{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T15:00:38Z","timestamp":1785164438537,"version":"3.55.0"},"reference-count":44,"publisher":"American Chemical Society (ACS)","issue":"29","license":[{"start":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T00:00:00Z","timestamp":1784073600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T00:00:00Z","timestamp":1784073600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T00:00:00Z","timestamp":1784073600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22175071"],"award-info":[{"award-number":["22175071"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22425104"],"award-info":[{"award-number":["22425104"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFA1506301"],"award-info":[{"award-number":["2023YFA1506301"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013061","name":"Jilin Provincial Scientific and Technological Development Program","doi-asserted-by":"publisher","award":["20260602006RC"],"award-info":[{"award-number":["20260602006RC"]}],"id":[{"id":"10.13039\/501100013061","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013314","name":"Higher Education Discipline Innovation Project","doi-asserted-by":"publisher","award":["B17020"],"award-info":[{"award-number":["B17020"]}],"id":[{"id":"10.13039\/501100013314","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,27]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Mesoporous metal vanadates (mMVO) are promising visible-light photocatalysts for energy conversion and environmental remediation owing to their suitable band structures, broad visible-light absorption, and excellent chemical stability. However, the controlled synthesis of crystalline mMVO remains challenging, involving the complicated coassembly process and high-temperature crystallization. Herein, we develop a facile polymer-oriented solvent-mediated coassembly strategy to prepare mMVO without additional chelating agents. Using mesoporous InVO4 (mIVO) as a representative example, the ethanol\/water volume ratio is used to tune solvent polarity and thereby regulate the electrostatic coassembly of protonated poly(ethylenimine) (PEI), polyoxovanadate species, and In3+ into compact inorganic\u2013organic composites. Subsequent hydrothermal crystallization and calcination yield mIVO with a well-developed mesoporous framework. This strategy can be extended to synthesize a series of mMVO. Among the obtained samples, mIVO (1\/1), synthesized at an ethanol\/water volume ratio of 1\/1, exhibits excellent visible-light photocatalytic degradation of methylene blue (MB), achieving a degradation efficiency of 97.8% within 40 min under irradiation with \u03bb &amp;gt; 420 nm. Experimental results demonstrate that the enhanced activity originates from the synergistic effects of the accessible mesoporous structure, abundant oxygen vacancies, and efficient separation and transport of photogenerated charge carriers.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c02465","type":"journal-article","created":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T12:52:35Z","timestamp":1784119955000},"page":"17165-17173","source":"Crossref","is-referenced-by-count":0,"title":["A Polymer-Oriented\nSolvent-Mediated Co-Assembly Strategy\nto Mesoporous Metal Vanadates for Photocatalytic Degradation"],"prefix":"10.1021","volume":"65","author":[{"given":"Pingfei","family":"Ma","sequence":"first","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, Jilin, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaqi","family":"Yang","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, Jilin, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ye","family":"Wang","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, Jilin, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiyuan","family":"Feng","sequence":"additional","affiliation":[{"name":"Hunan University , , ,","place":["Changsha, P. R. China, 410082"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lu","family":"Liu","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, Jilin, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Youcai","family":"Zhong","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, Jilin, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5511-1136","authenticated-orcid":true,"given":"Ling","family":"Zhang","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, Jilin, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6064-9360","authenticated-orcid":true,"given":"Zhen-An","family":"Qiao","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, Jilin, P. R. China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,15]]},"reference":[{"issue":"10","key":"2026072710090280700_cit1","doi-asserted-by":"publisher","first-page":"13652","DOI":"10.1021\/acsnano.0c05797","article-title":"Ordered bicontinuous\nmesoporous polymeric semiconductor photocatalyst","volume":"14","author":"Li","year":"2020","journal-title":"ACS Nano"},{"key":"2026072710090280700_cit2","doi-asserted-by":"publisher","first-page":"123","DOI":"10.1016\/j.pmatsci.2018.04.004","article-title":"Recent progress on the characterization of the high-pressure\nbehaviour of AVO4 orthovanadates","volume":"97","author":"Errandonea","year":"2018","journal-title":"Prog. Mater. Sci."},{"key":"2026072710090280700_cit3","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.131145","article-title":"InVO4-based photocatalysts for energy and environmental applications","volume":"428","author":"Yang","year":"2022","journal-title":"Chem. Eng. J."},{"issue":"2","key":"2026072710090280700_cit4","doi-asserted-by":"publisher","first-page":"1254","DOI":"10.1021\/acscatal.5b02015","article-title":"Substrate specificity in photocatalytic\ndegradation of mixtures of\norganic contaminants in water","volume":"6","author":"Roma\u0303o","year":"2016","journal-title":"ACS Catal."},{"issue":"3","key":"2026072710090280700_cit5","doi-asserted-by":"publisher","first-page":"1929","DOI":"10.1021\/acsami.5b10086","article-title":"Tailored\nfabrication of thoroughly mesoporous BiVO4 nanofibers and\ntheir visible-light photocatalytic activities","volume":"8","author":"Liu","year":"2016","journal-title":"ACS Appl. Mater. 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Colloid Interface Sci."},{"issue":"2","key":"2026072710090280700_cit13","doi-asserted-by":"publisher","first-page":"1063","DOI":"10.1021\/acsanm.8b02327","article-title":"General synthesis\nof ordered mesoporous\nrare-earth orthovanadate thin films and their use as photocatalysts\nand phosphors for lighting applications","volume":"2","author":"Reitz","year":"2019","journal-title":"ACS\nAppl. Nano Mater."},{"key":"2026072710090280700_cit14","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtsust.2024.100666","article-title":"A review on versatile metal vanadates\nphotocatalysts for energy conversion and environmental remediation","volume":"25","author":"Ahmad","year":"2024","journal-title":"Mater. 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Energy\nMater."},{"key":"2026072710090280700_cit19","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2019.100915","article-title":"Design of\nmeso\/macro porous 2D Mn-vanadate as potential novel anode materials\nfor sodium-ion storage","volume":"26","author":"Muruganantham","year":"2019","journal-title":"J. Energy Storage"},{"issue":"10","key":"2026072710090280700_cit20","doi-asserted-by":"publisher","first-page":"4209","DOI":"10.1021\/jacs.8b13673","article-title":"Convincing\nsynthesis\nof atomically thin, single-crystalline InVO4 sheets toward\npromoting highly selective and efficient solar conversion of CO2 into CO","volume":"141","author":"Han","year":"2019","journal-title":"J. Am. Chem. 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J."},{"issue":"45","key":"2026072710090280700_cit24","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202404909","article-title":"Modulating\nthe moderate d-band center of indium in InVO4 nanobelts\nby synergizing MnOx and oxygen vacancies for\nhigh-efficiency CO2 photoreduction","volume":"20","author":"Li","year":"2024","journal-title":"Small"},{"issue":"27","key":"2026072710090280700_cit25","doi-asserted-by":"publisher","first-page":"11053","DOI":"10.1002\/anie.202002051","article-title":"Solvent-free\nself-assembly for scalable preparation of highly crystalline mesoporous\nmetal oxides","volume":"59","author":"Xiong","year":"2020","journal-title":"Angew. Chem., Int. 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Eng."},{"issue":"8","key":"2026072710090280700_cit36","doi-asserted-by":"publisher","DOI":"10.26599\/NR.2025.94907653","article-title":"A polymer derived\nbubble templates strategy towards\nperovskite oxides with tunable pore structure and rich surface-active\nsites for boosting aerobic oxidation of benzyl alcohol","volume":"18","author":"Wang","year":"2025","journal-title":"Nano Res."},{"issue":"4","key":"2026072710090280700_cit37","doi-asserted-by":"publisher","first-page":"1952","DOI":"10.31635\/ccschem.025.202506070","article-title":"Low-temperature solid\u2013solid\ninterface crystallization to brick-mortar structured multicomponent\nmesoporous metal oxides for selective photocatalytic oxidation of\naromatic alcohol","volume":"8","author":"Yang","year":"2026","journal-title":"CCS Chem."},{"key":"2026072710090280700_cit38","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.137897","article-title":"Micellar\ninterface modulation self-assembly strategy\ntowards mesoporous bismuth oxychloride-based materials for boosting\nphotocatalytic pharmaceuticals degradation","volume":"450","author":"Li","year":"2022","journal-title":"Chem. 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Mater."},{"key":"2026072710090280700_cit43","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2020.128927","article-title":"Photocatalyst-coated\ncarbon microtube electrodes: Preparation and characterization of their\nproperties and photocatalytic degradation of methylene blue","volume":"267","author":"Xia","year":"2021","journal-title":"Chemosphere"},{"issue":"2","key":"2026072710090280700_cit44","doi-asserted-by":"publisher","first-page":"145","DOI":"10.1016\/S0926-3373(00)00276-9","article-title":"Photocatalytic degradation\npathway of methylene blue\nin water","volume":"31","author":"Houas","year":"2001","journal-title":"Appl. Catal., B"}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.6c02465","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/65\/29\/17165\/65953561\/acs.inorgchem.6c02465.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/65\/29\/17165\/65953561\/acs.inorgchem.6c02465.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T14:17:20Z","timestamp":1785161840000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/inocaj\/article\/65\/29\/17165\/5210684\/A-Polymer-Oriented-Solvent-Mediated-Co-Assembly"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,15]]},"references-count":44,"journal-issue":{"issue":"29","published-online":{"date-parts":[[2026,7,15]]},"published-print":{"date-parts":[[2026,7,27]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.inorgchem.6c02465","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,15]]}}}