{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T03:15:35Z","timestamp":1788405335773,"version":"build-2803163510"},"reference-count":34,"publisher":"American Chemical Society (ACS)","issue":"34","license":[{"start":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T00:00:00Z","timestamp":1787011200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T00:00:00Z","timestamp":1787011200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T00:00:00Z","timestamp":1787011200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["2020LANLE372"],"award-info":[{"award-number":["2020LANLE372"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-AC52-06NA25396"],"award-info":[{"award-number":["DE-AC52-06NA25396"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-SC0023693"],"award-info":[{"award-number":["DE-SC0023693"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-SC0024165"],"award-info":[{"award-number":["DE-SC0024165"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100008902","name":"Los Alamos National Laboratory","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100008902","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,31]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Tris(pyridinediimine)bis(tren) (TPT) was employed as a proligand in reactions with 243Am(NO3)3\u00b7nH2O in methanol generating several product types consistent with observations from analogous reactions with the lanthanide series. [Am(TPT)][Am(NO3)6] (1) was identified along with Am2(TPTOMe)(NO3)3 (2; TPTOMe = tris(pyridineimine)(tren)(tris(methoxylhemiacetalate))) from a reaction using Am(NO3)3\u00b7nH2O. In a second reaction, performed using a modified preparation of Am(NO3)3\u00b7nH2O, Am2(TPTOMe)(NO3)3(MeOH) (2\u00b7MeOH) was identified, where methanol coordinated to the terminal metal site. These results highlight the challenges of relying on lanthanide surrogates for actinide chemistry, and the 243Am products are consistent with both early- and late-lanthanide-like reactivity.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c02489","type":"journal-article","created":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T03:02:25Z","timestamp":1787108545000},"page":"19633-19637","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis Notes on Generating Bimetallic 243Am Complexes Using Inherent Lewis Acidity and the TPT Cryptand"],"prefix":"10.1021","volume":"65","author":[{"given":"Trever M.","family":"Bostelaar","sequence":"first","affiliation":[{"name":"Los Alamos National Laboratory , , ,","place":["Los Alamos, New Mexico, United States, 87544"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1916-5633","authenticated-orcid":true,"given":"Joseph M.","family":"Sperling","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Nuclear Science and Engineering Center , , ,","place":["Golden, Colorado, United States, 80401"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0407-6278","authenticated-orcid":true,"given":"Michael L.","family":"Tarlton","sequence":"additional","affiliation":[{"name":"Los Alamos National Laboratory , , ,","place":["Los Alamos, New Mexico, United States, 87544"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elodie","family":"Dalodie\u0300re","sequence":"additional","affiliation":[{"name":"Los Alamos National Laboratory , , ,","place":["Los Alamos, New Mexico, United States, 87544"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Harrison D.","family":"Root","sequence":"additional","affiliation":[{"name":"Los Alamos National Laboratory , , ,","place":["Los Alamos, New Mexico, United States, 87544"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5208-9129","authenticated-orcid":true,"given":"Cory J.","family":"Windorff","sequence":"additional","affiliation":[{"name":"New Mexico State University , , , ,","place":["Las Cruces, New Mexico, United States, 88005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2989-3311","authenticated-orcid":true,"given":"Thomas E.","family":"Albrecht","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Nuclear Science and Engineering Center , , ,","place":["Golden, Colorado, United States, 80401"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1168-0932","authenticated-orcid":true,"given":"Bonnie E.","family":"Klamm","sequence":"additional","affiliation":[{"name":"Los Alamos National Laboratory , , ,","place":["Los Alamos, New Mexico, United States, 87544"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0440-5497","authenticated-orcid":true,"given":"Aaron","family":"Tondreau","sequence":"additional","affiliation":[{"name":"Los Alamos National Laboratory , , ,","place":["Los Alamos, New Mexico, United States, 87544"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,18]]},"reference":[{"key":"2026090222511081400_cit1","doi-asserted-by":"publisher","first-page":"358","DOI":"10.1016\/j.proche.2012.10.056","article-title":"Main results\nof the French program on partitioning of minor actinides, a significant\nimprovement towards nuclear waste reduction","volume":"7","author":"Poinssot","year":"2012","journal-title":"Procedia Chem."},{"key":"2026090222511081400_cit2","doi-asserted-by":"publisher","first-page":"349","DOI":"10.1016\/j.proche.2012.10.055","article-title":"Recycling the actinides,\nthe cornerstone of any sustainable nuclear fuel cycles","volume":"7","author":"Poinssot","year":"2012","journal-title":"Procedia Chem."},{"issue":"4","key":"2026090222511081400_cit3","doi-asserted-by":"publisher","first-page":"193","DOI":"10.1524\/ract.2010.1708","article-title":"Demonstration of the\nLUCA process\nfor the separation of americium (III) from curium (III), californium\n(III), and lanthanides (III) in acidic solution using a synergistic\nmixture of bis(chlorophenyl) dithiophosphinic acid and tris(2-ethylhexyl)\nphosphate","volume":"98","author":"Modolo","year":"2010","journal-title":"Radiochim. 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