{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T13:34:33Z","timestamp":1786628073871,"version":"build-2736575974"},"reference-count":56,"publisher":"American Chemical Society (ACS)","issue":"8","license":[{"start":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T00:00:00Z","timestamp":1783900800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004359","name":"Vetenskapsr\u00e5det","doi-asserted-by":"publisher","award":["2020-03899"],"award-info":[{"award-number":["2020-03899"]}],"id":[{"id":"10.13039\/501100004359","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100018703","name":"HORIZON EUROPE European Innovation Council","doi-asserted-by":"publisher","award":["101070976"],"award-info":[{"award-number":["101070976"]}],"id":[{"id":"10.13039\/100018703","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFE0206200"],"award-info":[{"award-number":["2024YFE0206200"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001728","name":"Swedish Foundation for International Cooperation in Research and Higher Education","doi-asserted-by":"publisher","award":["CH2019-8287"],"award-info":[{"award-number":["CH2019-8287"]}],"id":[{"id":"10.13039\/501100001728","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22378182"],"award-info":[{"award-number":["22378182"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22494713"],"award-info":[{"award-number":["22494713"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,13]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The densities and viscosities of the three amine-based deep eutectic solvents (DESs), i.e., [EmimCl][MEA], [BmimCl][MEA], and [HmimCl][MEA], mixed with ethanol (EtOH), were measured from 288.15 to 323.15 K, and their enthalpies of mixing were determined at 298.15 and 308.15 K. Negative excess molar volumes across the entire compositional range indicate significant volume contraction and enhanced molecular packing, and their temperature dependence suggests the dominance of packing effects over hydrogen-bonding. Viscosity deviations show a characteristic U-shaped composition dependence, reflecting disruption of the original DES hydrogen-bond network by EtOH. The enthalpy of mixing changes from positive to negative as the DES composition increases, revealing strengthened DES\u2013EtOH interactions. The distinct composition-dependent trends observed for these three (DES + EtOH) systems indicate that variations in alkyl chain length modulate molecular packing and interaction strength, resulting in nonuniform ordering patterns across thermophysical properties. Compared to water, which strongly restructures the DES hydrogen-bond network and produces significant exothermic mixing effects, EtOH exerts a milder structural and thermodynamic impact. This work provides reliable thermodynamic data and mechanistic insight for the design and application of amine-based DESs.<\/jats:p>","DOI":"10.1021\/acs.jced.6c00157","type":"journal-article","created":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T09:54:28Z","timestamp":1783936468000},"page":"3381-3393","source":"Crossref","is-referenced-by-count":0,"title":["Thermodynamic Study\nof Amine-Based Deep Eutectic Solvents\nwith EtOH"],"prefix":"10.1021","volume":"71","author":[{"given":"Fei","family":"Lin","sequence":"first","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, P. R. China, 210009"]},{"name":"Lule\u00e5 University of Technology , , ,","place":["Lule\u00e5, Sweden, 97187"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yusi","family":"Shen","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, P. R. China, 210009"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhida","family":"Zuo","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, P. R. China, 210009"]},{"name":"Lule\u00e5 University of Technology , , ,","place":["Lule\u00e5, Sweden, 97187"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2963-8270","authenticated-orcid":true,"given":"Linghong","family":"Lu","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, P. R. China, 210009"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9244-6808","authenticated-orcid":true,"given":"Xiaohua","family":"Lu","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, P. R. China, 210009"]},{"name":"Suzhou Laboratory , ,","place":["Suzhou, P. R. China, 215125"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6643-2998","authenticated-orcid":true,"given":"Yudan","family":"Zhu","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, P. R. China, 210009"]},{"name":"Suzhou Laboratory , ,","place":["Suzhou, P. R. China, 215125"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0200-9960","authenticated-orcid":true,"given":"Xiaoyan","family":"Ji","sequence":"additional","affiliation":[{"name":"Lule\u00e5 University of Technology , , ,","place":["Lule\u00e5, Sweden, 97187"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,13]]},"reference":[{"key":"2026081308083615900_cit1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2020.122871","article-title":"Comprehensive 3E analysis and multi-objective optimization\nof a novel process for CO2 capture and separation process\nfrom syngas","volume":"274","author":"Wang","year":"2020","journal-title":"J. Cleaner Prod."},{"key":"2026081308083615900_cit2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2025.103303","article-title":"Numerical simulation and optimization\nof a CO2 absorption tower using solution absorption method\nfor capture","volume":"103","author":"Miao","year":"2026","journal-title":"J. CO2 Util."},{"key":"2026081308083615900_cit3","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2024.102727","article-title":"Advancements in CO2 capture by absorption\nand adsorption: A comprehensive review","volume":"81","author":"Soo","year":"2024","journal-title":"J. CO2 Util."},{"key":"2026081308083615900_cit4","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2019.06.008","article-title":"Experimental investigation on separation\nand energy-efficiency performance of temperature swing adsorption\nsystem for CO2 capture","volume":"227","author":"Liu","year":"2019","journal-title":"Sep. Purif.\nTechnol."},{"key":"2026081308083615900_cit5","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2023.102555","article-title":"Breaking boundaries\nin CO2 capture: Ionic liquid-based membrane separation\nfor post-combustion applications","volume":"75","author":"Mulk","year":"2023","journal-title":"J. CO2 Util."},{"key":"2026081308083615900_cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.energy.2023.128004","article-title":"Exergy and economic analysis of the\ntrade-off for design of post-combustion CO2 capture plant\nby chemical absorption with MEA","volume":"280","author":"Julio","year":"2023","journal-title":"Energy"},{"key":"2026081308083615900_cit7","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2026.136785","article-title":"BZA-based\nternary mixed amine absorbent for carbon dioxide capture: Performance\nand mechanism analysis","volume":"389","author":"Kong","year":"2026","journal-title":"Sep. Purif. Technol."},{"key":"2026081308083615900_cit8","doi-asserted-by":"publisher","first-page":"244","DOI":"10.1016\/j.psep.2022.05.025","article-title":"A strategy\nof development and selection of absorbent for efficient CO2 capture: An overview of properties and performance","volume":"163","author":"Tiwari","year":"2022","journal-title":"Process Saf. Environ. Prot."},{"key":"2026081308083615900_cit9","doi-asserted-by":"publisher","DOI":"10.3390\/en18164257","article-title":"Ionic liquids and poly\n(ionic liquids) for CO2 capture: A comprehensive review","volume":"18","author":"Kharade","year":"2025","journal-title":"Energies"},{"key":"2026081308083615900_cit10","doi-asserted-by":"publisher","first-page":"11060","DOI":"10.1021\/cr300162p","article-title":"Deep eutectic solvents (DESs) and\ntheir applications","volume":"114","author":"Smith","year":"2014","journal-title":"Chem. Rev."},{"key":"2026081308083615900_cit11","doi-asserted-by":"publisher","first-page":"70","DOI":"10.1039\/b210714g","article-title":"Novel solvent\nproperties of choline chloride\/urea mixtures","author":"Abbott","year":"2003","journal-title":"Chem. Commun."},{"key":"2026081308083615900_cit12","doi-asserted-by":"publisher","DOI":"10.3390\/molecules28145293","article-title":"Deep eutectic solvents: properties\nand applications in CO2 separation","volume":"28","author":"Cichowska-Kopczyn\u0301ska","year":"2023","journal-title":"Molecules"},{"key":"2026081308083615900_cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2023.113499","article-title":"Carbon dioxide separation performance evaluation of amine-based versus\ncholine-based deep eutectic solvents","volume":"184","author":"Song","year":"2023","journal-title":"Renewable\nSustainable Energy Rev."},{"key":"2026081308083615900_cit14","doi-asserted-by":"publisher","first-page":"1247","DOI":"10.1021\/je400884v","article-title":"Solubilities\nof carbon dioxide in eutectic mixtures of choline chloride and dihydric\nalcohols","volume":"59","author":"Chen","year":"2014","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit15","doi-asserted-by":"publisher","DOI":"10.1371\/journal.pone.0286960","article-title":"Experimental\ninvestigation of novel ternary amine-based deep eutectic solvents\nfor CO2 capture","volume":"18","author":"Rashidi","year":"2023","journal-title":"PLoS One"},{"key":"2026081308083615900_cit16","doi-asserted-by":"publisher","DOI":"10.3390\/cryst10110978","article-title":"Ionic liquids\/deep\neutectic solvents-based\nhybrid solvents for CO2 capture","volume":"10","author":"Liu","year":"2020","journal-title":"Crystals"},{"key":"2026081308083615900_cit17","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2025.132877","article-title":"Thermodynamic study on CO2 separation by\ndiamine functionalized aqueous deep eutectic solvents","volume":"367","author":"Shi","year":"2025","journal-title":"Sep. Purif. Technol."},{"key":"2026081308083615900_cit18","doi-asserted-by":"publisher","first-page":"2899","DOI":"10.1021\/acs.jced.2c00245","article-title":"Monoethanolamine + ethylene glycol\n+ choline chloride: an effect of the mixture composition on the CO2 absorption capacity, density, and viscosity","volume":"67","author":"Kazarina","year":"2022","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit19","doi-asserted-by":"publisher","first-page":"2230","DOI":"10.1021\/acs.jpcb.9b11753","article-title":"How hydration affects\nthe microscopic\nstructural morphology in a deep eutectic solvent","volume":"124","author":"Kaur","year":"2020","journal-title":"J. Phys. Chem. B"},{"key":"2026081308083615900_cit20","doi-asserted-by":"publisher","first-page":"15246","DOI":"10.1021\/acsomega.8b02447","article-title":"Influence of hydration\non the structure of reline deep\neutectic solvent: A molecular dynamics study","volume":"3","author":"Kumari","year":"2018","journal-title":"ACS Omega"},{"key":"2026081308083615900_cit21","doi-asserted-by":"publisher","first-page":"3335","DOI":"10.1021\/acs.jctc.0c00120","article-title":"Restructuring a deep eutectic solvent by water: the\nnanostructure of hydrated choline chloride\/urea","volume":"16","author":"Sapir","year":"2020","journal-title":"J. Chem. Theory Comput."},{"key":"2026081308083615900_cit22","doi-asserted-by":"publisher","first-page":"5302","DOI":"10.1021\/acs.jpcb.8b12322","article-title":"Ternary deep eutectic\nsolvent behavior of water and urea\u2013choline chloride mixtures","volume":"123","author":"Smith","year":"2019","journal-title":"J. Phys. Chem. B"},{"key":"2026081308083615900_cit23","doi-asserted-by":"publisher","first-page":"10601","DOI":"10.1021\/acs.jpcb.0c07934","article-title":"Microstructure of\ndeep eutectic solvents:\nCurrent understanding and challenges","volume":"124","author":"Kaur","year":"2020","journal-title":"J. Phys.\nChem. B"},{"key":"2026081308083615900_cit24","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jced.5c00695","article-title":"Thermodynamic study\nof amine-based deep eutectic solvents with H2O","volume":"71","author":"Zuo","year":"2026","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit25","doi-asserted-by":"publisher","first-page":"8685","DOI":"10.1039\/C8CS00325D","article-title":"The peculiar\neffect of water on ionic liquids and deep eutectic solvents","volume":"47","author":"Ma","year":"2018","journal-title":"Chem. Soc. Rev."},{"key":"2026081308083615900_cit26","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.153922","article-title":"Absorption\ncharacteristics and rheological properties of quaternized polyamine-based\ndeep eutectic solvents for high performance CO2 capture","volume":"496","author":"Ju","year":"2024","journal-title":"Chem. Eng. J."},{"key":"2026081308083615900_cit27","doi-asserted-by":"publisher","first-page":"24591","DOI":"10.1039\/C8CP03724H","article-title":"Intermolecular interactions upon\ncarbon dioxide capture\nin deep-eutectic solvents","volume":"20","author":"Shukla","year":"2018","journal-title":"Phys. Chem. Chem.\nPhys."},{"key":"2026081308083615900_cit28","doi-asserted-by":"publisher","first-page":"27306","DOI":"10.1039\/C5CP04050G","article-title":"Imidazole tailored\ndeep eutectic solvents for CO2 capture\nenhanced by hydrogen bonds","volume":"17","author":"Cao","year":"2015","journal-title":"Phys. Chem. Chem.\nPhys."},{"key":"2026081308083615900_cit29","doi-asserted-by":"publisher","DOI":"10.1016\/j.cep.2024.109859","article-title":"Study on CO2 absorption by EmimCl-MEA deep\neutectic solvent in microchannel","volume":"202","author":"Zhao","year":"2024","journal-title":"Chem. Eng.\nProcess"},{"key":"2026081308083615900_cit30","doi-asserted-by":"publisher","first-page":"3058","DOI":"10.1063\/1.1724948","article-title":"Dielectric constant of hydrogen bonded liquids. III.\nsuperheated alcohols","volume":"40","author":"Dannhauser","year":"1964","journal-title":"J. Chem. Phys."},{"key":"2026081308083615900_cit31","doi-asserted-by":"publisher","first-page":"962","DOI":"10.1007\/s10953-018-0793-1","article-title":"Insights\ninto the nature of eutectic\nand deep eutectic mixtures","volume":"48","author":"Martins","year":"2019","journal-title":"J. Solution Chem."},{"key":"2026081308083615900_cit32","doi-asserted-by":"publisher","DOI":"10.1063\/5.0053448","article-title":"Structural\nand dynamical changes observed when transitioning from an ionic liquid\nto a deep eutectic solvent","volume":"155","author":"Cui","year":"2021","journal-title":"J. Chem. Phys."},{"key":"2026081308083615900_cit33","doi-asserted-by":"publisher","first-page":"2699","DOI":"10.1021\/je400569s","article-title":"Improvement\nof quality in publication of experimental thermophysical property\ndata: Challenges, assessment tools, global implementation, and online\nsupport","volume":"58","author":"Chirico","year":"2013","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit34","doi-asserted-by":"publisher","first-page":"3377","DOI":"10.1021\/acs.jced.3c00537","article-title":"Physicochemical and thermodynamic\ninvestigation of ethanolic solution of phosphonium-based ionic liquids\u2500measurements,\ncorrelations, and application to absorption cycles","volume":"68","author":"Kro\u0301likowska","year":"2023","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit35","doi-asserted-by":"publisher","first-page":"869","DOI":"10.1021\/acs.jced.1c00924","article-title":"Thermodynamic properties of {diethyl\nphosphate-based\nionic liquid (1) + ethanol (2)} systems, experimental data and correlation","volume":"67","author":"Skonieczny","year":"2022","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit36","doi-asserted-by":"publisher","first-page":"65","DOI":"10.1021\/je500696p","article-title":"Phase equilibrium, excess enthalpies,\nand densities\nof binary mixtures of trimethylbutylammonium bis (trifluoromethylsulfonyl)\nimide with ethanol, 1-propanol, and dimethylformamide","volume":"60","author":"Massel","year":"2015","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit37","doi-asserted-by":"publisher","first-page":"4068","DOI":"10.1021\/je1002237","article-title":"Densities\nand excess molar volumes for binary mixtures of ionic liquid 1-ethyl-3-methylimidazolium\nethylsulfate with solvents","volume":"55","author":"Lehmann","year":"2010","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit38","doi-asserted-by":"publisher","DOI":"10.1016\/j.jct.2020.106241","article-title":"Density, viscosity\nand electrical conductivity of alcohol solutions of 2, 2-diethyl-1,\n1, 3, 3-tetramethylguanidinium bis (trifluoromethylsulfonyl) imide","volume":"151","author":"Lu","year":"2020","journal-title":"J. Chem. Thermodyn."},{"key":"2026081308083615900_cit39","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2020.113538","article-title":"Experimental\ndetermination\nof viscosity for the binary mixtures of the ether-functionalized ionic\nliquids [C22O1IM][TfO] with monohydric alcohols","volume":"313","author":"Wei","year":"2020","journal-title":"J. Mol. Liq."},{"key":"2026081308083615900_cit40","doi-asserted-by":"publisher","first-page":"5176","DOI":"10.1021\/acs.jced.0c00298","article-title":"Physical properties and its estimation\nof binary mixtures of ether-functionalized\nionic liquids [C22O1IM][NTF2] with alcohols","volume":"65","author":"Liu","year":"2020","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit41","doi-asserted-by":"publisher","first-page":"2618","DOI":"10.1021\/acs.jced.5b00259","article-title":"Densities\nand viscosities of binary mixtures of 2-ethyl-1, 1, 3, 3-tetramethylguanidinium\nionic liquids with ethanol and 1-propanol","volume":"60","author":"Lu","year":"2015","journal-title":"J.\nChem. Eng. Data"},{"key":"2026081308083615900_cit42","doi-asserted-by":"publisher","first-page":"216","DOI":"10.1021\/je60026a003","article-title":"Excess Thermodynamic Properties of\nAqueous Alcohol\nSolutions","volume":"10","author":"Lama","year":"1965","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit43","doi-asserted-by":"publisher","first-page":"318","DOI":"10.1021\/je60034a008","article-title":"Enthalpies\nof mixture of ethanol and water at 25. degree.\nC","volume":"12","author":"Boyne","year":"1967","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit44","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2022.119524","article-title":"Physicochemical properties of deep eutectic solvents:\nA review","volume":"360","author":"Omar","year":"2022","journal-title":"J. Mol. Liq."},{"key":"2026081308083615900_cit45","doi-asserted-by":"publisher","first-page":"6206","DOI":"10.1021\/jp501619y","article-title":"New experimental density data and soft-saft models\nof alkylimidazolium ([CnC1im]+) chloride\n(Cl\u2013), methylsulfate ([MeSO4]\u2212), and dimethylphosphate ([Me2PO4]\u2212) based ionic liquids","volume":"118","author":"Mac Dowell","year":"2014","journal-title":"J. Phys. Chem. B"},{"key":"2026081308083615900_cit46","doi-asserted-by":"publisher","first-page":"22479","DOI":"10.1021\/jp0634048","article-title":"Protic ionic liquids:\nSolvents with tunable phase behavior\nand physicochemical properties","volume":"110","author":"Greaves","year":"2006","journal-title":"J. Phys. Chem.\nB"},{"key":"2026081308083615900_cit47","doi-asserted-by":"publisher","first-page":"409","DOI":"10.1080\/00319100600744993","article-title":"Physical properties\nof the ternary mixture ethanol + water + 1-hexyl-3-methylimidazolium\nchloride at 298.15 K","volume":"44","author":"Go\u0301mez","year":"2006","journal-title":"Phys. Chem. Liq."},{"key":"2026081308083615900_cit48","doi-asserted-by":"publisher","first-page":"37","DOI":"10.1016\/j.jct.2019.01.025","article-title":"Volumetric properties\nof monoethanolamine and alcohol binary mixtures\nat different temperatures and 0.1 MPa","volume":"133","author":"Li","year":"2019","journal-title":"J. Chem.\nThermodyn."},{"key":"2026081308083615900_cit49","doi-asserted-by":"publisher","first-page":"343","DOI":"10.5488\/CMP.10.3.343","article-title":"Molecular\ntheory of partial molar volume and its applications to biomolecular\nsystems","volume":"10","author":"Imai","year":"2007","journal-title":"Condens. Matter Phys."},{"key":"2026081308083615900_cit50","doi-asserted-by":"publisher","first-page":"35537","DOI":"10.1007\/s11356-021-14485-2","article-title":"Insights into the relationships between physicochemical\nproperties, solvent performance, and applications of deep eutectic\nsolvents","volume":"28","author":"Zhang","year":"2021","journal-title":"Environ. Sci. Pollut. Res."},{"key":"2026081308083615900_cit51","doi-asserted-by":"publisher","first-page":"31","DOI":"10.1021\/je1007235","article-title":"Viscosities\nof acetate or chloride-based ionic liquids and some of their mixtures\nwith water or other common solvents","volume":"56","author":"Fendt","year":"2011","journal-title":"J. Chem.\nEng. Data"},{"key":"2026081308083615900_cit52","doi-asserted-by":"publisher","first-page":"206","DOI":"10.1021\/cr068040u","article-title":"Protic\nionic liquids: Properties and applications","volume":"108","author":"Greaves","year":"2008","journal-title":"Chem. Rev."},{"key":"2026081308083615900_cit53","doi-asserted-by":"publisher","first-page":"2446","DOI":"10.1021\/acs.jced.9b01113","article-title":"Thermodynamic\nstudy of choline chloride-based deep eutectic solvents with water\nand methanol","volume":"65","author":"Wang","year":"2020","journal-title":"J. Chem. Eng. Data"},{"key":"2026081308083615900_cit54","doi-asserted-by":"publisher","first-page":"283","DOI":"10.1063\/1.1749836","article-title":"Viscosity,\nplasticity, and diffusion as examples of absolute reaction rates","volume":"4","author":"Eyring","year":"1936","journal-title":"J. Chem. Phys."},{"key":"2026081308083615900_cit55","doi-asserted-by":"publisher","first-page":"1460","DOI":"10.1007\/s11814-014-0088-1","article-title":"Orientation effect\non sign and magnitude of excess thermodynamic functions of non electrolyte\nsolutions at different temperatures (303.15 K, 308.15 K, and 313.15K)","volume":"31","author":"Shaik","year":"2014","journal-title":"Korean J. Chem. Eng."},{"key":"2026081308083615900_cit56","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2021.106952","article-title":"Effect of\nwater on\namine-based deep eutectic solvents (choline chloride + monoethanolamine):\nStructure and physicochemical properties","volume":"10","author":"Li","year":"2022","journal-title":"J.\nEnviron. Chem. Eng."}],"container-title":["Journal of Chemical &amp;\nEngineering Data"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jced.6c00157","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jceaax\/article-pdf\/71\/8\/3381\/65882433\/acs.jced.6c00157.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jceaax\/article-pdf\/71\/8\/3381\/65882433\/acs.jced.6c00157.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T12:53:54Z","timestamp":1786625634000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jceaax\/article\/71\/8\/3381\/5206910\/Thermodynamic-Study-of-Amine-Based-Deep-Eutectic"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,13]]},"references-count":56,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2026,7,13]]},"published-print":{"date-parts":[[2026,8,13]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.jced.6c00157","relation":{},"ISSN":["0021-9568","1520-5134"],"issn-type":[{"value":"0021-9568","type":"print"},{"value":"1520-5134","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,13]]}}}