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Utilizing retinoic acid photoisomerization, the system reversibly switches host\u2013guest inclusion forms under visible light, dynamically tuning surface charge density and hydrophobicity. Under dark conditions, N-l-Cys-P6 nanochannels release triclopyr and R-2,4-DP 4-fold and 1.4-fold more than under visible light, respectively. Furthermore, chiral N-l-Cys-P6 imparts enantioselectivity: R-2,4-DP release is 1.7 times as large as that of the S isomer in darkness. Weeding tests verify that herbicides released in the dark present superior inhibition on broadleaf weeds. This design offers a new route for smart light-responsive pesticide delivery and facilitates an eco-friendly agricultural development.<\/jats:p>","DOI":"10.1021\/acs.jafc.6c02064","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T16:26:23Z","timestamp":1788452783000},"page":"28190-28199","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Light-Dark\nDual-Mode Herbicides Delivery:\nControlled Release and Enhanced Utilization with Functionalized Pillar[6]arene\nNanochannel Membranes"],"prefix":"10.1021","volume":"74","author":[{"given":"Sijin","family":"Li","sequence":"first","affiliation":[{"name":"Central China Normal University , , ,","place":["Wuhan, P. R. China, 430079"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haonan","family":"Qu","sequence":"additional","affiliation":[{"name":"Central China Normal University , , ,","place":["Wuhan, P. R. 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Mater."},{"key":"2026091609083565700_cit34","doi-asserted-by":"publisher","first-page":"165848","DOI":"10.1016\/j.cej.2025.165848","article-title":"Construction\nof dynamically regulated biomimetic nanochannels inspired by temperature-sensitive\nproteins for intelligent release of pesticides","volume":"520","author":"Qu","year":"2025","journal-title":"Chem. Eng. 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