{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T14:11:39Z","timestamp":1790604699026,"version":"4.1.0"},"reference-count":58,"publisher":"American Chemical Society (ACS)","issue":"38","license":[{"start":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T00:00:00Z","timestamp":1789344000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T00:00:00Z","timestamp":1789344000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T00:00:00Z","timestamp":1789344000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22307102"],"award-info":[{"award-number":["22307102"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22477100"],"award-info":[{"award-number":["22477100"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22577100"],"award-info":[{"award-number":["22577100"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100015401","name":"Key Research and Development Projects of Shaanxi Province","doi-asserted-by":"publisher","award":["2024GH-ZDXM-22"],"award-info":[{"award-number":["2024GH-ZDXM-22"]}],"id":[{"id":"10.13039\/501100015401","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100015401","name":"Key Research and Development Projects of Shaanxi Province","doi-asserted-by":"publisher","award":["2025SF-YBXM-400"],"award-info":[{"award-number":["2025SF-YBXM-400"]}],"id":[{"id":"10.13039\/501100015401","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Shaanxi Fundamental Science Research Project for Chemistry and Biology","award":["23JHQ039"],"award-info":[{"award-number":["23JHQ039"]}]},{"name":"Technology Innovation Leading Program of Shaanxi","award":["2024QCY-KXJ-142"],"award-info":[{"award-number":["2024QCY-KXJ-142"]}]},{"name":"Technology Innovation Leading Program of Shaanxi","award":["2025QCY-KXJ-124"],"award-info":[{"award-number":["2025QCY-KXJ-124"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Tetracycline hydrochloride is a common aquatic contaminant and poses significant risks to environmental and human health. However, developing high-performance removal materials with good recyclability remains a challenge. The electron-deficient benzothiadiazole linker endowed these frameworks with visible-light absorption capability, while lanthanide nodes regulated ligand\u2013metal electronic coupling and graphene oxide-mediated interfacial charge transfer, creating efficient photocatalyst composites (Ln-MOFs\/GO) for TC degradation. The graphene oxide loading was optimized to obtain Ho\/10-GO, which achieved 84.6% degradation of 10 ppm tetracycline (TC) hydrochloride within 40 min under visible-light irradiation after dark adsorption equilibrium had been reached. Encapsulating the composite in sodium alginate gel maintained a high pollutant removal rate over 15 catalytic cycles and enabled simple material recovery. Mechanistic studies combining radical-trapping tests and DMPO-based EPR measurements confirmed the generation of \u2022O2\u2013 and indicated that the O2\/electron-mediated pathway plays a key role in TC degradation. Structure\u2013property analysis showed that the photocatalytic performance results from the visible-light-responsive benzothiadiazole units and the formation of type II heterojunctions, which improve photogenerated carrier separation. Ho\/10-GO@Alg was also applied to visible-light-driven condensation\u2013cyclization synthesis of benzothiazole derivatives. This research provides an effective strategy for TC degradation and offers insights into treating TC contaminants in aquatic environments.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c03424","type":"journal-article","created":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T19:01:31Z","timestamp":1789412491000},"page":"22616-22630","source":"Crossref","is-referenced-by-count":0,"title":["Multistrategy\nOptimization of Benzothiadiazole-Based\nLn-MOF Composites for Enhanced Photocatalytic Degradation of Tetracycline"],"prefix":"10.1021","volume":"65","author":[{"given":"Shuai","family":"Yan","sequence":"first","affiliation":[{"name":"Northwest University , , , ,","place":["Xi\u2019an, Shaanxi, China, 710127"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenjia","family":"Yang","sequence":"additional","affiliation":[{"name":"Northwest University , , , ,","place":["Xi\u2019an, Shaanxi, China, 710127"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xusheng","family":"Li","sequence":"additional","affiliation":[{"name":"Northwest University , , , ,","place":["Xi\u2019an, Shaanxi, China, 710127"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5483-7493","authenticated-orcid":true,"given":"Mengyao","family":"She","sequence":"additional","affiliation":[{"name":"Northwest University , , , ,","place":["Xi\u2019an, Shaanxi, China, 710127"]},{"name":"Northwest University , , , ,","place":["Xi\u2019an, Shaanxi, China, 710069"]},{"name":"Northwest University , , , ,","place":["Yulin, Shaanxi, China, 719099"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8778-3199","authenticated-orcid":true,"given":"Ping","family":"Liu","sequence":"additional","affiliation":[{"name":"Northwest University , , , ,","place":["Xi\u2019an, Shaanxi, China, 710127"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4853-7961","authenticated-orcid":true,"given":"Jian-Li","family":"Li","sequence":"additional","affiliation":[{"name":"Northwest University , , , ,","place":["Xi\u2019an, Shaanxi, China, 710127"]},{"name":"Northwest University , , , ,","place":["Yulin, Shaanxi, China, 719099"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,14]]},"reference":[{"issue":"4","key":"2026092809223661900_cit1","doi-asserted-by":"publisher","DOI":"10.1136\/jitc-2023-008334","article-title":"Tetracyclines enhance antitumor T-cell immunity via the Zap70 signaling\npathway","volume":"12","author":"Tone","year":"2024","journal-title":"J. Immunothe. Cancer"},{"key":"2026092809223661900_cit2","doi-asserted-by":"publisher","first-page":"1590","DOI":"10.1016\/j.scitotenv.2018.08.371","article-title":"Bioconcentration,\nmetabolism and the effects of tetracycline on multiple biomarkers\nin larvae","volume":"649","author":"Xie","year":"2019","journal-title":"Sci. Total Environ."},{"key":"2026092809223661900_cit3","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2019.136086","article-title":"Biochar-induced\nmigration of tetracycline and the alteration of microbial community\nin agricultural soils","volume":"706","author":"Liu","year":"2020","journal-title":"Sci. Total Environ."},{"key":"2026092809223661900_cit4","doi-asserted-by":"publisher","first-page":"48","DOI":"10.1016\/j.cbpa.2016.03.011","article-title":"Development of a\nplatform. for the discovery and practical\nsynthesis of new tetracycline antibiotics","volume":"32","author":"Liu","year":"2016","journal-title":"Curr.\nOpin. Chem. Biol."},{"key":"2026092809223661900_cit5","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2025.178959","article-title":"Unraveling tetracycline\nand its degradation product: Induction mechanisms of antibiotic resistance\nin Escherichia coli","volume":"970","author":"Guo","year":"2025","journal-title":"Sci. Total Environ."},{"issue":"24","key":"2026092809223661900_cit6","doi-asserted-by":"publisher","first-page":"8208","DOI":"10.1039\/D5QI01205H","article-title":"In situ construction of hierarchical\nultrasmall MOF aerogels with tunable mesopores for selective adsorption\nand efficient catalysis","volume":"12","author":"Fang","year":"2025","journal-title":"Inorg. Chem. Front."},{"key":"2026092809223661900_cit7","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.159260","article-title":"Multi-Strategy optimized\nUiO-66 composite for simultaneous efficient adsorption and visible-light\ndegradation of tetracycline in wastewater","volume":"505","author":"Fu","year":"2025","journal-title":"Chem.\nEng. J."},{"issue":"5","key":"2026092809223661900_cit8","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2023.108903","article-title":"A nonradical oxidation\nprocess initiated by Ti-peroxo complex showed high specificity toward\nthe degradation of tetracycline antibiotics","volume":"35","author":"Peng","year":"2024","journal-title":"Chin. Chem. Lett."},{"issue":"9","key":"2026092809223661900_cit9","doi-asserted-by":"publisher","first-page":"4862","DOI":"10.1021\/acsanm.5c00429","article-title":"Flower-like\nTiO Nanostructures Coated with FeO Nanoparticles as Magnetic Ohmic\nHeterojunctions for the Photocatalytic Selective Oxidative Coupling\nof Primary Amines and Degradation of Tetracycline","volume":"8","author":"Li","year":"2025","journal-title":"ACS Appl. Nano Mater."},{"key":"2026092809223661900_cit10","doi-asserted-by":"publisher","first-page":"650","DOI":"10.1016\/j.jcis.2024.04.127","article-title":"Simultaneous\nphotocatalytic removal of tetracycline and hexavalent chromium by\nBiVO4\/0.6CdS photocatalyst: Insights into the performance,\nevaluation, calculation and mechanism","volume":"667","author":"Zheng","year":"2024","journal-title":"J. Colloid\nInterface Sci."},{"key":"2026092809223661900_cit11","doi-asserted-by":"publisher","DOI":"10.1016\/j.actphy.2025.100190","article-title":"Interfacial engineering of Cd0.5Zn0.5S\/BiOBr S-scheme heterojunction\nwith oxygen vacancies for effective photocatalytic antibiotic removal","volume":"41","author":"Ma","year":"2025","journal-title":"Acta Phys.-Chim. Sin."},{"key":"2026092809223661900_cit12","doi-asserted-by":"publisher","first-page":"265","DOI":"10.1016\/j.jmst.2025.05.011","article-title":"Manipulating interfacial\ncharge redistribution in Mn0. 5Cd0. 5S\/N-rich C3N5 S-scheme heterojunction\nfor high-performance photocatalytic removal of emerging contaminants","volume":"243","author":"Ma","year":"2026","journal-title":"J. Mater. Sci. Technol."},{"key":"2026092809223661900_cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.162782","article-title":"3D spongy porous g-CN material synthesized\nby supramolecular self-assembly for efficient degradation of tetracycline","volume":"513","author":"Bai","year":"2025","journal-title":"Chem. Eng. J."},{"issue":"10","key":"2026092809223661900_cit14","doi-asserted-by":"publisher","first-page":"4077","DOI":"10.1021\/acs.cgd.3c01547","article-title":"Solvent-Assisted\nLinker Exchange to Fabricate Pyrene-Modified MIL-125(Ti) for Enhancing\nthe Visible-Light-Driven Generation of Reactive Oxygen Species","volume":"24","author":"Su","year":"2024","journal-title":"Cryst. Growth Des."},{"issue":"2","key":"2026092809223661900_cit15","doi-asserted-by":"publisher","first-page":"564","DOI":"10.1039\/D5QI01658D","article-title":"The transformation\nof a bimetal carboxylate-MOF into a phosphonate-based MOF as a multifunctional\nphotocatalyst","volume":"13","author":"Cao","year":"2026","journal-title":"Inorg. Chem. Front."},{"issue":"9","key":"2026092809223661900_cit16","doi-asserted-by":"publisher","first-page":"3521","DOI":"10.1039\/D4QI03324H","article-title":"Isomorphic BODIPY-based\nmetal\u2013organic frameworks\nfor high-efficiency photoredox organic transformations","volume":"12","author":"Nie","year":"2025","journal-title":"Inorg. Chem. Front."},{"key":"2026092809223661900_cit17","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.124615","article-title":"Peculiar\nsynergetic effect of \u03b3-FeO\nnanoparticles and graphene oxide on MIL-53 (Fe) for boosting photocatalysis","volume":"390","author":"Wu","year":"2020","journal-title":"Chem. Eng. J."},{"key":"2026092809223661900_cit18","doi-asserted-by":"publisher","first-page":"471","DOI":"10.1016\/j.jcis.2024.04.195","article-title":"Facile synthesis of\nMOF-808\/RGO-based 3D macroscopic aerogel for\nenhanced photoreduction CO","volume":"668","author":"Song","year":"2024","journal-title":"J. Colloid Interface\nSci."},{"issue":"2","key":"2026092809223661900_cit19","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416286","article-title":"Emission\nLibrary and Applications of 2,1,3-Benzothiadiazole\nand Its Derivative-Based Luminescent Metal-Organic Frameworks","volume":"64","author":"Han","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"issue":"18","key":"2026092809223661900_cit20","doi-asserted-by":"publisher","first-page":"5973","DOI":"10.1039\/D4QI01368A","article-title":"Visible-light-active\nbenzothiadiazole-based MOFs as efficient ROS generators for the synthesis\nof benzimidazoles and benzothiazoles","volume":"11","author":"Liu","year":"2024","journal-title":"Inorg.\nChem. Front."},{"issue":"2","key":"2026092809223661900_cit21","doi-asserted-by":"publisher","first-page":"3244","DOI":"10.1021\/acsami.2c22571","article-title":"Noncentrosymmetric\nLanthanide-Based MOF Materials Exhibiting Strong SHG Activity and\nNIR Luminescence of Er3+: Application in Nonlinear Optical\nThermometry","volume":"15","author":"Runowski","year":"2023","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"13","key":"2026092809223661900_cit22","doi-asserted-by":"publisher","first-page":"4058","DOI":"10.1039\/D2DT03606A","article-title":"A 2D Dy-based metal\u2013organic\nframework derived from benzothiadiazole: structure and photocatalytic\nproperties","volume":"52","author":"Zhu","year":"2023","journal-title":"Dalton Trans."},{"issue":"15","key":"2026092809223661900_cit23","doi-asserted-by":"publisher","first-page":"2031","DOI":"10.1002\/asia.202100482","article-title":"Selective Photocatalytic Oxidation\nof Sulfides in Lanthanide Metal-Organic Frameworks Incorporating Ru\n(2, 2\u2032-bpy) 3 photosensitizer","volume":"16","author":"Zhang","year":"2021","journal-title":"Chem.\nAsian J."},{"issue":"46","key":"2026092809223661900_cit24","doi-asserted-by":"publisher","first-page":"23040","DOI":"10.1021\/acs.inorgchem.5c04407","article-title":"Eu-MOF and Bifunctional AgI@ Eu-MOF Composite for Fluorescence Sensing\nand Photocatalytic Degradation of Tetracycline","volume":"64","author":"Xing","year":"2025","journal-title":"Inorg. Chem."},{"key":"2026092809223661900_cit25","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2019.122011","article-title":"Benzothiadiazole functionalized Co-doped\nMIL-53-NH with electron\ndeficient units for enhanced photocatalytic degradation of bisphenol\nA and ofloxacin under visible light","volume":"387","author":"Lv","year":"2020","journal-title":"J. Hazard.\nMater."},{"issue":"30","key":"2026092809223661900_cit26","doi-asserted-by":"publisher","first-page":"11866","DOI":"10.1021\/acs.inorgchem.2c01619","article-title":"Fabrication\nof two Isomorphic and Hyperstable Rare\nEarth-based metal\u2013Organic frameworks with efficient Ratiometric\nProbe and Photocatalytic performances","volume":"61","author":"Tan","year":"2022","journal-title":"Inorg.\nChem."},{"key":"2026092809223661900_cit27","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2024.135031","article-title":"GO@MIL-53(Fe)\nadsorption-photocatalytic synergistic degradation of tetracycline","volume":"702","author":"Li","year":"2024","journal-title":"Colloids Surf. A"},{"key":"2026092809223661900_cit28","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2024.133947","article-title":"Facile fabrication of graphene oxide\nand rare earth based metal organic frameworks decorated alginate and\nchitosan biopolymeric hybrid materials for defluoridation studies","volume":"276","author":"Jeyaseelan","year":"2024","journal-title":"Int. J. Biol. Macromol."},{"key":"2026092809223661900_cit29","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2023.171757","article-title":"Synthesis\nof Ta2O5 by introducing graphene quantum dot\nwith excellent photocatalytic performance for degradation of tetracycline","volume":"968","author":"Li","year":"2023","journal-title":"J. Alloys  Compd."},{"issue":"29","key":"2026092809223661900_cit30","doi-asserted-by":"publisher","first-page":"10473","DOI":"10.1039\/D2TC01949C","article-title":"Enhanced luminescence in multivariate metal\u2013organic\nframeworks\nthrough an isolated-ligand strategy","volume":"10","author":"Jiang","year":"2022","journal-title":"J. Mater.\nChem. C"},{"key":"2026092809223661900_cit31","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121820","article-title":"Direct Z-scheme Bi2MoO6\/UiO-66-NH2 heterojunctions for\nenhanced photocatalytic degradation of ofloxacin and ciprofloxacin\nunder visible light","volume":"318","author":"Su","year":"2022","journal-title":"Appl. Catal.,  B"},{"issue":"42","key":"2026092809223661900_cit32","doi-asserted-by":"publisher","first-page":"17182","DOI":"10.1021\/acs.inorgchem.3c02212","article-title":"Incorporating\na D\u2013A\u2013D-Type Benzothiadiazole\nPhotosensitizer into MOFs for Photocatalytic Oxidation of Phenylsulfides\nand Benzylamines","volume":"62","author":"Li","year":"2023","journal-title":"Inorg. Chem."},{"issue":"23","key":"2026092809223661900_cit33","doi-asserted-by":"publisher","first-page":"3054","DOI":"10.1039\/D4CE00324A","article-title":"Accelerating interfacial\ncharge transfer and photocatalytic activity of a Z-scheme Zn-MOF\/GO\nheterojunction towards the removal of Cr(VI) and methylene blue","volume":"26","author":"Chen","year":"2024","journal-title":"CrystEngComm"},{"key":"2026092809223661900_cit34","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.127638","article-title":"3D monolithic composites TiO2\/HKUST-1\/RGO@melamine foam\nwith improved surface mass transfer for efficient photocatalytic degradation\nof toluene gas","volume":"347","author":"Chen","year":"2024","journal-title":"Sep. Purif. Technol."},{"key":"2026092809223661900_cit35","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2021.110948","article-title":"Copper benzene-1,\n3, 5-tricarboxylate (HKUST-1)\u2013graphene\noxide pellets for methane adsorption","volume":"316","author":"Doma\u0301n","year":"2021","journal-title":"Microporous\nMesoporous Mater."},{"key":"2026092809223661900_cit36","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2022.111825","article-title":"Meso\/microporous\nMOF@\ngraphene oxide composite aerogels prepared by generic supercritical\nCO2 technology","volume":"335","author":"Borra\u0301s","year":"2022","journal-title":"Microporous  Mesoporous\nMater."},{"issue":"12","key":"2026092809223661900_cit37","doi-asserted-by":"publisher","first-page":"4609","DOI":"10.1039\/D2EN00809B","article-title":"Enhanced adsorption and synergistic\nphotocatalytic degradation of tetracycline by MOF-801\/GO composites\nvia solvothermal synthesis","volume":"9","author":"Wu","year":"2022","journal-title":"Environ. Sci.: Nano"},{"issue":"13","key":"2026092809223661900_cit38","doi-asserted-by":"publisher","first-page":"7058","DOI":"10.1039\/D1TA10493D","article-title":"Acoustotemplating:\nrapid synthesis of freestanding quasi-2D MOF\/graphene oxide heterostructures\nfor supercapacitor applications","volume":"10","author":"Ehrnst","year":"2022","journal-title":"J. Mater. Chem.\nA"},{"issue":"5","key":"2026092809223661900_cit39","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2024.113823","article-title":"Anchoring\nof Mono\/bimetallic ZIFs onto amine-functionalized GO hybrid nanocomposite:\nA green approach and its pseudo-first order catalytic role for the\nremoval of water pollutants","volume":"12","author":"Prasannan","year":"2024","journal-title":"J. Environ. Chem.\nEng."},{"key":"2026092809223661900_cit40","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2023.125583","article-title":"Cooperative\nreinforcement of photocatalysis-coupled capacitive deionization in\nfructose intercalated MoS2 for removal of tetracycline","volume":"331","author":"Li","year":"2024","journal-title":"Sep. Purif. Technol."},{"key":"2026092809223661900_cit41","doi-asserted-by":"publisher","first-page":"337","DOI":"10.1016\/j.apcatb.2019.03.054","article-title":"Highly efficient\nvisible-light-driven photocatalytic degradation of VOCs by CO2-assisted synthesized mesoporous carbon confined mixed-phase\nTiO2 nanocomposites derived from MOFs","volume":"250","author":"Liu","year":"2019","journal-title":"Appl. Catal. B Environ."},{"key":"2026092809223661900_cit42","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2019.213146","article-title":"The chemical\nconsequences of the gradual decrease of the ionic radius along the\nLn-series","volume":"406","author":"Peters","year":"2020","journal-title":"Coord. Chem. Rev."},{"key":"2026092809223661900_cit43","doi-asserted-by":"publisher","first-page":"9245","DOI":"10.1039\/D4CS01148A","article-title":"Lanthanide\n(iii)-binding peptides\nand proteins: coordination properties and applications","volume":"54","author":"Falcone","year":"2025","journal-title":"Chem. Soc. Rev."},{"issue":"24","key":"2026092809223661900_cit44","doi-asserted-by":"publisher","first-page":"16248","DOI":"10.1039\/D3RA02803H","article-title":"A novel N\u2013P heterojunction Bi2S3\/ZnCo2O4 photocatalyst for boosting\nvisible-light-driven photocatalytic performance toward indigo carmine","volume":"13","author":"Mai Tho","year":"2023","journal-title":"RSC Adv."},{"key":"2026092809223661900_cit45","doi-asserted-by":"publisher","first-page":"1052","DOI":"10.1016\/j.jcis.2024.08.032","article-title":"A novel Bi12O17Cl2\/GO\/Co3O4 Z-type heterojunction\nphotocatalyst with ZIF-67 derivative modified\nfor highly efficient degradation of antibiotics under visible light","volume":"677","author":"Lu","year":"2025","journal-title":"J. Colloid Interface Sci."},{"key":"2026092809223661900_cit46","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.148646","article-title":"MOF derived MnFeO supported on carbon\ncloth as electrochemical anode\nfor peroxymonosulfate electro-activation and persistent organic pollutants\ndegradation","volume":"481","author":"Zhang","year":"2024","journal-title":"Chem. Eng. J."},{"key":"2026092809223661900_cit47","doi-asserted-by":"publisher","first-page":"159227","DOI":"10.1016\/j.apsusc.2023.159227","article-title":"Efficient removal\nof tetracycline from MOF-on-MOF heterojunctions\ndriven by visible light: Evaluation of photocatalytic mechanisms and\ndegradation pathway","volume":"651","author":"Gao","year":"2024","journal-title":"Appl. Surf. Sci."},{"issue":"31","key":"2026092809223661900_cit48","doi-asserted-by":"publisher","first-page":"13415","DOI":"10.1021\/jacs.0c02371","article-title":"Preparation\nof Highly Porous Metal-Organic Framework\nBeads for Metal Extraction from Liquid Streams","volume":"142","author":"Yang","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"2026092809223661900_cit49","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.131462","article-title":"Co-doped magnetic\nN-TiO\/rGO heterojunction@cellulose nanofibrous flakelet for enhanced\nphotocatalytic oxidation and facile separation: Efficient charge separation\nand self-floatability","volume":"425","author":"Cai","year":"2021","journal-title":"Chem. Eng. J."},{"key":"2026092809223661900_cit50","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtsust.2024.100998","article-title":"Graphene oxide-containing\nchitosan@HKUST-1 beads with increased chemical stability for CO2 capture","volume":"28","author":"Khadiri","year":"2024","journal-title":"Mater. Today Sustain."},{"issue":"3","key":"2026092809223661900_cit51","doi-asserted-by":"publisher","first-page":"359","DOI":"10.1016\/j.nanoms.2024.04.015","article-title":"Synthesis\nof binary and ternary MOF\/carbon based composites\n(MOF\/carbon nitride\/graphene oxide) for the visible-light assisted\ndestruction of tetracycline and textile dye","volume":"7","author":"Mahmoodi","year":"2025","journal-title":"Nano. Mater. Sci."},{"issue":"10","key":"2026092809223661900_cit52","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2023.108562","article-title":"Robust chromophore-integrated\nMOFs\nas highly visible-white-light active and tunable size-selective photocatalysts\ntowards benzothiazoles","volume":"34","author":"Liu","year":"2023","journal-title":"Chin. Chem. Lett."},{"key":"2026092809223661900_cit53","doi-asserted-by":"publisher","first-page":"156","DOI":"10.1016\/j.jcat.2017.01.014","article-title":"Visible-light-induced\ntandem reaction of o-aminothiophenols and alcohols to benzothiazoles\nover Fe-based MOFs: Influence of the structure elucidated by transient\nabsorption spectroscopy","volume":"349","author":"Wang","year":"2017","journal-title":"J. Catal."},{"issue":"6","key":"2026092809223661900_cit54","doi-asserted-by":"publisher","first-page":"190","DOI":"10.1007\/s42114-023-00771-9","article-title":"Z-scheme\nmetal organic framework@graphene oxide composite photocatalysts with\nenhanced photocatalytic degradation of tetracycline","volume":"6","author":"Tang","year":"2023","journal-title":"Adv. Compos. Hybrid Mater."},{"key":"2026092809223661900_cit55","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2023.169391","article-title":"Self-assembled synthesis of recyclable\ng-C3N4\/NH2-MIL-53(Fe) aerogel for\nenhanced photocatalytic degradation\nof organic pollutants","volume":"946","author":"He","year":"2023","journal-title":"J. Alloys Compd."},{"key":"2026092809223661900_cit56","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.122150","article-title":"BiOBr\/MXene\/gC3N4 Z-scheme heterostructure photocatalysts mediated\nby oxygen vacancies and MXene quantum dots for tetracycline degradation:\nProcess, mechanism and toxicity analysis","volume":"323","author":"Gao","year":"2023","journal-title":"Appl.\nCatal. B Environ."},{"key":"2026092809223661900_cit57","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123225","article-title":"Magnetic field facilitated\nelectrocatalytic degradation of tetracycline in wastewater by magnetic\nporous carbonized phthalonitrile resin","volume":"340","author":"Zeng","year":"2024","journal-title":"Appl.\nCatal. B Environ."},{"key":"2026092809223661900_cit58","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2023.139188","article-title":"Plant tannin foam anchored iron nanoparticles:\nEfficient and recyclable\ndegradation of tetracycline antibiotics under high salt conditions","volume":"426","author":"Jia","year":"2023","journal-title":"J. Clean. Prod."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.6c03424","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/65\/38\/22616\/68504000\/acs.inorgchem.6c03424.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/65\/38\/22616\/68504000\/acs.inorgchem.6c03424.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T13:49:27Z","timestamp":1790603367000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/inocaj\/article\/65\/38\/22616\/5429631\/Multistrategy-Optimization-of-Benzothiadiazole"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,14]]},"references-count":58,"journal-issue":{"issue":"38","published-online":{"date-parts":[[2026,9,14]]},"published-print":{"date-parts":[[2026,9,28]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.inorgchem.6c03424","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,14]]}}}