{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T17:56:42Z","timestamp":1788199002820,"version":"build-2803163510"},"reference-count":45,"publisher":"American Chemical Society (ACS)","issue":"6","license":[{"start":{"date-parts":[[2021,2,17]],"date-time":"2021-02-17T00:00:00Z","timestamp":1613520000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2021,2,17]],"date-time":"2021-02-17T00:00:00Z","timestamp":1613520000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2021,2,17]],"date-time":"2021-02-17T00:00:00Z","timestamp":1613520000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21172201"],"award-info":[{"award-number":["21172201"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Org. Chem."],"published-print":{"date-parts":[[2021,3,19]]},"DOI":"10.1021\/acs.joc.0c02953","type":"journal-article","created":{"date-parts":[[2021,2,18]],"date-time":"2021-02-18T04:55:33Z","timestamp":1613624133000},"page":"4512-4531","source":"Crossref","is-referenced-by-count":14,"title":["Investigation of the Stereochemical Mechanism of the Nucleophilic Substitution Reaction at Pentacoordinate Phosphorus of Spirophosphorane"],"prefix":"10.1021","volume":"86","author":[{"given":"Kehui","family":"Han","sequence":"first","affiliation":[{"name":"Green Catalysis Center, College of Chemistry, Zhengzhou University, Kexue Road No. 100, Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanyan","family":"Wang","sequence":"additional","affiliation":[{"name":"Green Catalysis Center, College of Chemistry, Zhengzhou University, Kexue Road No. 100, Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pei","family":"Zhao","sequence":"additional","affiliation":[{"name":"Green Catalysis Center, College of Chemistry, Zhengzhou University, Kexue Road No. 100, Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaohui","family":"You","sequence":"additional","affiliation":[{"name":"Green Catalysis Center, College of Chemistry, Zhengzhou University, Kexue Road No. 100, Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Wang","sequence":"additional","affiliation":[{"name":"Green Catalysis Center, College of Chemistry, Zhengzhou University, Kexue Road No. 100, Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1214-5525","authenticated-orcid":true,"given":"Yanchun","family":"Guo","sequence":"additional","affiliation":[{"name":"Green Catalysis Center, College of Chemistry, Zhengzhou University, Kexue Road No. 100, Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yufen","family":"Zhao","sequence":"additional","affiliation":[{"name":"Green Catalysis Center, College of Chemistry, Zhengzhou University, Kexue Road No. 100, Zhengzhou 450001, China"},{"name":"Institute Drug Discovery Technology, Ningbo University, Ningbo, Zhejiang 315211, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4325-5527","authenticated-orcid":true,"given":"Shuxia","family":"Cao","sequence":"additional","affiliation":[{"name":"Green Catalysis Center, College of Chemistry, Zhengzhou University, Kexue Road No. 100, Zhengzhou 450001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2021,2,17]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1082710"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60105f"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b13803"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4039(95)00266-F"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1039\/b106501g"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/ja053422n"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1021\/jo060358z"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/ja9621408"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1039\/B304420C"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200700971"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/ja906875d"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.09.025"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201701718"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.5756"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(97)00837-X"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1007\/s00726-005-0207-8"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1039\/b909786d"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1039\/jr9450000660"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1039\/jr9470000674"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/jo100473s"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2013.09.001"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.10.117"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.7b01326"},{"key":"ref24\/cit24","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1002\/9783527672240.ch5","volume-title":"Organophosphorus Chemistry: From Molecules to Applications","author":"Yoshifuji M.","year":"2019"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.3390\/molecules21111573"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b01861"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20001002)6:19<3575::AID-CHEM3575>3.3.CO;2-R"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1063\/1.1730820"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/ja105306s"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01133"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/ja026776c"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/ic0609047"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2012.09.056"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetasy.2009.05.009"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1080\/10426507.2014.991824"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2019.130886"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/cr068021k"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.201701363"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1021\/jo4018342"},{"key":"ref40\/cit40","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, O.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J. Gaussian 09, revision C.01; Gaussian, Inc.: Wallingford, CT, 2009."},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(89)87234-3"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1007\/s00214-007-0310-x"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1021\/jp810292n"}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.0c02953","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,26]],"date-time":"2023-04-26T01:39:16Z","timestamp":1682473156000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.joc.0c02953"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,2,17]]},"references-count":45,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2021,3,19]]}},"alternative-id":["10.1021\/acs.joc.0c02953"],"URL":"https:\/\/doi.org\/10.1021\/acs.joc.0c02953","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,2,17]]}}}