati , , , ,","place":["Tirupati, Andhra Pradesh, India, 517619"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6740-9607","authenticated-orcid":true,"given":"Ashwath","family":"Kudlu","sequence":"additional","affiliation":[{"name":"Indian Institute of Science Education and Research (IISER) Tirupati , , , ,","place":["Tirupati, Andhra Pradesh, India, 517619"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manasi","family":"Baccha","sequence":"additional","affiliation":[{"name":"Visvesvaraya National Institute of Technology , , , ,","place":["Nagpur, Maharashtra, India, 440010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7464-9633","authenticated-orcid":true,"given":"Babasaheb R.","family":"Sankapal","sequence":"additional","affiliation":[{"name":"Visvesvaraya National Institute of Technology , , , ,","place":["Nagpur, Maharashtra, India, 440010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5883-4329","authenticated-orcid":true,"given":"Sudipta","family":"Roy","sequence":"additional","affiliation":[{"name":"Indian Institute of Science Education and Research (IISER) Tirupati , , , ,","place":["Tirupati, Andhra Pradesh, India, 517619"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,17]]},"reference":[{"issue":"11","key":"2026080308081311300_cit1","doi-asserted-by":"publisher","first-page":"845","DOI":"10.1038\/nmat2297","article-title":"Materials for Electrochemical\nCapacitors","volume":"7","author":"Simon","year":"2008","journal-title":"Nat. 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China Chem."},{"issue":"2","key":"2026080308081311300_cit26","doi-asserted-by":"publisher","first-page":"519","DOI":"10.31635\/ccschem.024.202404301","article-title":"Boosting Circularly Polarized Luminescent\nand Decagram-Scale Mechanochemistry Synthesis of Atomically Precise\nSuperstructure from Achiral Silver Cluster and Chiral Cyclodextrin","volume":"7","author":"Xu","year":"2024","journal-title":"CCS Chem."},{"issue":"10","key":"2026080308081311300_cit27","doi-asserted-by":"publisher","DOI":"10.1016\/j.cjsc.2025.100735","article-title":"Order-by-order Control\nover the Nonlinear Optical Properties of Atomically Precise Nanoclusters","volume":"44","author":"Xu","year":"2025","journal-title":"Chin. J. Struct. 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Optical Mater."},{"issue":"64","key":"2026080308081311300_cit35","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202202324","article-title":"Isolation of Homo-\/Mixed-Valence\nAg12, Ag29, and Ag8 Clusters Stabilized\nby Cyclic Alkyl(Amino) Carbene-Anchored Monoanionic Phosphorus Ligand","volume":"28","author":"Nag","year":"2022","journal-title":"Chem. - Eur. J."},{"key":"2026080308081311300_cit36","doi-asserted-by":"publisher","first-page":"203","DOI":"10.1016\/0022-2860(89)85163-4","article-title":"The Vibrational Spectrum of Trimethylphosphine-Silver\nIodide, [AgI\u00b7P(CH3)3]4","volume":"197","author":"Edwards","year":"1989","journal-title":"J. Mol. Struct."},{"issue":"10","key":"2026080308081311300_cit37","doi-asserted-by":"publisher","first-page":"2876","DOI":"10.1021\/ic50188a039","article-title":"Tri-Tert-Butylphosphine Complexes\nof Silver(I). Preparation, Characterization,\nand Spectral Studies","volume":"17","author":"Goel","year":"1978","journal-title":"Inorg. 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