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Herein, we rationally designed and synthesized two asymmetric BF2-curcuminoid AIE photosensitizers (TBT and TBCT) featuring a D1\u2013\u03c0\u2013A\u2013\u03c0\u2013D2 architecture, employing thiophene and methoxy-substituted tetraphenylethene (MTPE) as dual donors\/AIE units, difluoroboron \u03b2-diketonate (BF2bdk) as the acceptor, and styrene\/ethylene as \u03c0-bridges. This asymmetric design effectively separates Frontier molecular orbitals, reduces the singlet\u2013triplet energy gap (\u0394EST), and enhances ISC efficiency. Both photosensitizers exhibit solvent-dependent photophysical properties, high molar extinction coefficients, and excellent AIE performance. Notably, TBCT displays a smaller \u0394EST (0.223 eV) than TBT (0.393 eV), leading to efficient singlet oxygen (1O2) generation, outstanding photostability, and nearly 100% photodynamic eradication of Escherichia coli (E. coli). Collectively, this asymmetric molecular engineering provides a reliable paradigm for high-performance AIE photosensitizers with strong light absorption, efficient 1O2 generation, and bacterial sterilization, showing promise for further exploration in antibacterial applications.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c02852","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T16:04:05Z","timestamp":1786550645000},"page":"19438-19447","source":"Crossref","is-referenced-by-count":0,"title":["Asymmetric\nBF2-Curcuminoid-Based\nAIE Photosensitizers Enable Singlet Oxygen Generation for Specific\nBacterial Eradication"],"prefix":"10.1021","volume":"65","author":[{"given":"Linyu","family":"Zhang","sequence":"first","affiliation":[{"name":"Nanyang Normal University , , ,","place":["Nanyang, P. R. China, 473061"]},{"name":"Luoyang Normal University , , ,","place":["Luoyang, P. R. China, 471934"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongliang","family":"Feng","sequence":"additional","affiliation":[{"name":"Luoyang Normal University , , ,","place":["Luoyang, P. R. China, 471934"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yangyang","family":"Wang","sequence":"additional","affiliation":[{"name":"Luoyang Normal University , , ,","place":["Luoyang, P. R. China, 471934"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuzhu","family":"Zheng","sequence":"additional","affiliation":[{"name":"Luoyang Normal University , , ,","place":["Luoyang, P. R. China, 471934"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinwen","family":"Zhan","sequence":"additional","affiliation":[{"name":"Luoyang Normal University , , ,","place":["Luoyang, P. R. China, 471934"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinkuan","family":"Gong","sequence":"additional","affiliation":[{"name":"Luoyang Normal University , , ,","place":["Luoyang, P. R. China, 471934"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ning","family":"Liu","sequence":"additional","affiliation":[{"name":"Luoyang Normal University , , ,","place":["Luoyang, P. R. China, 471934"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kongyang","family":"Wu","sequence":"additional","affiliation":[{"name":"Luoyang Normal University , , ,","place":["Luoyang, P. R. China, 471934"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2658-2286","authenticated-orcid":true,"given":"Ziyong","family":"Li","sequence":"additional","affiliation":[{"name":"Luoyang Normal University , , ,","place":["Luoyang, P. R. 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