{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T03:14:27Z","timestamp":1791083667824,"version":"4.1.0"},"reference-count":68,"publisher":"American Chemical Society (ACS)","issue":"30","license":[{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["32372418"],"award-info":[{"award-number":["32372418"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The persistent migration of pesticides into aquatic ecosystems poses severe risks to environmental and public health. Monitoring pesticide residues along these migration pathways is therefore critical. Herein, we report the first application of a three-dimensional (3D) photonic microsphere surface-enhanced Raman spectroscopy (SERS) substrate (ZIF-8 PCMs-NH2@AuNPs) for the targeted adsorption and trace detection of the pesticide thiram. Synthesized via microfluidics, these hierarchically porous metal\u2013organic framework microspheres overcome the poor reproducibility of conventional substrates by yielding highly uniform, stable \u201cRaman hotspots\u201d through surface-modified AuNPs. This structurally reproducible substrate achieved an enhancement factor of 8.4 \u00d7 107. For thiram analysis, it demonstrated a broad linear range (0.05\u201310 \u03bcg\/mL) and a low limit of detection (0.0137 \u03bcg\/mL). Validated in real water samples, this platform provides a robust analytical tool for monitoring pesticide residues of the migration pathways (soil water\u2013river water\u2013tap water).<\/jats:p>","DOI":"10.1021\/acs.jafc.6c07225","type":"journal-article","created":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T16:58:26Z","timestamp":1784825906000},"page":"23935-23946","source":"Crossref","is-referenced-by-count":1,"title":["3D MOF Photonic\nMicrospheres for Thiram SERS Fingerprint\nDetection"],"prefix":"10.1021","volume":"74","author":[{"given":"Ziqiang","family":"Li","sequence":"first","affiliation":[{"name":"Nanjing Normal University , , ,","place":["Nanjing, China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Li","sequence":"additional","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyi","family":"Wang","sequence":"additional","affiliation":[{"name":"Nanjing Normal University , , ,","place":["Nanjing, China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aiqin","family":"Chen","sequence":"additional","affiliation":[{"name":"Nanjing Normal University , , ,","place":["Nanjing, China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Wang","sequence":"additional","affiliation":[{"name":"Nanjing Normal University , , ,","place":["Nanjing, China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan","family":"Lu","sequence":"additional","affiliation":[{"name":"Nanjing Normal University , , ,","place":["Nanjing, China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shan","family":"Muhammad","sequence":"additional","affiliation":[{"name":"Nanjing Normal University , , ,","place":["Nanjing, China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6498-7284","authenticated-orcid":true,"given":"Qianjin","family":"Li","sequence":"additional","affiliation":[{"name":"Nanjing Normal University , , ,","place":["Nanjing, China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5267-3931","authenticated-orcid":true,"given":"Jianlin","family":"Li","sequence":"additional","affiliation":[{"name":"Nanjing Normal University , , ,","place":["Nanjing, China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,23]]},"reference":[{"issue":"13","key":"2026080510093604000_cit1","doi-asserted-by":"publisher","first-page":"8026","DOI":"10.1021\/acs.jafc.4c12970","article-title":"Sensitive and stable\ndetection of pesticide residues using flexible 3D nanocellulose-based\nSERS substrates","volume":"73","author":"Zhou","year":"2025","journal-title":"J. Agric. Food Chem."},{"issue":"6","key":"2026080510093604000_cit2","doi-asserted-by":"publisher","first-page":"4253","DOI":"10.1021\/acsanm.2c05351","article-title":"Au\u2013Ag nanoparticles with controllable\nmorphologies for the surface-enhanced Raman scattering detection of\ntrace thiram","volume":"6","author":"Sun","year":"2023","journal-title":"ACS Appl. Nano Mater."},{"key":"2026080510093604000_cit3","doi-asserted-by":"publisher","first-page":"140405","DOI":"10.1016\/j.foodchem.2024.140405","article-title":"Carbon dots-based\nstimuli-responsive hydrogel for in-situ detection of thiram on fruits\nand vegetables","volume":"460","author":"Li","year":"2024","journal-title":"Food Chem."},{"key":"2026080510093604000_cit4","doi-asserted-by":"publisher","first-page":"468","DOI":"10.3390\/ijerph18020468","article-title":"Pesticides in drinking water\u2500A review","volume":"18","author":"Syafrudin","year":"2021","journal-title":"Int. J. Environ. Res. 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