{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T12:55:15Z","timestamp":1791204915518,"version":"4.1.0"},"reference-count":52,"publisher":"American Chemical Society (ACS)","issue":"39","license":[{"start":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:00:00Z","timestamp":1789948800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:00:00Z","timestamp":1789948800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:00:00Z","timestamp":1789948800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>High color purity remains a critical limitation in deep-blue phosphorescent materials. The origin of ultranarrow emission (10\u201314 nm) in trans-(NHC)2Pt(C\u2261C\u2013C\u2261C\u2013R)2 complexes (Pt-TMS, R = TMS; Pt-Ph, R = Ph) is elucidated through a symmetry-guided vibronic coupling analysis. Direction-dependent Pt\u2013ligand donation interaction, reinforced by the trans effect, localizes the excitation on the butadiynyl ligand (Bdiy) and confines the T1\u2192S0 transition dipole moment to the x-axis. Under C2V symmetry constraints, vibronic coupling becomes strongly mode-selective, yielding a dominant 0\u20130 emission character. In Pt-TMS, \u03c3\u2013\u03c0 isolation induces vibrational mode decoupling, preserving the low-frequency TMS rotational modes with large displacements, which generate vibrational focusing and enable Franck\u2013Condon (FC) activity, while symmetry suppresses Herzberg\u2013Teller (HT) contributions, minimizing vibronic broadening. In Pt-Ph, \u03c0-conjugation reduces out-of-plane phenyl vibrational displacements that are symmetry-allowed for HT coupling, leading to vibrational confinement that suppresses HT-induced spectral broadening and maintains narrowband emission. Moreover, vibrational focusing in Pt-TMS enhances both radiative and nonradiative decay rates, whereas vibrational confinement in Pt-Ph suppresses structural relaxation and internal conversion. These results identify vibrational focusing and vibrational confinement as complementary mechanisms underlying vibronic regulation in ultranarrowband phosphorescent emitters.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c03486","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T13:02:37Z","timestamp":1789995757000},"page":"23188-23198","source":"Crossref","is-referenced-by-count":0,"title":["Symmetry-Selective\nFranck\u2013Condon and Herzberg\u2013Teller\nCoupling Enables Ultra-Narrow Blue Phosphorescence in Pt(II) Complexes"],"prefix":"10.1021","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-8297-952X","authenticated-orcid":true,"given":"Cong","family":"Zhang","sequence":"first","affiliation":[{"name":"Nanjing Tech University , , , ,","place":["Nanjing, Jiangsu, China, 210009"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-1344-2643","authenticated-orcid":true,"given":"Wenhuan","family":"Wang","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , , ,","place":["Nanjing, Jiangsu, China, 210009"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3097-1268","authenticated-orcid":true,"given":"Xiao-chun","family":"Hang","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , , ,","place":["Nanjing, Jiangsu, China, 210009"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,21]]},"reference":[{"key":"2026100508081377400_cit1","doi-asserted-by":"publisher","first-page":"216374","DOI":"10.1016\/j.ccr.2024.216374","article-title":"Pt(II) complexes\nwith tetradentate ligands: Toward commercially applicable blue organic\nelectroluminescence devices","volume":"526","author":"You","year":"2025","journal-title":"Coord. 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