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In this work, two polymorphic Cd-based mixed-ligand MOFs, MOF-J and MOF-A, were synthesized solvothermally using N\u20321,N\u20324-bis((E)-pyridin-4-ylmethylene)terephthalohydrazide (L1) and 4,4\u2032-oxybis(benzene dicarboxylic acid) (H2oba). Their formation was governed by crystallization time, with monoclinic MOF-J representing the kinetically favored phase and triclinic MOF-A the thermodynamically stable phase. Structural analyses by single-crystal and powder X-ray diffraction confirmed their distinct framework architectures. Among the polymorphs, MOF-J exhibited superior multifunctional performance, achieving an iodine vapor adsorption capacity of 606 wt % at 75 \u00b0C within 7 h, along with excellent recyclability and structural stability. Iodine adsorption enhanced its electrical conductivity from 6.84 \u00d7 10\u20139 to 2.46 \u00d7 10\u20134 S m\u20131, attributed to iodine-induced charge transport and band gap reduction. Density functional theory (DFT) calculations revealed strong host\u2013guest interactions responsible for effective iodine confinement. In addition, MOF-J acted as an effective recyclable heterogeneous catalyst for one-pot Knoevenagel\u2013Michael cyclocondensation, affording 2-amino-4H-benzo[b]pyran derivatives in excellent yields under mild conditions. This work highlights time-controlled polymorphism as an effective strategy for designing multifunctional MOFs for iodine capture and heterogeneous catalysis.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c02857","type":"journal-article","created":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T04:01:46Z","timestamp":1786075306000},"page":"19448-19464","source":"Crossref","is-referenced-by-count":0,"title":["Time-Resolved\nPolymorphism in a Cd-MOF with Dual Applications\nin Iodine Adsorption and One-Pot Tandem Knoevenagel\u2013Michael\nCyclocondensation Catalysis"],"prefix":"10.1021","volume":"65","author":[{"given":"Lata","family":"Meena","sequence":"first","affiliation":[{"name":"Indian Institute of Technology Indore , , ,","place":["Indore, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sayantan","family":"Sarkar","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , ,","place":["Indore, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amardeep","family":"Kumar","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , ,","place":["Indore, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9523-6918","authenticated-orcid":true,"given":"Rakesh","family":"Ganguly","sequence":"additional","affiliation":[{"name":"Shiv Nadar Institution of Eminence , Delhi-NCR , ,","place":["Greater Noida, India, 201314"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5729-6189","authenticated-orcid":true,"given":"Maxim L.","family":"Kuznetsov","sequence":"additional","affiliation":[{"name":"Universidade de Lisboa , , Av. Rovisco Pais , ,","place":["Lisbon, Portugal, 1049-001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5314-891X","authenticated-orcid":true,"given":"Suman","family":"Mukhopadhyay","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , ,","place":["Indore, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,6]]},"reference":[{"issue":"4","key":"2026083104351635900_cit1","doi-asserted-by":"publisher","first-page":"1802922","DOI":"10.1002\/adma.201802922","article-title":"Porous Polymers as Multifunctional Material Platforms\ntoward Task-Specific Applications","volume":"31","author":"Wu","year":"2019","journal-title":"Adv. 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