{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T02:28:46Z","timestamp":1778552926193,"version":"3.51.4"},"reference-count":52,"publisher":"American Chemical Society (ACS)","issue":"13","license":[{"start":{"date-parts":[[2026,3,24]],"date-time":"2026-03-24T00:00:00Z","timestamp":1774310400000},"content-version":"vor","delay-in-days":365,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100007480","name":"Universidad de Castilla-La Mancha","doi-asserted-by":"publisher","award":["2021-GRIN-31240"],"award-info":[{"award-number":["2021-GRIN-31240"]}],"id":[{"id":"10.13039\/501100007480","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011033","name":"Agencia Estatal de Investigaci?n","doi-asserted-by":"publisher","award":["PID2020117788RB-I00"],"award-info":[{"award-number":["PID2020117788RB-I00"]}],"id":[{"id":"10.13039\/501100011033","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011033","name":"Agencia Estatal de Investigaci?n","doi-asserted-by":"publisher","award":["PID2023-147240OB-I00"],"award-info":[{"award-number":["PID2023-147240OB-I00"]}],"id":[{"id":"10.13039\/501100011033","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011033","name":"Agencia Estatal de Investigaci?n","doi-asserted-by":"publisher","award":["RED2022134287-T"],"award-info":[{"award-number":["RED2022134287-T"]}],"id":[{"id":"10.13039\/501100011033","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008530","name":"European Regional Development Fund","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011698","name":"Junta de Comunidades de Castilla-La Mancha","doi-asserted-by":"publisher","award":["SBPLY\/21\/180501\/000132"],"award-info":[{"award-number":["SBPLY\/21\/180501\/000132"]}],"id":[{"id":"10.13039\/501100011698","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002850","name":"Fondo Nacional de Desarrollo Cient?fico y Tecnol?gico","doi-asserted-by":"publisher","award":["11230124"],"award-info":[{"award-number":["11230124"]}],"id":[{"id":"10.13039\/501100002850","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002850","name":"Fondo Nacional de Desarrollo Cient?fico y Tecnol?gico","doi-asserted-by":"publisher","award":["1220241"],"award-info":[{"award-number":["1220241"]}],"id":[{"id":"10.13039\/501100002850","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002850","name":"Fondo Nacional de Desarrollo Cient?fico y Tecnol?gico","doi-asserted-by":"publisher","award":["3220023"],"award-info":[{"award-number":["3220023"]}],"id":[{"id":"10.13039\/501100002850","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002850","name":"Fondo Nacional de Desarrollo Cient?fico y Tecnol?gico","doi-asserted-by":"publisher","award":["FOVI230027"],"award-info":[{"award-number":["FOVI230027"]}],"id":[{"id":"10.13039\/501100002850","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Org. Chem."],"published-print":{"date-parts":[[2025,4,4]]},"DOI":"10.1021\/acs.joc.4c03070","type":"journal-article","created":{"date-parts":[[2025,3,24]],"date-time":"2025-03-24T19:30:10Z","timestamp":1742844610000},"page":"4560-4570","source":"Crossref","is-referenced-by-count":2,"title":["Amino Acids as Catalysts for the Regioselective Rearrangement of Epoxides into Ketones"],"prefix":"10.1021","volume":"90","author":[{"given":"Francisca","family":"Werlinger","sequence":"first","affiliation":[{"name":"Facultad de Ciencias Qu\u00edmicas y Farmac\u00e9uticas, Departamento de Qu\u00edmica Org\u00e1nica y Fisicoqu\u00edmica, Universidad de Chile, Sergio Livingstone 1007, Casilla 233, Metropolitan Region, Santiago 8380492, Chile"},{"name":"Departamento de Qu\u00edmica Org\u00e1nica, Facultad de Qu\u00edmica, Universidad de Concepci\u00f3n, Edmundo Larenas 129, Concepci\u00f3n 4070371, Chile"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Enrique","family":"Franc\u00e9s-Poveda","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica Org\u00e1nica y Bioqu\u00edmica-Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2212CINQA) Facultad de Ciencias y Tecnolog\u00edas Qu\u00edmicas and Instituto Regional de Investigaci\u00f3n Cient\u00edfica Aplicada-IRICA","place":["Ciudad Real, Spain"]},{"name":"Universidad de Castilla-La Mancha","place":["Ciudad Real, Spain"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Oscar A.","family":"Douglas-Gallardo","sequence":"additional","affiliation":[{"name":"Instituto de Ciencias Qu\u00edmicas, Facultad de Ciencias, Universidad Austral de Chile, Independencia 631, Isla Teja 509000, Valdivia, Chile"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marta","family":"Navarro","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica Org\u00e1nica y Bioqu\u00edmica-Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2212CINQA) Facultad de Ciencias y Tecnolog\u00edas Qu\u00edmicas and Instituto Regional de Investigaci\u00f3n Cient\u00edfica Aplicada-IRICA","place":["Ciudad Real, Spain"]},{"name":"Universidad de Castilla-La Mancha","place":["Ciudad Real, Spain"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1079-6730","authenticated-orcid":true,"given":"Oleksandra S.","family":"Trofymchuk","sequence":"additional","affiliation":[{"name":"Facultad de Ciencias Qu\u00edmicas y Farmac\u00e9uticas, Departamento de Qu\u00edmica Org\u00e1nica y Fisicoqu\u00edmica, Universidad de Chile, Sergio Livingstone 1007, Casilla 233, Metropolitan Region, Santiago 8380492, Chile"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3720-9345","authenticated-orcid":true,"given":"Felipe","family":"de la Cruz-Martinez","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica Org\u00e1nica y Bioqu\u00edmica-Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2212CINQA) Facultad de Ciencias y Tecnolog\u00edas Qu\u00edmicas and Instituto Regional de Investigaci\u00f3n Cient\u00edfica Aplicada-IRICA","place":["Ciudad Real, Spain"]},{"name":"Universidad de Castilla-La Mancha","place":["Ciudad Real, Spain"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Juan","family":"Tejeda","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica Org\u00e1nica y Bioqu\u00edmica-Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2212CINQA) Facultad de Ciencias y Tecnolog\u00edas Qu\u00edmicas and Instituto Regional de Investigaci\u00f3n Cient\u00edfica Aplicada-IRICA","place":["Ciudad Real, Spain"]},{"name":"Universidad de Castilla-La Mancha","place":["Ciudad Real, Spain"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1538-0689","authenticated-orcid":true,"given":"Javier","family":"Mart\u00ednez","sequence":"additional","affiliation":[{"name":"Facultad de Ciencias Qu\u00edmicas y Farmac\u00e9uticas, Departamento de Qu\u00edmica Org\u00e1nica y Fisicoqu\u00edmica, Universidad de Chile, Sergio Livingstone 1007, Casilla 233, Metropolitan Region, Santiago 8380492, Chile"},{"name":"Instituto de Ciencias Qu\u00edmicas, Facultad de Ciencias, Universidad Austral de Chile, Independencia 631, Isla Teja 509000, Valdivia, Chile"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6547-4862","authenticated-orcid":true,"given":"Agust\u00edn","family":"Lara-S\u00e1nchez","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica Org\u00e1nica y Bioqu\u00edmica-Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2212CINQA) Facultad de Ciencias y Tecnolog\u00edas Qu\u00edmicas and Instituto Regional de Investigaci\u00f3n Cient\u00edfica Aplicada-IRICA","place":["Ciudad Real, Spain"]},{"name":"Universidad de Castilla-La Mancha","place":["Ciudad Real, Spain"]}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2025,3,24]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1055\/s-1984-30921"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1039\/b104372m"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1021\/cr500036t"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202204889"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201900392"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c00770"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC09262E"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/ja00888a022"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)90389-8"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC05260A"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(99)01363-5"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/jo0303867"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(97)10363-5"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(85)87389-7"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201900594"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1039\/C4QO00324A"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.8b03171"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.201900164"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2017.05.018"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/cs501671a"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b10419"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/ja400325w"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1055\/s-2004-832842"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b05197"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.8b01448"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07514"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1039\/d0gc01870h"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2021.101840"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC02475J"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1039\/D1SE00060H"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1039\/D4OB00339J"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1039\/C3CY00769C"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC07154A"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2010.06.005"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202300102"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1021\/acs.oprd.1c00473"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2023.102659"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201700898"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201406645"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b00109"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1063\/1.5090222"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.81"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.1606"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jctc.1c00462"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1021\/ct400687b"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410637"},{"key":"ref49\/cit49","unstructured":"Http:\/\/Www.Iboview.Org\/Index.Html (accessed Feb 2, 2025)."},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1063\/1.1323224"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(94)00731-4"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1063\/1.4878664"}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.4c03070","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.4c03070","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,24]],"date-time":"2026-03-24T10:23:16Z","timestamp":1774347796000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.joc.4c03070"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,3,24]]},"references-count":52,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2025,4,4]]}},"alternative-id":["10.1021\/acs.joc.4c03070"],"URL":"https:\/\/doi.org\/10.1021\/acs.joc.4c03070","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,3,24]]}}}