{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T09:18:05Z","timestamp":1788254285153,"version":"build-2803163510"},"reference-count":69,"publisher":"American Chemical Society (ACS)","issue":"33","license":[{"start":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T00:00:00Z","timestamp":1786492800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T00:00:00Z","timestamp":1786492800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T00:00:00Z","timestamp":1786492800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100014219","name":"National Science Fund for Distinguished Young Scholars","doi-asserted-by":"publisher","award":["42125703"],"award-info":[{"award-number":["42125703"]}],"id":[{"id":"10.13039\/501100014219","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["42177204"],"award-info":[{"award-number":["42177204"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,26]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Dissolved black carbon (DBC) is widespread in natural environments and interacts strongly with Fe(III) (oxyhydr)oxides, yet how these interactions regulate phosphorus (P) retention by ferrihydrite (Fh) remains unclear. Here, we prepared DBC from biochars pyrolyzed at 300 \u00b0C (DBC300) and 550 \u00b0C (DBC550) to investigate their impacts using experimental studies and DFT simulations. DBC300 reduced Fh\u2019s maximum P adsorption capacity by 10% via competitive ligand exchange, while DBC550 increased it by 42%. With low molecular weight and high aromaticity, DBC550 promoted Fe(III) dissolution to enhance phosphate retention, as evidenced by the Fe(III)-P correlation. This Fe(III) dissolution-mediated phosphate immobilization process dominated over competitive inhibition across a pH range of 4.0\u20138.5 and C\/P ratios of 0.25\u20132.25. DFT confirms that DBC550 lengthens Fe\u2013O bonds to destabilize Fh. Our findings show that rising pyrolysis temperature shifts DBC from a P mobilizer to a fixator; overlooking this pathway may overestimate DBC-induced eutrophication risk.<\/jats:p>","DOI":"10.1021\/acs.jafc.6c08196","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T07:02:29Z","timestamp":1786518149000},"page":"26133-26143","source":"Crossref","is-referenced-by-count":0,"title":["Temperature-Driven\nShift in the Role of Dissolved\nBlack Carbon in Ferrihydrite\u2013Phosphorus Interactions: From\nInhibition to Promotion"],"prefix":"10.1021","volume":"74","author":[{"given":"Chenyu","family":"Gao","sequence":"first","affiliation":[{"name":"North China Electric Power University , , ,","place":["Beijing, China, 102206"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunchao","family":"Wu","sequence":"additional","affiliation":[{"name":"North China Electric Power University , , ,","place":["Beijing, China, 102206"]},{"name":"Beijing Jingcheng Jiayu Environmental Technology Co., Ltd. , ,","place":["Beijing, China, 100053"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengge","family":"Wang","sequence":"additional","affiliation":[{"name":"North China Electric Power University , , ,","place":["Beijing, China, 102206"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyuan","family":"Huang","sequence":"additional","affiliation":[{"name":"North China Electric Power University , , ,","place":["Beijing, China, 102206"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liping","family":"Zhai","sequence":"additional","affiliation":[{"name":"North China Electric Power University , , ,","place":["Beijing, China, 102206"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yihua","family":"Zhang","sequence":"additional","affiliation":[{"name":"North China Electric Power University , , ,","place":["Beijing, China, 102206"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9091-920X","authenticated-orcid":true,"given":"Jie","family":"Jin","sequence":"additional","affiliation":[{"name":"North China Electric Power University , , ,","place":["Beijing, China, 102206"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0425-7754","authenticated-orcid":true,"given":"Ke","family":"Sun","sequence":"additional","affiliation":[{"name":"Beijing Normal University , , ,","place":["Beijing, China, 100875"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,12]]},"reference":[{"issue":"4","key":"2026090104464066000_cit1","doi-asserted-by":"publisher","first-page":"239","DOI":"10.1038\/s41579-024-01119-w","article-title":"The microbial\nphosphorus cycle in aquatic ecosystems","volume":"23","author":"Duhamel","year":"2025","journal-title":"Nat.\nRev. Microbiol."},{"issue":"1","key":"2026090104464066000_cit2","doi-asserted-by":"publisher","DOI":"10.1007\/s44246-023-00038-4","article-title":"Chemical composition, sources, and\necological effect of organic phosphorus\nin water ecosystems: a review","volume":"2","author":"Feng","year":"2023","journal-title":"Carbon Res."},{"key":"2026090104464066000_cit3","doi-asserted-by":"publisher","first-page":"135","DOI":"10.1016\/S0065-2113(06)94003-6","article-title":"Phosphate reaction\ndynamics in soils and soil components:\na multiscale approach","volume":"94","author":"Arai","year":"2007","journal-title":"Adv. Agron."},{"issue":"4","key":"2026090104464066000_cit4","doi-asserted-by":"publisher","first-page":"447","DOI":"10.1111\/j.1365-2389.1978.tb00794.x","article-title":"The description\nof phosphate adsorption curves","volume":"29","author":"Barrow","year":"1978","journal-title":"J. Soil Sci."},{"issue":"16","key":"2026090104464066000_cit5","doi-asserted-by":"publisher","first-page":"9182","DOI":"10.1021\/es400997n","article-title":"Natural and pyrogenic humic acids\nat goethite and natural oxide surfaces interacting with phosphate","volume":"47","author":"Hiemstra","year":"2013","journal-title":"Environ. Sci. Technol."},{"key":"2026090104464066000_cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemgeo.2024.122352","article-title":"Effects of mineral\nadsorption on the molecular composition of soil dissolved organic\nmatter: evidence from spectral analyses","volume":"669","author":"Li","year":"2024","journal-title":"Chem.\nGeol."},{"issue":"2","key":"2026090104464066000_cit7","doi-asserted-by":"publisher","DOI":"10.3390\/toxics13020120","article-title":"Influencing factors of phosphorus\nmobility and retention in the sediment\nof three typical plateau lakes","volume":"13","author":"Wu","year":"2025","journal-title":"Toxics"},{"key":"2026090104464066000_cit8","doi-asserted-by":"publisher","DOI":"10.1016\/j.jenvman.2024.120883","article-title":"Influence\nof dissolved organic matter with different molecular weight from chicken\nmanure on ferrihydrite adsorption and re-release of antimony(V)","volume":"358","author":"Qiu","year":"2024","journal-title":"J. Environ. Manage."},{"issue":"12","key":"2026090104464066000_cit9","doi-asserted-by":"publisher","first-page":"4479","DOI":"10.1021\/es100066s","article-title":"Formation of binary\nand ternary colloids\nand dissolved complexes of organic matter, Fe and As","volume":"44","author":"Sharma","year":"2010","journal-title":"Environ. Sci. Technol."},{"issue":"4","key":"2026090104464066000_cit10","doi-asserted-by":"publisher","first-page":"2078","DOI":"10.1021\/acs.est.3c09359","article-title":"Differential adsorption of dissolved\norganic matter and phosphorus on clay mineral in water-sediment system","volume":"58","author":"Yu","year":"2024","journal-title":"Environ. Sci. Technol."},{"issue":"1","key":"2026090104464066000_cit11","doi-asserted-by":"publisher","first-page":"76","DOI":"10.1111\/gcb.12985","article-title":"Towards a global assessment\nof pyrogenic carbon from vegetation fires","volume":"22","author":"Santi\u0301n","year":"2016","journal-title":"Glob.\nChang. Biol."},{"issue":"3","key":"2026090104464066000_cit12","doi-asserted-by":"publisher","first-page":"168","DOI":"10.1002\/lol2.10076","article-title":"Dissolved black carbon in aquatic\necosystems","volume":"3","author":"Wagner","year":"2018","journal-title":"Limnol. Oceanogr. Lett."},{"issue":"1","key":"2026090104464066000_cit13","doi-asserted-by":"publisher","DOI":"10.1007\/s44246-022-00022-4","article-title":"Analytical\nmethods, molecular structures and biogeochemical behaviors of dissolved\nblack carbon","volume":"1","author":"Chen","year":"2022","journal-title":"Carbon Res."},{"key":"2026090104464066000_cit14","doi-asserted-by":"publisher","DOI":"10.1016\/j.envadv.2022.100297","article-title":"Molecular\nCharacterization by ultrahigh\nresolution mass spectrometry of dissolved black carbon-like molecules\nin summer along the pearl river estuary, China","volume":"9","author":"Wang","year":"2022","journal-title":"Environ. Adv."},{"key":"2026090104464066000_cit15","doi-asserted-by":"publisher","first-page":"217","DOI":"10.1016\/j.jes.2023.09.040","article-title":"Dissolved carbon in biochar: exploring\nits chemistry, iron complexing capability, toxicity in natural redox\nenvironment","volume":"147","author":"Lai","year":"2025","journal-title":"J. Environ. Sci."},{"issue":"7","key":"2026090104464066000_cit16","doi-asserted-by":"publisher","DOI":"10.3390\/separations10070408","article-title":"Review of photochemical\nactivity of dissolved black carbon in aquatic environments: primary\ninfluencing factors and mechanisms","volume":"10","author":"Liu","year":"2023","journal-title":"Separations"},{"issue":"3","key":"2026090104464066000_cit17","doi-asserted-by":"publisher","first-page":"4155","DOI":"10.1021\/acsomega.5c08272","article-title":"Characteristics\nof dissolved organic matter from feces-based biochar: effects of pyrolysis\ntemperature and extraction solution pH","volume":"11","author":"Xie","year":"2026","journal-title":"ACS\nOmega"},{"key":"2026090104464066000_cit18","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2026.134650","article-title":"Temperature-dependent\nmolecular evolution\nof dissolved black carbon and its interaction mechanism with dissimilatory\niron reduction","volume":"453","author":"Zhai","year":"2026","journal-title":"Bioresour. 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Total Environ."},{"issue":"18","key":"2026090104464066000_cit27","doi-asserted-by":"publisher","first-page":"10322","DOI":"10.1021\/es401301z","article-title":"Effect of ferrihydrite\ncrystallite size on phosphate\nadsorption reactivity","volume":"47","author":"Wang","year":"2013","journal-title":"Environ. Sci. Technol."},{"key":"2026090104464066000_cit28","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2020.122260","article-title":"Sorption and molecular\nfractionation of biochar-derived dissolved organic matter on ferrihydrite","volume":"392","author":"Zhang","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"2026090104464066000_cit29","doi-asserted-by":"publisher","DOI":"10.3389\/fenvs.2022.893212","article-title":"Effect of biochar addition\non phosphorus\nadsorption characteristics of red soil","volume":"10","author":"Wu","year":"2022","journal-title":"Front.\nEnviron. Sci."},{"key":"2026090104464066000_cit30","doi-asserted-by":"publisher","first-page":"1300","DOI":"10.1016\/j.scitotenv.2018.04.099","article-title":"Speciation\nof phosphorus in plant- and manure-derived biochars and\nits dissolution under various aqueous conditions","volume":"634","author":"Sun","year":"2018","journal-title":"Sci. Total Environ."},{"issue":"1","key":"2026090104464066000_cit31","doi-asserted-by":"publisher","DOI":"10.1007\/s42773-024-00415-1","article-title":"Biochar application\nto soils can regulate soil phosphorus availability:\na review","volume":"7","author":"Zhang","year":"2025","journal-title":"Biochar"},{"issue":"6","key":"2026090104464066000_cit32","doi-asserted-by":"publisher","first-page":"230","DOI":"10.4319\/lom.2008.6.230","article-title":"A simple and\nefficient\nmethod for the solid-phase extraction of dissolved organic matter\n(SPE-DOM) from seawater","volume":"6","author":"Dittmar","year":"2008","journal-title":"Limnol. Oceanogr. Methods"},{"issue":"20","key":"2026090104464066000_cit33","doi-asserted-by":"publisher","first-page":"11730","DOI":"10.1021\/acsomega.0c01055","article-title":"In-house standard\nmethod for molecular\ncharacterization of dissolved organic matter by FT-ICR mass spectrometry","volume":"5","author":"He","year":"2020","journal-title":"ACS Omega"},{"issue":"8","key":"2026090104464066000_cit34","doi-asserted-by":"publisher","first-page":"4419","DOI":"10.1021\/es203901u","article-title":"Molecular\nfractionation of dissolved\norganic matter with metal salts","volume":"46","author":"Riedel","year":"2012","journal-title":"Environ. Sci.\nTechnol."},{"issue":"17","key":"2026090104464066000_cit35","doi-asserted-by":"publisher","first-page":"4397","DOI":"10.1021\/ac020019f","article-title":"Ionization and fragmentation\nof humic substances in electrospray ionization Fourier transform-ion\ncyclotron resonance mass spectrometry","volume":"74","author":"Stenson","year":"2002","journal-title":"Anal.\nChem."},{"issue":"17","key":"2026090104464066000_cit36","doi-asserted-by":"publisher","first-page":"11624","DOI":"10.1021\/acs.est.1c00083","article-title":"Novel insights into the molecular-level mechanism linking the chemical\ndiversity and copper binding heterogeneity of biochar-derived dissolved\nblack carbon and dissolved organic matter","volume":"55","author":"Song","year":"2021","journal-title":"Environ.\nSci. Technol."},{"issue":"5","key":"2026090104464066000_cit37","doi-asserted-by":"publisher","first-page":"2715","DOI":"10.1021\/acs.est.9b05864","article-title":"Application of hydrochar altered\nsoil microbial community composition and the molecular structure of\nnative soil organic carbon in a paddy soil","volume":"54","author":"Sun","year":"2020","journal-title":"Environ. Sci. Technol."},{"key":"2026090104464066000_cit38","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2022.153300","article-title":"Coupling band\nstructure and oxidation-reduction potential to expound photodegradation\nperformance difference of biochar-derived dissolved black carbon for\norganic pollutants under light irradiation","volume":"820","author":"Guo","year":"2022","journal-title":"Sci. Total Environ."},{"issue":"27","key":"2026090104464066000_cit39","doi-asserted-by":"publisher","first-page":"11998","DOI":"10.1021\/acs.est.4c01829","article-title":"Revealing\nmolecular structures of nitrogen-containing compounds in dissolved\nblack carbon using ultrahigh-resolution mass spectrometry combined\nwith thermodynamic calculations","volume":"58","author":"Zhang","year":"2024","journal-title":"Environ. Sci.\nTechnol."},{"issue":"5","key":"2026090104464066000_cit40","doi-asserted-by":"publisher","first-page":"1636","DOI":"10.1021\/es051501t","article-title":"Removal of arsenite\nand arsenate using hydrous ferric oxide incorporated into naturally\noccurring porous diatomite","volume":"40","author":"Jang","year":"2006","journal-title":"Environ. Sci. Technol."},{"issue":"23","key":"2026090104464066000_cit41","doi-asserted-by":"publisher","first-page":"13751","DOI":"10.1021\/es503669u","article-title":"Properties of Fe-organic\nmatter associations via coprecipitation versus adsorption","volume":"48","author":"Chen","year":"2014","journal-title":"Environ. Sci. Technol."},{"issue":"18","key":"2026090104464066000_cit42","doi-asserted-by":"publisher","first-page":"10605","DOI":"10.1021\/acs.est.7b03249","article-title":"Kinetics of\ncation and oxyanion adsorption and desorption on ferrihydrite: roles\nof ferrihydrite binding sites and a unified model","volume":"51","author":"Tian","year":"2017","journal-title":"Environ. Sci. Technol."},{"key":"2026090104464066000_cit43","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2024.121962","article-title":"Molecular-level\ntransformations of dissolved black carbon in UV-based\nadvanced oxidation processes","volume":"260","author":"Lu","year":"2024","journal-title":"Water Res."},{"key":"2026090104464066000_cit44","doi-asserted-by":"publisher","first-page":"356","DOI":"10.1016\/j.cej.2019.01.154","article-title":"Molecular weight-dependent\nadsorption fractionation of natural organic matter on ferrihydrite\ncolloids in aquatic environment","volume":"363","author":"Xu","year":"2019","journal-title":"Chem. Eng.\nJ."},{"key":"2026090104464066000_cit45","doi-asserted-by":"publisher","first-page":"55","DOI":"10.1016\/j.geoderma.2011.11.001","article-title":"Reprint of: Molecular modeling of soil organic matter:\nsquaring the circle?","volume":"169","author":"Schaumann","year":"2011","journal-title":"Geoderma"},{"key":"2026090104464066000_cit46","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.152960","article-title":"Molecular-level\ninsight into the origin-dependent adsorption fractionation of dissolved\norganic matter on ferrihydrite in aquatic environment: implications\nfor carbon sink in eutrophic lakes","volume":"494","author":"Suo","year":"2024","journal-title":"Chem. Eng.\nJ."},{"key":"2026090104464066000_cit47","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.gca.2017.04.045","article-title":"Effects of complexation\nbetween organic matter (OM) and clay mineral on OM pyrolysis","volume":"212","author":"Bu","year":"2017","journal-title":"Geochim. Cosmochim. 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Technol."},{"key":"2026090104464066000_cit50","doi-asserted-by":"publisher","first-page":"20","DOI":"10.1016\/j.biortech.2016.10.033","article-title":"Effect of pyrolysis\ntemperature on characteristics\nand aromatic contaminants adsorption behavior of magnetic biochar\nderived from pyrolysis oil distillation residue","volume":"223","author":"Li","year":"2017","journal-title":"Bioresour. Technol."},{"issue":"6","key":"2026090104464066000_cit51","doi-asserted-by":"publisher","first-page":"2093","DOI":"10.1016\/j.scitotenv.2008.11.022","article-title":"Aggregation\nand disaggregation of iron oxide nanoparticles: influence of particle\nconcentration, pH and natural organic matter","volume":"407","author":"Baalousha","year":"2009","journal-title":"Sci. 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Hydrol."},{"issue":"2","key":"2026090104464066000_cit55","doi-asserted-by":"publisher","first-page":"279","DOI":"10.1016\/j.jcis.2008.02.011","article-title":"Effects\nof anionic\nsurfactants on ligand-promoted dissolution of iron and aluminum hydroxides","volume":"321","author":"Carrasco","year":"2008","journal-title":"J. Colloid Interface Sci."},{"issue":"12","key":"2026090104464066000_cit56","doi-asserted-by":"publisher","first-page":"7236","DOI":"10.1021\/acs.est.5b01191","article-title":"Synergistic effect\nof reductive and ligand-promoted dissolution of goethite","volume":"49","author":"Wang","year":"2015","journal-title":"Environ. Sci. Technol."},{"key":"2026090104464066000_cit57","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2021.148923","article-title":"Mechanisms for the\ndissolved biochar promoted iron dissolution and\nconsequential chromium release","volume":"796","author":"Wu","year":"2021","journal-title":"Sci. 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