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Herein, we designed a water-dispersible, bioinspired nanopesticide (IND@PLA@PZTA) by coating indoxacarb-loaded poly(lactic acid) nanoparticles with a phosphorylated zein\u2013tannic acid coating. The formulation achieved 96.3% encapsulation efficacy and sustained pesticide release for 96 h while exhibiting improved wettability, foliage retention, and enhanced UV protection, retaining 72% of the pesticide after 3 h of UV exposure. Against Spodoptera litura, the nanopesticides produced 96.7% larval mortality after 56 h, representing a 2.6-fold improvement over the commercial formulation, and effectively suppressed larval development. A greenhouse study further validated these results. Moreover, the nanoformulation also showed reduced toxicity toward nontarget organisms, including ladybirds, soil bacteria, Daphnia magna, Vigna radiata and human keratinocytes. Constructed entirely from Generally Recognized as Safe (GRAS) materials, this multifunctional nanopesticide represents a sustainable strategy for pesticide delivery.<\/jats:p>","DOI":"10.1021\/acs.jafc.6c07146","type":"journal-article","created":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T21:02:11Z","timestamp":1790197331000},"page":"31429-31443","source":"Crossref","is-referenced-by-count":0,"title":["A Bioinspired, Photostable, Rain-Resilient Zein-Polyphenol-Based\nNanocomposite with Enhanced Pesticidal Activity for Sustainable Agrochemical\nDelivery"],"prefix":"10.1021","volume":"74","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9319-9394","authenticated-orcid":true,"given":"Nikita","family":"Shraogi","sequence":"first","affiliation":[{"name":"CSIR-Indian Institute of Toxicology Research (CSIR-IITR) , , Vishvigyan Bhawan, 31, Mahatma Gandhi Marg , , ,","place":["Lucknow, Uttar Pradesh, India, 226001"]},{"name":"Academy of Scientific and Innovative Research (AcSIR) , ,","place":["Ghaziabad, India, 201002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9566-0655","authenticated-orcid":true,"given":"Joel","family":"Saji","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Toxicology Research (CSIR-IITR) , , Vishvigyan Bhawan, 31, Mahatma Gandhi Marg , , ,","place":["Lucknow, Uttar Pradesh, India, 226001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chitrita","family":"Chakraborty","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Toxicology Research (CSIR-IITR) , , Vishvigyan Bhawan, 31, Mahatma Gandhi Marg , , ,","place":["Lucknow, Uttar Pradesh, India, 226001"]},{"name":"Academy of Scientific and Innovative Research (AcSIR) , ,","place":["Ghaziabad, India, 201002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amrita","family":"Singh","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Toxicology 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226001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4615-3956","authenticated-orcid":true,"given":"Shriza","family":"Rai","sequence":"additional","affiliation":[{"name":"University of Lucknow , , ,","place":["Lucknow, India, 226007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sadasivam","family":"Anbumani","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Toxicology Research (CSIR-IITR) , , Vishvigyan Bhawan, 31, Mahatma Gandhi Marg , , ,","place":["Lucknow, Uttar Pradesh, India, 226001"]},{"name":"Academy of Scientific and Innovative Research (AcSIR) , ,","place":["Ghaziabad, India, 201002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Geetanjali","family":"Mishra","sequence":"additional","affiliation":[{"name":"University of Lucknow , , ,","place":["Lucknow, India, 226007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3732-0564","authenticated-orcid":true,"given":"Praveen Chandra","family":"Verma","sequence":"additional","affiliation":[{"name":"Academy of Scientific and Innovative Research (AcSIR) , ,","place":["Ghaziabad, India, 201002"]},{"name":"CSIR-National Botanical Research Institute , , ,","place":["Lucknow, India, 226001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Debabrata","family":"Ghosh","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Toxicology Research (CSIR-IITR) , , Vishvigyan Bhawan, 31, Mahatma Gandhi Marg , , ,","place":["Lucknow, Uttar Pradesh, India, 226001"]},{"name":"Academy of Scientific and Innovative Research (AcSIR) , ,","place":["Ghaziabad, India, 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Saf."},{"key":"2026101408090482200_cit17","first-page":"125","article-title":"Recent Trends\nin Nano-Enabled Solutions for Sustainable\nAgriculture and Global Food Security","volume-title":"Application\nof Nanotechnology for Sustainable Agriculture and Food Security Vol.\n2: innovations in Pre-and Post-Harvest Crop Management","author":"Shraogi","year":"2025"},{"issue":"21","key":"2026101408090482200_cit18","doi-asserted-by":"publisher","first-page":"12146","DOI":"10.1021\/acs.jafc.4c00980","article-title":"Smart and\nsustainable crop protection: design and evaluation of a novel \u03b1-amylase-responsive\nnanopesticide for effective pest control","volume":"72","author":"Li","year":"2024","journal-title":"J.\nAgric. 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