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HOFs are generally constructed via highly directional intermolecular N\u2013H\u00b7\u00b7\u00b7N and O\u2013H\u00b7\u00b7\u00b7O hydrogen bonds, while the study of HOFs constructed by low-directional hydrogen bonds has lagged somewhat. The present study reveals that charge-neutral N\u2013H\u00b7\u00b7\u00b7Br hydrogen bonds are suitable for the construction of HOFs. Specifically, single crystals of a bis(benzimidazole)NiBr2 complex (bis(benzimidazole) = phenylbis(benzimidazol-2-yl)methane) were found to be a HOF supported by intermolecular N\u2013H\u00b7\u00b7\u00b7Br hydrogen bonds. This HOF exhibits interesting flexibility, i.e., the intermolecular N\u2013H\u00b7\u00b7\u00b7Br hydrogen bonds are cleaved and reformed upon the adsorption\/desorption of organic vapors. Moreover, it can adsorb organic vapors in a recyclable fashion (for at least 10 cycles when acetone is used). This study expands the classes of low-directional hydrogen bonds applicable to the construction of HOFs.<\/jats:p>","DOI":"10.1021\/acs.inorgchem.6c04419","type":"journal-article","created":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T02:01:20Z","timestamp":1789092080000},"page":"22198-22207","source":"Crossref","is-referenced-by-count":0,"title":["Charge-Neutral\nN\u2013H\u00b7\u00b7\u00b7Br as a\nHydrogen-Bond Family for the Construction of Hydrogen-Bonded Organic\nFrameworks"],"prefix":"10.1021","volume":"65","author":[{"given":"Tatsunari","family":"Murakami","sequence":"first","affiliation":[{"name":"Hirosaki University , , ,","place":["Hirosaki, Japan, 036-8561"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiroto","family":"Kikuya","sequence":"additional","affiliation":[{"name":"Hirosaki University , , ,","place":["Hirosaki, Japan, 036-8561"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shusuke","family":"Fujita","sequence":"additional","affiliation":[{"name":"Hirosaki University , , ,","place":["Hirosaki, Japan, 036-8561"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Satoshi","family":"Sasaki","sequence":"additional","affiliation":[{"name":"Hirosaki University , , ,","place":["Hirosaki, Japan, 036-8561"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2433-9442","authenticated-orcid":true,"given":"Tomoyuki","family":"Toda","sequence":"additional","affiliation":[{"name":"Nagaoka University of Technology , , 1603-1 Kamitomioka , , ,","place":["Nagaoka, Niigata, Japan, 940-2188"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9685-7524","authenticated-orcid":true,"given":"Masanobu","family":"Sagisaka","sequence":"additional","affiliation":[{"name":"Hirosaki University , , ,","place":["Hirosaki, Japan, 036-8561"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masaaki","family":"Okazaki","sequence":"additional","affiliation":[{"name":"Hirosaki University , , ,","place":["Hirosaki, Japan, 036-8561"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5096-8472","authenticated-orcid":true,"given":"Shun","family":"Ohta","sequence":"additional","affiliation":[{"name":"Hirosaki University , , ,","place":["Hirosaki, Japan, 036-8561"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,10]]},"reference":[{"key":"2026092108265756200_cit1","doi-asserted-by":"publisher","first-page":"10082","DOI":"10.1002\/chem.201201351","article-title":"Permanent\nporous materials from discrete organic molecules\u2013towards ultra-high\nsurface areas","volume":"18","author":"Mastalerz","year":"2012","journal-title":"Chem.\u2013Eur. 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