{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T13:25:17Z","timestamp":1786973117029,"version":"build-2736575974"},"reference-count":48,"publisher":"American Chemical Society (ACS)","issue":"32","license":[{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22578191"],"award-info":[{"award-number":["22578191"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004775","name":"Natural Science Foundation of Gansu Province","doi-asserted-by":"publisher","award":["24YFGA002"],"award-info":[{"award-number":["24YFGA002"]}],"id":[{"id":"10.13039\/501100004775","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFA1506804"],"award-info":[{"award-number":["2023YFA1506804"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The oxidative esterification of biomass-derived furfural is a sustainable pathway to value-added chemicals, yet current catalytic systems typically require harsh oxidants and alkali additives, which limit scalability and complicate downstream processing. Herein, a single-atom manganese catalyst (MnSA@CN) with atomically dispersed Mn\u2013N4 sites is fabricated by coordinating Mn2+ with 1,4-diazabicyclo[2.2.2]octane (N(CH2CH2)3N, DABCO), followed by controlled thermal treatment and acid leaching. Under mild, additive-free conditions (90 \u00b0C, ambient-pressure air), MnSA@CN affords quantitative conversion of furfural to methyl furoate with &amp;gt;99% selectivity in a single step. Radical scavenging experiments combined with density functional theory calculations reveal a cooperative activation mechanism: the Mn\u2013N4 sites synergistically activate O2 and furfural, generating methanol-derived hydroxyl radicals that mediate direct C\u2013H oxidation and esterification, thereby bypassing the conventional furoic acid intermediate. This work highlights the pivotal role of isolated Mn\u2013N4 centers in substrate-oxidant coactivation and delivers a scalable, noble-metal-free catalytic platform for sustainable biomass valorization, bridging fundamental single-atom catalysis with practical biorefinery transformations.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c02859","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T22:02:26Z","timestamp":1785967346000},"page":"18948-18958","source":"Crossref","is-referenced-by-count":0,"title":["Atomically\nDispersed Mn Sites Promote O2 Activation for Oxidative\nEsterification of Furfural"],"prefix":"10.1021","volume":"65","author":[{"given":"Wei","family":"Gao","sequence":"first","affiliation":[{"name":"Lanzhou University , , ,","place":["Lanzhou, PR China, 730000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuang","family":"Liu","sequence":"additional","affiliation":[{"name":"Lanzhou University , , ,","place":["Lanzhou, PR China, 730000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunfeng","family":"Zheng","sequence":"additional","affiliation":[{"name":"PetroChina , , ,","place":["Lanzhou, PR China, 730060"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Gao","sequence":"additional","affiliation":[{"name":"Lanzhou University , , ,","place":["Lanzhou, PR China, 730000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhufeng","family":"Lu","sequence":"additional","affiliation":[{"name":"Lanzhou University , , ,","place":["Lanzhou, PR China, 730000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bowen","family":"Shi","sequence":"additional","affiliation":[{"name":"Lanzhou University , , ,","place":["Lanzhou, PR China, 730000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0293-382X","authenticated-orcid":true,"given":"Fang","family":"Niu","sequence":"additional","affiliation":[{"name":"Lanzhou University , , ,","place":["Lanzhou, PR China, 730000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0775-1133","authenticated-orcid":true,"given":"Zhengping","family":"Dong","sequence":"additional","affiliation":[{"name":"Lanzhou University , , ,","place":["Lanzhou, PR China, 730000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,5]]},"reference":[{"key":"2026081708321701800_cit1","doi-asserted-by":"publisher","first-page":"4511","DOI":"10.1021\/acs.chemrev.5c00784","article-title":"Biomass Demineralization: A Critical Need for Future\nBiorefineries","volume":"126","author":"Santiago-Marti\u0301nez","year":"2026","journal-title":"Chem. Rev."},{"key":"2026081708321701800_cit2","doi-asserted-by":"publisher","first-page":"116775","DOI":"10.1016\/j.rser.2026.116775","article-title":"Progress and\nchallenges in thermochemical technologies for biomass humification:\nA comprehensive review","volume":"232","author":"Sarlaki","year":"2026","journal-title":"Renewable Sustainable\nEnergy Rev."},{"key":"2026081708321701800_cit3","doi-asserted-by":"publisher","first-page":"8520","DOI":"10.1021\/acscatal.6c01031","article-title":"Biocatalytic\nUpcycling\nof Biomass via Immobilized Enzymes in Continuous Flow","volume":"16","author":"Wang","year":"2026","journal-title":"ACS Catal."},{"key":"2026081708321701800_cit4","doi-asserted-by":"publisher","first-page":"71","DOI":"10.1016\/S1872-2067(25)64741-3","article-title":"Accurate restricted\ntransition-state shape selective\nhydrogenation of furfural over zeolite confined Cu catalyst","volume":"74","author":"Liang","year":"2025","journal-title":"Chin. J. Catal."},{"key":"2026081708321701800_cit5","doi-asserted-by":"publisher","first-page":"125880","DOI":"10.1016\/j.apcatb.2025.125880","article-title":"One-step valorization of cellulose\nacetate plastic waste into 5-hydroxymethylfurfural","volume":"381","author":"Gong","year":"2026","journal-title":"Appl. Catal., B"},{"key":"2026081708321701800_cit6","doi-asserted-by":"publisher","first-page":"122036","DOI":"10.1016\/j.carbpol.2024.122036","article-title":"Effect of hemicellulose hydrolysate addition on the\ndehydration and redispersion characteristic of cellulose nanofibrils","volume":"334","author":"Kim","year":"2024","journal-title":"Carbohydr. Polym."},{"key":"2026081708321701800_cit7","doi-asserted-by":"publisher","first-page":"877","DOI":"10.1021\/acs.accounts.4c00819","article-title":"Aldehyde-Stabilization Strategies\nfor Building Biobased Consumer Products around Intact lignocellulosic\nStructures","volume":"58","author":"Zheng","year":"2025","journal-title":"Acc. Chem. Res."},{"key":"2026081708321701800_cit8","doi-asserted-by":"publisher","first-page":"1288","DOI":"10.1021\/jacs.1c10908","article-title":"Catalytic Furfural\/5-Hydroxymethyl\nFurfural Oxidation to Furoic Acid\/Furan-2,5-dicarboxylic Acid with\nH2 Production Using Alkaline Water as the Formal Oxidant","volume":"144","author":"Kar","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026081708321701800_cit9","doi-asserted-by":"publisher","first-page":"135257","DOI":"10.1016\/j.fuel.2025.135257","article-title":"Thermochemistry of hydrogen storage: Alkyl furoates\nas sustainable LOHC from renewable sources","volume":"396","author":"Siewert","year":"2025","journal-title":"Fuel"},{"key":"2026081708321701800_cit10","doi-asserted-by":"publisher","first-page":"159","DOI":"10.1007\/s11998-018-0110-3","article-title":"Alkyl 2-furoates obtained\nby green chemistry procedures as suitable new antifoulants for marine\nprotective coatings","volume":"16","author":"Escobar","year":"2019","journal-title":"J. Coat. Technol. Res."},{"key":"2026081708321701800_cit11","doi-asserted-by":"publisher","first-page":"27060","DOI":"10.1039\/D4RA05903D","article-title":"Manganese-catalyzed\noxidation of furfuryl alcohols and furfurals to efficient synthesis\nof furoic acids","volume":"14","author":"Kou","year":"2024","journal-title":"RSC Adv."},{"key":"2026081708321701800_cit12","doi-asserted-by":"publisher","first-page":"107587","DOI":"10.1016\/j.bej.2020.107587","article-title":"Kinetic study\nof lipase-catalyzed esterification of furoic acid to methyl-2-furoate","volume":"161","author":"Zhang","year":"2020","journal-title":"Biochem. Eng. J."},{"key":"2026081708321701800_cit13","doi-asserted-by":"publisher","first-page":"126790","DOI":"10.1016\/j.jhazmat.2021.126790","article-title":"Response of soil protozoa to acid\nmine drainage in a contaminated\nterrace","volume":"421","author":"Xu","year":"2022","journal-title":"J. Hazard. Mater."},{"key":"2026081708321701800_cit14","doi-asserted-by":"publisher","first-page":"147686","DOI":"10.1016\/j.cej.2023.147686","article-title":"A hierarchical\nporous\nN-doped carbon material as catalyst derived from the folic acid-Zn\/KBr\nhydrogel: Reaction network and kinetics and mechanism for the oxidation\nof furfural to maleic acid","volume":"479","author":"Jiao","year":"2024","journal-title":"Chem. Eng. J."},{"key":"2026081708321701800_cit15","doi-asserted-by":"publisher","first-page":"22008","DOI":"10.1021\/jacs.2c09136","article-title":"Surface-Clean Au25 Nanoclusters in Modulated\nMicroenvironment Enabled by Metal\u2013Organic Frameworks for Enhanced\nCatalysis","volume":"144","author":"Wang","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026081708321701800_cit16","doi-asserted-by":"publisher","first-page":"148153","DOI":"10.1016\/j.cej.2023.148153","article-title":"Synergetic oxidative\nesterification of 5-hydroxymethylfurfural using Pd-Au bimetallic nanocomposite\nunder mild conditions","volume":"481","author":"Kumar","year":"2024","journal-title":"Chem. Eng. J."},{"key":"2026081708321701800_cit17","doi-asserted-by":"publisher","first-page":"287","DOI":"10.1016\/j.apcatb.2012.09.035","article-title":"Au\/ZrO2: An efficient and reusable catalyst\nfor the oxidative esterification of renewable furfural","volume":"129","author":"Signoretto","year":"2013","journal-title":"Appl. Catal., B"},{"key":"2026081708321701800_cit18","doi-asserted-by":"publisher","first-page":"106","DOI":"10.1039\/D2IM00045H","article-title":"Hierarchically ordered\nporous carbon\nwith atomically dispersed cobalt for oxidative esterification of furfural","volume":"1","author":"Yao","year":"2023","journal-title":"Ind. Chem. Mater."},{"key":"2026081708321701800_cit19","doi-asserted-by":"publisher","first-page":"1148","DOI":"10.1016\/S1872-2067(17)62841-9","article-title":"High-efficiency oxidative esterification\nof furfural to methylfuroate with a non-precious metal Co-N-C\/MgO\ncatalyst","volume":"38","author":"Huo","year":"2017","journal-title":"Chin. J. Catal."},{"key":"2026081708321701800_cit20","doi-asserted-by":"publisher","first-page":"6565","DOI":"10.1021\/acscatal.4c01035","article-title":"Nitrogen, Sulfur Co-doped Hollow\nCarbon-Encapsulated Cu\/Co2P for Selective Oxidation Esterification\nof Furfurals","volume":"14","author":"Dong","year":"2024","journal-title":"ACS Catal."},{"key":"2026081708321701800_cit21","doi-asserted-by":"publisher","first-page":"6406","DOI":"10.1021\/acscatal.0c05497","article-title":"Adsorption Configuration-Determined\nSelective Hydrogenative Ring Opening and Ring Rearrangement of Furfural\nover Metal Phosphate","volume":"11","author":"Tong","year":"2021","journal-title":"ACS Catal."},{"key":"2026081708321701800_cit22","doi-asserted-by":"publisher","first-page":"126668","DOI":"10.1016\/j.apcatb.2026.126668","article-title":"Surface-enriched Mn\nsingle-atom radical\nscavengers enable dual enhancement of activity and stability in Fe-N-C\nORR catalysts","volume":"391","author":"Wang","year":"2026","journal-title":"Appl. Catal., B"},{"key":"2026081708321701800_cit23","doi-asserted-by":"publisher","first-page":"4053","DOI":"10.1021\/acscatal.6c00407","article-title":"Nitrogen Coordination\nEngineering in Co\u2013N4 Single-Atom Catalysts: Distinct\nRoles of Pyridinic and Pyrrolic Coordination in Regulating Reactive\nOxygen Species Generation","volume":"16","author":"Ye","year":"2026","journal-title":"ACS Catal."},{"key":"2026081708321701800_cit24","doi-asserted-by":"publisher","first-page":"807","DOI":"10.1016\/j.jechem.2026.04.039","article-title":"N-bridged Zn-Ni dual-site\nsingle-atom catalysts: Steering cascade transfer hydrogenation via\nsite-specific synergy","volume":"118","author":"Zhang","year":"2026","journal-title":"J. Energy Chem."},{"key":"2026081708321701800_cit25","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202419630","article-title":"Sabatier Optimal of\nMn-N4 Single Atom Catalysts for Selective Oxidative Desulfurization","volume":"64","author":"Ye","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081708321701800_cit26","doi-asserted-by":"publisher","first-page":"12005","DOI":"10.1021\/jacs.9b04569","article-title":"Single-Atom\nMn\u2013N4 Site-Catalyzed Peroxone Reaction for the Efficient\nProduction of Hydroxyl Radicals in an Acidic Solution","volume":"141","author":"Guo","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"2026081708321701800_cit27","doi-asserted-by":"publisher","first-page":"2897","DOI":"10.1016\/j.joule.2019.09.015","article-title":"Transforming Energy with Single-Atom Catalysts","volume":"3","author":"Ding","year":"2019","journal-title":"Joule"},{"key":"2026081708321701800_cit28","doi-asserted-by":"publisher","first-page":"10207","DOI":"10.1021\/acscatal.6c00872","article-title":"Versatile and Robust\nNickel Single Atom Catalysts","volume":"16","author":"Burnside","year":"2026","journal-title":"ACS Catal."},{"key":"2026081708321701800_cit29","doi-asserted-by":"publisher","first-page":"217829","DOI":"10.1016\/j.ccr.2026.217829","article-title":"From isolated\natoms to active sites: The rise of heterogenous single-atom catalysts","volume":"559","author":"Beniwal","year":"2026","journal-title":"Coord. Chem. Rev."},{"key":"2026081708321701800_cit30","doi-asserted-by":"publisher","first-page":"102424","DOI":"10.1016\/j.jcou.2023.102424","article-title":"Triethylenetetramine-impregnated ZIF-8 nanoparticles\nfor CO2 adsorption","volume":"69","author":"Mohammadi","year":"2023","journal-title":"J. CO2 Util."},{"key":"2026081708321701800_cit31","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202516438","article-title":"Direct\nAir Capture\nand Photoconversion of CO 2 to Ethylene by Defect-Tailored Cu 3 -Based\nMetal\u2013Organic Frameworks","volume":"65","author":"He","year":"2026","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026081708321701800_cit32","doi-asserted-by":"publisher","first-page":"101089","DOI":"10.1016\/j.pmatsci.2023.101089","article-title":"Raman spectroscopy\nof carbon materials and their composites: Graphene, nanotubes and\nfibres","volume":"135","author":"Li","year":"2023","journal-title":"Prog. Mater. Sci."},{"key":"2026081708321701800_cit33","doi-asserted-by":"publisher","first-page":"388","DOI":"10.1016\/j.carbon.2016.06.017","article-title":"A multi wavelength\nRaman scattering study of defective graphitic carbon materials: The\nfirst order Raman spectra revisited","volume":"107","author":"Couzi","year":"2016","journal-title":"Carbon"},{"key":"2026081708321701800_cit34","doi-asserted-by":"publisher","first-page":"4012","DOI":"10.1021\/acscatal.2c06340","article-title":"Marriage of Ultralow Platinum and\nSingle-Atom MnN4 Moiety for Augmented ORR and HER Catalysis","volume":"13","author":"Gong","year":"2023","journal-title":"ACS Catal."},{"key":"2026081708321701800_cit35","doi-asserted-by":"publisher","first-page":"126129","DOI":"10.1016\/j.seppur.2023.126129","article-title":"Efficient activation\nof peroxymonosulfate by Mn single-atom: Critical role of Mn-N4 coordination\nfor generating singlet oxygen","volume":"335","author":"Jia","year":"2024","journal-title":"Sep. Purif. Technol."},{"key":"2026081708321701800_cit36","doi-asserted-by":"publisher","first-page":"16698","DOI":"10.1021\/acscatal.4c06021","article-title":"Single-Atom\nManganese-Based Catalysts for the Oxidative Dehydrogenation of Propane","volume":"14","author":"Byron","year":"2024","journal-title":"ACS Catal."},{"key":"2026081708321701800_cit37","doi-asserted-by":"publisher","first-page":"115278","DOI":"10.1016\/j.watres.2019.115278","article-title":"Periodate activation with manganese oxides for sulfanilamide\ndegradation","volume":"169","author":"Du","year":"2020","journal-title":"Water Res."},{"key":"2026081708321701800_cit38","doi-asserted-by":"publisher","first-page":"1048","DOI":"10.1080\/1536383X.2020.1794851","article-title":"A review on C1s XPS-spectra\nfor some\nkinds of carbon materials","volume":"28","author":"Chen","year":"2020","journal-title":"Fullerenes, Nanotubes\nCarbon Nanostruct."},{"key":"2026081708321701800_cit39","doi-asserted-by":"publisher","first-page":"5443","DOI":"10.1021\/acs.nanolett.0c01925","article-title":"Engineering Isolated\nMn\u2013N2C2 Atomic Interface Sites for Efficient\nBifunctional Oxygen Reduction and Evolution Reaction","volume":"20","author":"Shang","year":"2020","journal-title":"Nano Lett."},{"key":"2026081708321701800_cit40","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202315032","article-title":"Single-Atom Manganese-Catalyzed\nOxygen\nEvolution Drives the Electrochemical Oxidation of Silane to Silanol","volume":"63","author":"Tang","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081708321701800_cit41","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202314933","article-title":"Potential\nDominates Structural Recombination of Single Atom Mn Sites for Promoting\nOxygen Reduction Reaction","volume":"62","author":"Tong","year":"2023","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026081708321701800_cit42","doi-asserted-by":"publisher","first-page":"10796","DOI":"10.1007\/s12274-023-5859-8","article-title":"The d-orbital regulation\nof isolated\nmanganese sites for enhanced oxygen evolution","volume":"16","author":"Bai","year":"2023","journal-title":"Nano Res."},{"key":"2026081708321701800_cit43","doi-asserted-by":"publisher","first-page":"389","DOI":"10.1038\/s41929-026-01513-y","article-title":"Iron-based single-atom catalysts\nfor selective ammoxidation of C(sp3)\u2013H bonds and\noxidative C\u2013C cleavage reactions","volume":"9","author":"Ma","year":"2026","journal-title":"Nat.\nCatal."},{"key":"2026081708321701800_cit44","doi-asserted-by":"publisher","first-page":"116586","DOI":"10.1016\/j.jcat.2025.116586","article-title":"Crucial role of surface\nhydroxyl in Au\/CaCO3-Al2O3-HT catalyst\nfor base-free oxidative esterification of furfural","volume":"453","author":"Li","year":"2026","journal-title":"J. Catal."},{"key":"2026081708321701800_cit45","doi-asserted-by":"publisher","first-page":"3280","DOI":"10.1039\/D0RA09945G","article-title":"Oxidative\nesterification of renewable furfural on cobalt dispersed on ordered\nporous nitrogen-doped carbon","volume":"11","author":"Yin","year":"2021","journal-title":"RSC Adv."},{"key":"2026081708321701800_cit46","doi-asserted-by":"publisher","first-page":"123857","DOI":"10.1016\/j.jhazmat.2020.123857","article-title":"Excellent\nvisible light responsive photocatalytic behavior of N-doped TiO2 toward decontamination of organic pollutants","volume":"403","author":"Huang","year":"2021","journal-title":"J. Hazard. Mater."},{"key":"2026081708321701800_cit47","doi-asserted-by":"publisher","first-page":"179","DOI":"10.2478\/s11696-006-0033-9","article-title":"The \u03b2-carotene dilemma: ESR study with coordinated peroxyl\nradicals","volume":"60","author":"Tka\u0301c\u030c","year":"2006","journal-title":"Chem. Pap."},{"key":"2026081708321701800_cit48","doi-asserted-by":"publisher","first-page":"12634","DOI":"10.1021\/acs.est.6c00461","article-title":"Are We Truly Accurately\nQuantifying HO\u2022 Using Benzoic Acid Hydroxylation in Engineered\nHO\u2022-Producing Systems?","volume":"60","author":"Zheng","year":"2026","journal-title":"Environ. Sci.\nTechnol."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.6c02859","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/65\/32\/18948\/66419582\/acs.inorgchem.6c02859.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/65\/32\/18948\/66419582\/acs.inorgchem.6c02859.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T12:36:11Z","timestamp":1786970171000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/inocaj\/article\/65\/32\/18948\/5246563\/Atomically-Dispersed-Mn-Sites-Promote-O2"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,5]]},"references-count":48,"journal-issue":{"issue":"32","published-online":{"date-parts":[[2026,8,5]]},"published-print":{"date-parts":[[2026,8,17]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.inorgchem.6c02859","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,5]]}}}