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Iron-based nanomaterials (Fe-NMs)\u2500primarily nanoscale zerovalent iron and iron oxides\u2500have emerged as core functional materials in nanoenabled agriculture, owing to their environmental compatibility, tunable physicochemical properties, cost effectiveness, and redox activity. This review systematically details controllable synthetic paradigms, three mainstream application modalities (foliar spraying, soil amendment, seed priming), and underlying mechanisms for crop growth promotion, abiotic\/biotic stress tolerance, and in situ farmland remediation via Fe2+\/Fe3+ redox regulation and adsorption-catalytic activity. It critically analyzes bottlenecks restricting large-scale deployment and highlights key research priorities, providing systematic guidance for the safe, standardized development of iron-based nanoagricultural technology.<\/jats:p>","DOI":"10.1021\/acs.jafc.6c05668","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T14:02:31Z","timestamp":1789999351000},"page":"29674-29699","source":"Crossref","is-referenced-by-count":0,"title":["Iron-Based Nanotechnology\nEmpowers Sustainable Agriculture"],"prefix":"10.1021","volume":"74","author":[{"given":"Lubing","family":"Sang","sequence":"first","affiliation":[{"name":"Beijing University of Chemical Technology , , ,","place":["Beijing, P. R. China, 100029"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yimeng","family":"Cao","sequence":"additional","affiliation":[{"name":"Beijing University of Chemical Technology , , ,","place":["Beijing, P. R. China, 100029"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenchen","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing University of Chemical Technology , , ,","place":["Beijing, P. R. China, 100029"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinwei","family":"Li","sequence":"additional","affiliation":[{"name":"Beijing University of Chemical Technology , , ,","place":["Beijing, P. R. China, 100029"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingyuan","family":"Cui","sequence":"additional","affiliation":[{"name":"Zhejiang University of Water Resources and Electric Power , , ,","place":["Zhejiang, P. R. China, 310018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2998-830X","authenticated-orcid":true,"given":"Chenliu","family":"Tang","sequence":"additional","affiliation":[{"name":"Beijing University of Chemical Technology , , ,","place":["Beijing, P. 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