{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:43:16Z","timestamp":1792784596817,"version":"4.5.0"},"reference-count":49,"publisher":"American Chemical Society (ACS)","issue":"37","license":[{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22276100"],"award-info":[{"award-number":["22276100"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22304086"],"award-info":[{"award-number":["22304086"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Key Laboratory of Control Technology and Standard for Agro-product Safety Quality"},{"name":"Foundation of State Key Laboratory of Analytical Chemistry for Life Science","award":["SKLACLS2509"],"award-info":[{"award-number":["SKLACLS2509"]}],"id":[{"id":"https:\/\/ror.org\/01xnz3256","id-type":"ROR","asserted-by":"crossref"}]},{"name":"Ministry of Agriculture and Rural Affair Key Laboratory of Control Technology and Standard for Agro-product Safety and Quality"},{"name":"Innovation Fund for Agricultural Science and Technology of Jiangsu Province","award":["CX(24)3036"],"award-info":[{"award-number":["CX(24)3036"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Organophosphorus pesticides (OPs) are widely used agrochemicals that pose health risks through irreversible acetylcholinesterase (AChE) inhibition, necessitating reliable detection. Herein, we report an electrochemiluminescence (ECL) biosensor based on Pd\u2013Pt nanoflowers (Pd\u2013Pt NFs) for diazinon detection, powered by oxygen reduction reaction (ORR). Driven by galvanic replacement, cubic Pd templates evolve into Pd@Pt nanodendrites and finally fully alloyed Pd\u2013Pt NFs. Benefiting from the nanoflower geometry and the ligand effect-modulated Pt d-band center, the catalyst delivers exceptional ORR activity. On this basis, an ORR-mediated ECL signal transduction strategy is proposed. Diazinon inhibits AChE, reducing thiocholine (TCh) generation from acetylthiocholine (ATCh); the thiol-bearing TCh selectively poisons ORR-active sites of Pd\u2013Pt NFs, quenching the ECL signal in a concentration-dependent manner. Experimental and theoretical results verify the strong TCh adsorption affinity on the Pd\u2013Pt alloy surface. The biosensor achieves a detection limit of 2.7 pg mL\u20131 toward diazinon, alongside favorable selectivity, reproducibility, and reliable recoveries in real samples. Moreover, the platform was extended to flexible hydrogel-integrated electrodes for in situ cleaning and degradation monitoring. This work demonstrates that galvanic replacement-tuned Pd\u2013Pt NFs, coupling ORR catalysis with coreactant-free ECL, offer a versatile strategy for OPs biosensing.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c04089","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T20:34:29Z","timestamp":1788467669000},"page":"22162-22170","source":"Crossref","is-referenced-by-count":0,"title":["Galvanic Replacement-Driven\nStructural Evolution of\nPd\u2013Pt Alloy Nanoflowers with Modulated d-Band Center\nfor Electrochemiluminescence Biosensing of Organophosphates"],"prefix":"10.1021","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8934-7195","authenticated-orcid":true,"given":"Yue","family":"Cao","sequence":"first","affiliation":[{"name":"Nanjing University of Posts & Telecommunications (NJUPT) , , ,","place":["Nanjing, PR China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fu","family":"Wang","sequence":"additional","affiliation":[{"name":"Nanjing University of Posts & Telecommunications (NJUPT) , , ,","place":["Nanjing, PR China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoyuan","family":"Song","sequence":"additional","affiliation":[{"name":"Nanjing University of Posts & Telecommunications (NJUPT) , , ,","place":["Nanjing, PR China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yating","family":"Wang","sequence":"additional","affiliation":[{"name":"Nanjing University of Posts & Telecommunications (NJUPT) , , ,","place":["Nanjing, PR China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-8654-5134","authenticated-orcid":true,"given":"Ru","family":"Wu","sequence":"additional","affiliation":[{"name":"Nanjing University , , ,","place":["Nanjing, PR China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-7015-7640","authenticated-orcid":true,"given":"Tingting","family":"Han","sequence":"additional","affiliation":[{"name":"Jiangsu Academy of Agricultural Sciences , , ,","place":["Nanjing, China, 210014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenlei","family":"Zhu","sequence":"additional","affiliation":[{"name":"Nanjing University , , ,","place":["Nanjing, PR China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Zhou","sequence":"additional","affiliation":[{"name":"Nanjing University of Posts & Telecommunications (NJUPT) , , ,","place":["Nanjing, PR China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,3]]},"reference":[{"key":"2026092108270041700_cit1","doi-asserted-by":"publisher","first-page":"1284","DOI":"10.1021\/acs.analchem.5c04795","article-title":"Electrochemical detection of organophosphates\nusing dual-modal enzyme-based biosensors","volume":"98","author":"Johnson","year":"2026","journal-title":"Anal.\nChem."},{"key":"2026092108270041700_cit2","doi-asserted-by":"publisher","first-page":"20640","DOI":"10.1021\/acs.analchem.6c03222","article-title":"From poisoning to signal transduction:\nd-band modulated Au@RuPt nanozyme for oxygen reduction reaction inhibition-based\ndetection of organophosphates","volume":"98","author":"Cao","year":"2026","journal-title":"Anal. Chem."},{"key":"2026092108270041700_cit3","doi-asserted-by":"publisher","first-page":"118451","DOI":"10.1016\/j.trac.2025.118451","article-title":"Combatting organophosphate\ntoxicity: Novel strategies for detection, analysis, and sensor development\nfor public health protection","volume":"193","author":"Gupta","year":"2025","journal-title":"TrAC, Trends Anal.\nChem."},{"key":"2026092108270041700_cit4","doi-asserted-by":"publisher","first-page":"130777","DOI":"10.1016\/j.jhazmat.2023.130777","article-title":"Sn\/MoC@NC hollow nanospheres\nas Schottky catalyst for highly sensitive electrochemical detection\nof methyl parathion","volume":"447","author":"Li","year":"2023","journal-title":"J. Hazard. Mater."},{"key":"2026092108270041700_cit5","doi-asserted-by":"publisher","first-page":"118595","DOI":"10.1016\/j.bios.2026.118595","article-title":"Explainable artificial intelligence-enhanced dual-mode\nelectrochemical\nsensor for online monitoring of dimethoate","volume":"304","author":"Wang","year":"2026","journal-title":"Biosens. Bioelectron."},{"key":"2026092108270041700_cit6","doi-asserted-by":"publisher","first-page":"116845","DOI":"10.1016\/j.bios.2024.116845","article-title":"Two-dimensional photonic\ncrystal acetylcholinesterase hydrogel and organohydrogel sensors for\nefficient detection of organophosphorus compounds","volume":"267","author":"Zhao","year":"2025","journal-title":"Biosens. Bioelectron."},{"key":"2026092108270041700_cit7","doi-asserted-by":"publisher","first-page":"145702","DOI":"10.1016\/j.foodchem.2025.145702","article-title":"Sensitive\ndetection of diazinon and bioaccumulation monitoring in crops enabled\nby cu-sealed metal-organic framework nanosystem with target-responsive\naggregation-induced emission","volume":"493","author":"Tang","year":"2025","journal-title":"Food Chem."},{"key":"2026092108270041700_cit8","doi-asserted-by":"publisher","first-page":"114654","DOI":"10.1016\/j.microc.2025.114654","article-title":"Nanoarchitectured novel\nNiZn2O4@CQD electrocatalyst for real-time electrochemical detection\nof diazinon pesticide","volume":"216","author":"Akash","year":"2025","journal-title":"Microchem. J."},{"key":"2026092108270041700_cit9","doi-asserted-by":"publisher","first-page":"2137","DOI":"10.1039\/D5AN00288E","article-title":"Strategic engineering of CoS2\/ZnIn2S4 heterostructures incorporating\nAr plasma-induced sulfur vacancies\nfor potentiating electrocatalytic activity in furazolidone determination","volume":"150","author":"Cao","year":"2025","journal-title":"Analyst"},{"key":"2026092108270041700_cit10","doi-asserted-by":"publisher","first-page":"125121","DOI":"10.1016\/j.talanta.2023.125121","article-title":"Different sized gold\nnanoparticles for array-based sensing of pesticides and its application\nfor strawberry pollution monitoring","volume":"267","author":"Abdali","year":"2024","journal-title":"Talanta"},{"key":"2026092108270041700_cit11","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202517919","article-title":"Enhanced recognition via defect engineered\namorphous metal-organic framework for sensitive and stable pesticide\nbiosensor","volume":"13","author":"Su","year":"2026","journal-title":"Adv. Sci."},{"key":"2026092108270041700_cit12","doi-asserted-by":"publisher","first-page":"11658","DOI":"10.1021\/acs.analchem.8b03250","article-title":"Metallic transition\nmetal dichalcogenide nanosheets as an effective and biocompatible\ntransducer for electrochemical detection of pesticide","volume":"90","author":"Zhao","year":"2018","journal-title":"Anal. Chem."},{"key":"2026092108270041700_cit13","doi-asserted-by":"publisher","first-page":"111452","DOI":"10.1016\/j.bios.2019.111452","article-title":"An acetylcholinesterase\nbiosensor based on doping Au\nnanorod@SiO2 nanoparticles into TiO2-chitosan\nhydrogel for detection of organophosphate pesticides","volume":"141","author":"Cui","year":"2019","journal-title":"Biosens. Bioelectron."},{"key":"2026092108270041700_cit14","doi-asserted-by":"publisher","first-page":"2611","DOI":"10.1016\/j.bios.2010.04.028","article-title":"Acetylcholinesterase\nbiosensor based on Prussian blue-modified electrode\nfor detecting organophosphorous pesticides","volume":"25","author":"Sun","year":"2010","journal-title":"Biosens. Bioelectron."},{"key":"2026092108270041700_cit15","doi-asserted-by":"publisher","first-page":"117443","DOI":"10.1016\/j.trac.2023.117443","article-title":"Progress,\nenhancement mechanisms and applications of electrochemiluminescence\nand photoluminescence metal nanoclusters","volume":"170","author":"Guo","year":"2024","journal-title":"TrAC,\nTrends Anal. Chem."},{"key":"2026092108270041700_cit16","doi-asserted-by":"publisher","first-page":"20240047","DOI":"10.1360\/nso\/20240047","article-title":"Pulsed electrochemistry: A pathway\nto enhanced electrocatalysis and sustainable electrosynthesis","volume":"3","author":"Chen","year":"2024","journal-title":"Natl. Sci. Open"},{"key":"2026092108270041700_cit17","doi-asserted-by":"publisher","first-page":"2203005","DOI":"10.1002\/adfm.202203005","article-title":"A bioinspired photocatalysis\nand electrochemiluminescence scaffold for simultaneous degradation\nand in situ evaluation","volume":"32","author":"Cao","year":"2022","journal-title":"Adv. Funct. Mater."},{"key":"2026092108270041700_cit18","doi-asserted-by":"publisher","first-page":"8927","DOI":"10.1039\/D2DT00810F","article-title":"Recent\nprogress of metal nanoclusters in electrochemiluminescence","volume":"51","author":"Cao","year":"2022","journal-title":"Dalton Trans."},{"key":"2026092108270041700_cit19","doi-asserted-by":"publisher","first-page":"7","DOI":"10.53941\/nenp.2026.100007","article-title":"Electrochemiluminescence sensing\nfor food freshness detection","volume":"2","author":"Wu","year":"2026","journal-title":"Nano-electrochem.\nNano-photochem."},{"key":"2026092108270041700_cit20","doi-asserted-by":"publisher","first-page":"485","DOI":"10.1021\/cbmi.5c00105","article-title":"Recent proceedings of advanced electrochemiluminescence imaging technology\nand applications in accurate analysis","volume":"4","author":"Sehar","year":"2026","journal-title":"Chem.\nBiomed. Imaging"},{"key":"2026092108270041700_cit21","doi-asserted-by":"publisher","first-page":"37","DOI":"10.1007\/s40820-023-01249-5","article-title":"Advances of electrochemical\nand electrochemiluminescent sensors based on covalent organic frameworks","volume":"16","author":"Cao","year":"2024","journal-title":"Nano-Micro Lett."},{"key":"2026092108270041700_cit22","doi-asserted-by":"publisher","first-page":"108753","DOI":"10.1016\/j.cclet.2023.108753","article-title":"Coupling WO3\u2013x dots-encapsulated\nmetal-organic frameworks and template-free branched polymerization\nfor dual signal-amplified electrochemiluminescence biosensing","volume":"35","author":"Yin","year":"2024","journal-title":"Chin. Chem. Lett."},{"key":"2026092108270041700_cit23","doi-asserted-by":"publisher","first-page":"8916","DOI":"10.1039\/D4CC03145H","article-title":"Oxygen electrocatalysis-driven electrochemiluminescence\nby hierarchical\ncarbon nanoflower-supported copper-modulated cobalt sulfide for cytosensing","volume":"60","author":"Cao","year":"2024","journal-title":"Chem. Commun."},{"key":"2026092108270041700_cit24","doi-asserted-by":"publisher","first-page":"5141","DOI":"10.1021\/acs.analchem.5c08008","article-title":"Deprotonation-Driven\nAssembly of Copper Nanoclusters Boosts Electrochemiluminescence\nfor Sensitive N-Acetyl-beta-d-glucosaminidase Biosensing","volume":"98","author":"Sun","year":"2026","journal-title":"Anal. Chem."},{"key":"2026092108270041700_cit25","doi-asserted-by":"publisher","first-page":"3","DOI":"10.53941\/nenp.2025.100003","article-title":"Graphene Quantum\nDots: Synthesis, Properties, and Applications\nin Electroanalysis","volume":"1","author":"Geng","year":"2025","journal-title":"Nano-electrochem. Nano-photochem."},{"key":"2026092108270041700_cit26","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202312053","article-title":"Ligand-induced assembly of copper\nnanoclusters with enhanced electrochemical excitation and radiative\ntransition for electrochemiluminescence","volume":"62","author":"Sun","year":"2023","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026092108270041700_cit27","doi-asserted-by":"publisher","first-page":"4","DOI":"10.53941\/nenp.2026.100004","article-title":"CRISPR\/Cas Powered Electrochemiluminescence\nBiosensing","volume":"2","author":"Xiang","year":"2026","journal-title":"Nano-electrochem. Nano-photochem."},{"key":"2026092108270041700_cit28","doi-asserted-by":"publisher","first-page":"3534","DOI":"10.1002\/anie.201914643","article-title":"Single-atom iron boosts\nelectrochemiluminescence","volume":"59","author":"Gu","year":"2020","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026092108270041700_cit29","doi-asserted-by":"publisher","first-page":"12197","DOI":"10.1021\/jacs.4c02986","article-title":"Regulating reactive\noxygen species over M-N-C single-atom catalysts for potential-resolved\nelectrochemiluminescence","volume":"146","author":"Zhou","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"2026092108270041700_cit30","doi-asserted-by":"publisher","first-page":"7741","DOI":"10.1021\/jacs.2c00865","article-title":"Identifying luminol electrochemiluminescence at the\ncathode via single-atom catalysts tuned oxygen reduction reaction","volume":"144","author":"Xia","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026092108270041700_cit31","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202521284","article-title":"Engineering Pt-Ni alloy coral nanoclusters\nwith efficient oxygen reduction: Enabling endogenous oxygen-mediated\nsustainable electrochemiluminescence for breast cancer diagnosis","volume":"36","author":"Cao","year":"2026","journal-title":"Adv. Funct. Mater."},{"key":"2026092108270041700_cit32","doi-asserted-by":"publisher","first-page":"850","DOI":"10.1126\/science.aaw7493","article-title":"Engineering bunched\nPt-Ni alloy nanocages\nfor efficient oxygen reduction in practical fuel cells","volume":"366","author":"Tian","year":"2019","journal-title":"Science"},{"key":"2026092108270041700_cit33","doi-asserted-by":"publisher","first-page":"11262","DOI":"10.1021\/jacs.1c05856","article-title":"Hydrogen-intercalation-induced\nlattice expansion of Pd@Pt core-shell\nnanoparticles for highly efficient electrocatalytic alcohol oxidation","volume":"143","author":"Liu","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"2026092108270041700_cit34","doi-asserted-by":"publisher","first-page":"12263","DOI":"10.1021\/jacs.6b07213","article-title":"Quantitative analysis of the reduction kinetics responsible\nfor the one-pot synthesis of Pd-Pt bimetallic nanocrystals with different\nstructures","volume":"138","author":"Zhou","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"2026092108270041700_cit35","doi-asserted-by":"publisher","first-page":"6078","DOI":"10.1021\/ja201156s","article-title":"Synthesis of Pd-Pt\nbimetallic nanocrystals with a concave structure through a bromide-induced\ngalvanic replacement reaction","volume":"133","author":"Zhang","year":"2011","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026092108270041700_cit36","doi-asserted-by":"publisher","first-page":"20250042","DOI":"10.1360\/nso\/20250042","article-title":"Rare-earth-metal-alloyed\nmesoporous PtPb nanosheets\nfor selective electrosynthesis of glyceric acid from glycerol upcycling","volume":"4","author":"Gai","year":"2025","journal-title":"Natl. Sci. Open"},{"key":"2026092108270041700_cit37","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202511476","article-title":"Interstitial\ncobalt in Pt shell of Pd@Pt mesoporous core-shell nanospheres with\nstrong d-d orbital hybridization for enhanced electrocatalytic ammonia\noxidation","volume":"37","author":"Lin","year":"2025","journal-title":"Adv. Mater."},{"key":"2026092108270041700_cit38","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202522126","article-title":"Spatial\nconfiguration modulation of 2D Pd-Pt heterostructures for boosting\nelectrochemical oxygen reduction","volume":"36","author":"Jiao","year":"2026","journal-title":"Adv. Funct.\nMater."},{"key":"2026092108270041700_cit39","doi-asserted-by":"publisher","first-page":"7710","DOI":"10.1038\/s41467-025-63067-0","article-title":"Pd nanocatalysts\nengineering for direct oxidation methane-to-methanol\nwith 99.7% selectivity","volume":"16","author":"Deng","year":"2025","journal-title":"Nat. Commun."},{"key":"2026092108270041700_cit40","doi-asserted-by":"publisher","first-page":"3570","DOI":"10.1021\/nl501205j","article-title":"Atomic layer-by-layer deposition of Pt on Pd nanocubes\nfor catalysts with enhanced activity and durability toward oxygen\nreduction","volume":"14","author":"Xie","year":"2014","journal-title":"Nano Lett."},{"key":"2026092108270041700_cit41","doi-asserted-by":"publisher","first-page":"3816","DOI":"10.1021\/ja200329p","article-title":"Shape-selective\nsynthesis and facet-dependent enhanced electrocatalytic activity and\ndurability of monodisperse sub-10 nm Pt-Pd tetrahedrons and cubes","volume":"133","author":"Yin","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"2026092108270041700_cit42","doi-asserted-by":"publisher","first-page":"16762","DOI":"10.1021\/ja407773x","article-title":"Metallic nanocages:\nsynthesis of bimetallic Pt-Pd hollow\nnanoparticles with dendritic shells by selective chemical etching","volume":"135","author":"Wang","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"2026092108270041700_cit43","doi-asserted-by":"publisher","first-page":"489","DOI":"10.1038\/s44160-026-01025-4","article-title":"Phase and facet engineering\nfor nanoscale catalyst discovery in electrochemical CO2 reduction","volume":"5","author":"Xie","year":"2026","journal-title":"Nat. Synth."},{"key":"2026092108270041700_cit44","doi-asserted-by":"publisher","first-page":"100090","DOI":"10.59717\/j.xinn-mater.2024.100090","article-title":"Heterogeneous catalysis for the environment","volume":"2","author":"Liu","year":"2024","journal-title":"Innov. Mater."},{"key":"2026092108270041700_cit45","doi-asserted-by":"publisher","first-page":"3131","DOI":"10.1039\/D4AN00412D","article-title":"Anisotropic growth\nof gold anchors on CdSe semiconductor quantum platelets for self-assembled\narchitectures with well-connected electronic circuits for the electrochemical\ndetection of enrofloxacin","volume":"149","author":"Cao","year":"2024","journal-title":"Analyst"},{"key":"2026092108270041700_cit46","doi-asserted-by":"publisher","first-page":"553","DOI":"10.1021\/acssensors.7b00051","article-title":"Wearable flexible and\nstretchable glove biosensor for on-site detection of organophosphorus\nchemical threats","volume":"2","author":"Mishra","year":"2017","journal-title":"ACS Sens."},{"key":"2026092108270041700_cit47","doi-asserted-by":"publisher","first-page":"547","DOI":"10.1021\/jacs.1c11313","article-title":"Preparation of Au@Pd core-shell nanorods with fcc-2H-fcc\nheterophase\nfor highly efficient electrocatalytic alcohol oxidation","volume":"144","author":"Zhou","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026092108270041700_cit48","doi-asserted-by":"publisher","first-page":"2422533","DOI":"10.1002\/adfm.202422533","article-title":"Manipulating d-band center by interface-induced dislocation\nin Pt@PtCu\nnanowires boosting oxygen reduction","volume":"35","author":"Luo","year":"2025","journal-title":"Adv. Funct.\nMater."},{"key":"2026092108270041700_cit49","doi-asserted-by":"publisher","first-page":"2001575","DOI":"10.1002\/adfm.202001575","article-title":"Structure design reveals\nthe role\nof Au for ORR catalytic performance optimization in PtCo-based catalysts","volume":"30","author":"Guo","year":"2020","journal-title":"Adv. Funct. Mater."}],"container-title":["Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.inorgchem.6c04089","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/65\/37\/22162\/68281804\/acs.inorgchem.6c04089.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/inocaj\/article-pdf\/65\/37\/22162\/68281804\/acs.inorgchem.6c04089.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T12:44:10Z","timestamp":1789994650000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/inocaj\/article\/65\/37\/22162\/5412907\/Galvanic-Replacement-Driven-Structural-Evolution"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,3]]},"references-count":49,"journal-issue":{"issue":"37","published-online":{"date-parts":[[2026,9,3]]},"published-print":{"date-parts":[[2026,9,21]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.inorgchem.6c04089","relation":{},"ISSN":["0020-1669","1520-510X"],"issn-type":[{"value":"0020-1669","type":"print"},{"value":"1520-510X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,3]]}}}