{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:44:39Z","timestamp":1792784679734,"version":"4.5.0"},"reference-count":31,"publisher":"American Chemical Society (ACS)","issue":"37","license":[{"start":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T00:00:00Z","timestamp":1788739200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T00:00:00Z","timestamp":1788739200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T00:00:00Z","timestamp":1788739200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["25-12-00028"],"award-info":[{"award-number":["25-12-00028"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS-2020-NR049601"],"award-info":[{"award-number":["RS-2020-NR049601"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Lomonosov Moscow State University Program of Development","id":[{"id":"https:\/\/ror.org\/010pmpe69","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The evolution of magnetic properties in molybdenum chloride systems caused by structural motif changes was investigated by magnetic property measurements and DFT calculations. In \u03be-MoCl5, characterized by the presence of molybdenum dimers, the formation of ferromagnetic (FM) order is observed at T1 = 12.4 K and its additional transformation at T2 = 2.6 K. The influence of the electronic structure on the FM state was studied by substituting Nb5+ and Re5+ for Mo5+. Replacing half the Mo5+(4d1) cations with Re5+(5d2) leads to the formation of a ferrimagnetically ordered state below TNRe1 = 3.8 K and its additional transformation below TNRe2 = 2.6 K in Re0.5Mo0.5Cl5. In contrast, introducing Nb5+(4d0) suppresses a long-range order formation in Nb0.5Mo0.5Cl5. The PCl4MoCl6 compound containing isolated MoCl6\u2013 octahedral anions exhibits transition to a long-range ferrimagnetic order below TNPCl4 = 4.2 K.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c03423","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T09:02:03Z","timestamp":1788771723000},"page":"21956-21964","source":"Crossref","is-referenced-by-count":0,"title":["Effect of\nStructural Motif on Magnetic Properties\nin Molybdenum Chlorides of Mo5+ Ions: Ferromagnetism from\nMo2Cl10 Dimers and Antiferromagnetism from Isolated\nMoCl6\u2013 Anions"],"prefix":"10.1021","volume":"65","author":[{"given":"Anna A.","family":"Vorobyova","sequence":"first","affiliation":[{"name":"Lomonosov Moscow State University , , ,","place":["Moscow, Russia, 119991"]},{"name":"Higher School of Economics , ,","place":["Moscow, Russia, 101000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3385-5801","authenticated-orcid":true,"given":"Tatyana M.","family":"Vasilchikova","sequence":"additional","affiliation":[{"name":"Lomonosov Moscow State University , , ,","place":["Moscow, Russia, 119991"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-7121-2963","authenticated-orcid":true,"given":"Oleg D.","family":"Gontar","sequence":"additional","affiliation":[{"name":"Lomonosov Moscow State University , , ,","place":["Moscow, Russia, 119991"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander I.","family":"Boltalin","sequence":"additional","affiliation":[{"name":"Lomonosov Moscow State University , , ,","place":["Moscow, Russia, 119991"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Igor V.","family":"Morozov","sequence":"additional","affiliation":[{"name":"Lomonosov Moscow State University , , ,","place":["Moscow, Russia, 119991"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Konstantin A.","family":"Lyssenko","sequence":"additional","affiliation":[{"name":"Lomonosov Moscow State University , , ,","place":["Moscow, Russia, 119991"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0855-2251","authenticated-orcid":true,"given":"Daniil M.","family":"Ivanov","sequence":"additional","affiliation":[{"name":"Saint Petersburg State University , , 7\/9 Universitetskaya Nab. , ,","place":["Saint Petersburg, Russia, 199034"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Denis G.","family":"Golovanov","sequence":"additional","affiliation":[{"name":"Lomonosov Moscow State University , , ,","place":["Moscow, Russia, 119991"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0414-4768","authenticated-orcid":true,"given":"Hongcheng","family":"Lu","sequence":"additional","affiliation":[{"name":"Huazhong University of Science and Technology , , ,","place":["Wuhan, China, 430074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2220-1124","authenticated-orcid":true,"given":"Myung-Hwan","family":"Whangbo","sequence":"additional","affiliation":[{"name":"North Carolina State University , , , ,","place":["Raleigh, North Carolina, United States, 27695-8204"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9232-8289","authenticated-orcid":true,"given":"Hyun-Joo","family":"Koo","sequence":"additional","affiliation":[{"name":"Kyung Hee University , , ,","place":["Seoul, Republic of Korea, 02447"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7853-4801","authenticated-orcid":true,"given":"Olga S.","family":"Volkova","sequence":"additional","affiliation":[{"name":"Lomonosov Moscow State University , , ,","place":["Moscow, Russia, 119991"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,7]]},"reference":[{"key":"2026092108520689000_cit1","doi-asserted-by":"publisher","first-page":"1921","DOI":"10.1002\/ejoc.201600025","article-title":"MoV Reagents in Organic Synthesis","volume":"2016","author":"Schubert","year":"2016","journal-title":"Eur. 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Chem."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.6c03423","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/65\/37\/21956\/68401079\/acs.inorgchem.6c03423.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/65\/37\/21956\/68401079\/acs.inorgchem.6c03423.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T13:26:03Z","timestamp":1789997163000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/inocaj\/article\/65\/37\/21956\/5422222\/Effect-of-Structural-Motif-on-Magnetic-Properties"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,7]]},"references-count":31,"journal-issue":{"issue":"37","published-online":{"date-parts":[[2026,9,7]]},"published-print":{"date-parts":[[2026,9,21]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.inorgchem.6c03423","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,7]]}}}