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The complexes, [{trans-Ru(dmpe)2(C\u2261CtBu)}2(\u03bc2-C\u2261C(2,6-C10H6)C\u2261C)], [{trans-Ru(dmpe)2(C\u2261CtBu)}2(\u03bc2-C\u2261C(2,7-C10H6)C\u2261C)], and [{trans-Ru(dmpe)2(C\u2261CtBu)}3(\u03bc3-(C\u2261C)3(1,3,5C6H3)], were formed via the metathesis of terminal organic bisacetylenes with the methylruthenium complex, [trans-Ru(dmpe)2(CH3)(C\u2261CtBu)], in the presence of methanol and under mild conditions. Spectroelectrochemical analyses of these species showed that the linearly \u03c0-conjugated 2,6-naphthylene bridge enabled better electronic communication between redox-active ruthenium-acetylide sites than the cross-conjugated 2,7-naphthylene bridge.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c02469","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T23:01:48Z","timestamp":1788476508000},"page":"21563-21571","source":"Crossref","is-referenced-by-count":0,"title":["Electronic\nCommunication in Oxidized Di- and Trinuclear\nRuthenium Acetylide Complexes"],"prefix":"10.1021","volume":"65","author":[{"given":"Surabhi","family":"Naik","sequence":"first","affiliation":[{"name":"UNSW Sydney , , , ,","place":["Sydney, New South Wales, Australia, 2052"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4457-5722","authenticated-orcid":true,"given":"James D.","family":"Watson","sequence":"additional","affiliation":[{"name":"UNSW Sydney , , , ,","place":["Sydney, New South Wales, Australia, 2052"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michelle","family":"Huang","sequence":"additional","affiliation":[{"name":"UNSW Sydney , , , ,","place":["Sydney, New South Wales, Australia, 2052"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sebastian","family":"Devine-Poulos","sequence":"additional","affiliation":[{"name":"UNSW Sydney , , , ,","place":["Sydney, New South Wales, Australia, 2052"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3693-9063","authenticated-orcid":true,"given":"Mohan","family":"Bhadbhade","sequence":"additional","affiliation":[{"name":"UNSW Sydney , , , ,","place":["Sydney, New South Wales, Australia, 2052"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruoming","family":"Tian","sequence":"additional","affiliation":[{"name":"UNSW Sydney , , , ,","place":["Sydney, New South Wales, Australia, 2052"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7319-1464","authenticated-orcid":true,"given":"Hunter J.","family":"Windsor","sequence":"additional","affiliation":[{"name":"UNSW Sydney , , , ,","place":["Sydney, New South Wales, Australia, 2052"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9361-3137","authenticated-orcid":true,"given":"Hsiu L.","family":"Li","sequence":"additional","affiliation":[{"name":"UNSW Sydney , , , ,","place":["Sydney, New South Wales, Australia, 2052"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9057-9444","authenticated-orcid":true,"given":"Martin D.","family":"Peeks","sequence":"additional","affiliation":[{"name":"UNSW Sydney , , , ,","place":["Sydney, New South Wales, Australia, 2052"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5519-5472","authenticated-orcid":true,"given":"Leslie D.","family":"Field","sequence":"additional","affiliation":[{"name":"UNSW Sydney , , , ,","place":["Sydney, New South Wales, Australia, 2052"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,3]]},"reference":[{"issue":"C","key":"2026092108314891900_cit1","doi-asserted-by":"publisher","first-page":"247","DOI":"10.1016\/S0065-2792(08)60179-X","article-title":"Mixed Valence Chemistry-A Survey and Classification","volume":"10","author":"Robin","year":"1968","journal-title":"Adv. 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