{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T09:07:03Z","timestamp":1788858423385,"version":"build-2803163510"},"reference-count":38,"publisher":"American Chemical Society (ACS)","issue":"15","license":[{"start":{"date-parts":[[2020,7,22]],"date-time":"2020-07-22T00:00:00Z","timestamp":1595376000000},"content-version":"vor","delay-in-days":12,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_ccby_termsofuse.html"}],"funder":[{"DOI":"10.13039\/501100002428","name":"Austrian Science Fund","doi-asserted-by":"publisher","award":["P 31276-B21"],"award-info":[{"award-number":["P 31276-B21"]}],"id":[{"id":"10.13039\/501100002428","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2020,8,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>3,3-Bis(2,4,6-triisopropylphenyl)-1,1-binaphthyl-2,2-diyl hydrogenphosphate (TRIP) catalyzes the asymmetric allylation of aldehydes with organozinc compounds, leading to highly valuable structural motifs, like precursors to lignan natural products. Our previously reported mechanistic proposal relies on two reaction intermediates and requires further investigation to really understand the mode of action and the origins of stereoselectivity. Detailed ab initio calculations, supported by experimental data, render a substantially different mode of action to the allyl boronate congener. Instead of a Br\u00f8nsted acid-based catalytic activation, the chiral phosphate acts as a counterion for the Lewis acidic zinc ion, which provides the activation of the aldehyde.<\/jats:p>","DOI":"10.1021\/acs.joc.0c00992","type":"journal-article","created":{"date-parts":[[2020,7,10]],"date-time":"2020-07-10T11:18:00Z","timestamp":1594379880000},"page":"9672-9679","source":"Crossref","is-referenced-by-count":7,"title":["Mechanistic Studies\nof the TRIP-Catalyzed Allylation\nwith Organozinc Reagents"],"prefix":"10.1021","volume":"85","author":[{"given":"Peter E.","family":"Hartmann","sequence":"first","affiliation":[{"name":"University of Graz , , Heinrichstrasse 28\/II , , ,","place":["Graz, Austria, Europe, 8010"]},{"name":"University of Graz , , Heinrichstrasse 28\/IV , , ,","place":["Graz, Austria, Europe, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mattia","family":"Lazzarotto","sequence":"additional","affiliation":[{"name":"University of Graz , , Heinrichstrasse 28\/II , , ,","place":["Graz, Austria, Europe, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jakob","family":"Pletz","sequence":"additional","affiliation":[{"name":"University of Graz , , Heinrichstrasse 28\/II , , ,","place":["Graz, Austria, Europe, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8654-4057","authenticated-orcid":true,"given":"Stefan","family":"Tanda","sequence":"additional","affiliation":[{"name":"University of Graz , , Universita\u0308tsplatz 1\/I , , ,","place":["Graz, Austria, Europe, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Philipp","family":"Neu","sequence":"additional","affiliation":[{"name":"University of Graz , , Heinrichstrasse 28\/II , , ,","place":["Graz, Austria, Europe, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Walter","family":"Goessler","sequence":"additional","affiliation":[{"name":"University of Graz , , Universita\u0308tsplatz 1\/I , , ,","place":["Graz, Austria, Europe, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2151-6394","authenticated-orcid":true,"given":"Wolfgang","family":"Kroutil","sequence":"additional","affiliation":[{"name":"University of Graz , , Heinrichstrasse 28\/II , , ,","place":["Graz, Austria, Europe, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7388-778X","authenticated-orcid":true,"given":"A. 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