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J., Sr., Ed.  Sax\u2019s Dangerous Properties of Industrial Materials, 11th ed. Wiley-Interscience, Wiley & Sons, Inc: Hoboken, NJ, 2004; p 2436."},{"key":"ref4\/cit4c","unstructured":"c Anhydrous DCM is not corrosive\nfor most metals, but in the presence of water, it slowly hydrolyzes\nreleasing small amounts of HCl, which can attack stainless steel,\naluminum, or even copper pipes. See any dichlorometane Safety Data\nSheet (MSDS, e.g., Fisher, ACC no. 14930)."},{"key":"ref4\/cit4d","doi-asserted-by":"publisher","DOI":"10.1021\/jo100276m"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00864a026"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201603303"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201809341"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/ed081p1415"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1021\/cr800399g"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201500753"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.1081\/SCC-120018774"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15962"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2015.02.021"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1002\/9783527805624.ch4"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2016.01.060"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201606427"},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702905"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1021\/jm020949r"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2003.11.032"},{"key":"ref11\/cit11c","doi-asserted-by":"publisher","DOI":"10.1021\/jm500139a"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4020(95)00632-I"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(02)01151-8"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1039\/B401425A"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201501263"},{"key":"ref14\/cit14a","doi-asserted-by":"publisher","DOI":"10.1021\/ja8025938"},{"key":"ref14\/cit14b","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2016.07.056"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC06465C"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1002\/slct.201600019"},{"key":"ref17\/cit17a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b02141"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00879"},{"key":"ref18\/cit18a","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC05551F"},{"key":"ref18\/cit18b","doi-asserted-by":"publisher","DOI":"10.1039\/C9CY02172H"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.8b00579"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915534"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC07661H"},{"key":"ref22\/cit22a","doi-asserted-by":"publisher","DOI":"10.1021\/jp513020y"},{"key":"ref22\/cit22b","doi-asserted-by":"publisher","DOI":"10.1021\/ac60366a030"},{"key":"ref23\/cit23a","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2015.04.031"},{"key":"ref23\/cit23b","doi-asserted-by":"publisher","DOI":"10.1039\/C5CY01858G"},{"key":"ref23\/cit23c","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY01030G"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2008.02.014"},{"key":"ref25\/cit25a","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.18872400204"},{"key":"ref25\/cit25b","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19370700807"},{"key":"ref26\/cit26","unstructured":"Direct separation of methylal from DCM is a technical\nproblem that\ncan be efficiently addressed by special distillation techniques. See,\nfor example:Berg, L. Separation of methylene vhloride from methylal by extractive distillation. US Patent US5051153A. Sept. 24, 1991."},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15206H"},{"key":"ref28\/cit28","unstructured":"The\nTOF figure allows\nan estimation of the pseudo-first-order rate for the dichloromethane\nactivation in the order k\u2032 \u2248  10\u20132 s\u20131 (=45 h\u20131\/3600\ns h\u20131). We have shown before that the reaction of 1a with DCM is very slow at room temperature but completes\nwithin 24 h at 60 \u00b0C. 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