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However, their practical utilization is severely hindered by poor moisture and thermal stability, especially in the case of manganese-based compounds, which tend to degrade rapidly under humid conditions. To address this challenge, we propose a polyaromatic molecular engineering strategy. By incorporating bulky hydrophobic triazine-derived cations (TNZ-2 and TNZ-3), we successfully synthesized two zero-dimensional Mn2+-based halides, (TNZ-2)2MnBr4 and (TNZ-3)2MnBr4, featuring isolated [MnBr4]2\u2013 tetrahedra. Notably, (TNZ-3)2MnBr4 exhibits significantly enhanced stability under high-humidity conditions (70% relative humidity for 30 days) or even upon immersion in water, and achieves efficient green emission with a photoluminescence quantum yield of 33.11%, benefiting from the strong quantum confinement effect of its zero-dimensional structure. Furthermore, flexible (TNZ-3)2MnBr4@PMMA composite films were fabricated and demonstrated to function effectively in X-ray imaging, highlighting their potential in flexible optoelectronic devices. This work provides a viable molecular design route toward stable and highly luminescent OIMH materials.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c02458","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T14:02:25Z","timestamp":1785852145000},"page":"18789-18799","source":"Crossref","is-referenced-by-count":0,"title":["Conjugated Molecules as Multifunctional Architects:\nBoosting Water Stability and Radiance of Mn-Based Metal Halides for\nFlexible X-ray Scintillation Imaging"],"prefix":"10.1021","volume":"65","author":[{"given":"Jia","family":"Liu","sequence":"first","affiliation":[{"name":"Guangdong University of Petrochemical Technology , , ,","place":["Maoming, People\u2019s Republic of China, 525000"]},{"name":"Guangdong University of Petrochemical Technology , , ,","place":["Maoming, People\u2019s Republic of China, 525000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Yang","sequence":"additional","affiliation":[{"name":"Guangdong University of Petrochemical Technology , , ,","place":["Maoming, People\u2019s Republic of China, 525000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziqing","family":"Liu","sequence":"additional","affiliation":[{"name":"Guangdong University of Petrochemical Technology , , ,","place":["Maoming, People\u2019s Republic of China, 525000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6388-0688","authenticated-orcid":true,"given":"Long","family":"Yu","sequence":"additional","affiliation":[{"name":"Guangdong University of Petrochemical Technology , , ,","place":["Maoming, People\u2019s Republic of China, 525000"]},{"name":"Guangdong University of Petrochemical Technology , , ,","place":["Maoming, People\u2019s Republic of China, 525000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8973-2707","authenticated-orcid":true,"given":"Xin","family":"Li","sequence":"additional","affiliation":[{"name":"Guangdong University of Petrochemical Technology , , ,","place":["Maoming, People\u2019s Republic of China, 525000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqing","family":"Wen","sequence":"additional","affiliation":[{"name":"Guangdong University of Petrochemical Technology , , ,","place":["Maoming, People\u2019s Republic of China, 525000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhizai","family":"Li","sequence":"additional","affiliation":[{"name":"Soochow University , , ,","place":["Suzhou, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9728-0296","authenticated-orcid":true,"given":"Qiangsheng","family":"Zhang","sequence":"additional","affiliation":[{"name":"Hainan University , , ,","place":["Haikou, China, 570228"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8257-4937","authenticated-orcid":true,"given":"Suhua","family":"Wang","sequence":"additional","affiliation":[{"name":"Guangdong University of Petrochemical Technology , , ,","place":["Maoming, People\u2019s Republic of China, 525000"]},{"name":"Guangdong University of Petrochemical Technology , , ,","place":["Maoming, People\u2019s Republic of China, 525000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,31]]},"reference":[{"issue":"9","key":"2026081708305681100_cit1","doi-asserted-by":"publisher","first-page":"637","DOI":"10.1038\/s41566-022-01046-3","article-title":"Ultrastable Near-Infrared Perovskite Light-Emitting Diodes","volume":"16","author":"Guo","year":"2022","journal-title":"Nat. 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