{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T20:51:06Z","timestamp":1786999866065,"version":"build-2736575974"},"reference-count":46,"publisher":"American Chemical Society (ACS)","issue":"30","license":[{"start":{"date-parts":[[2025,7,17]],"date-time":"2025-07-17T00:00:00Z","timestamp":1752710400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,7,17]],"date-time":"2025-07-17T00:00:00Z","timestamp":1752710400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,7,17]],"date-time":"2025-07-17T00:00:00Z","timestamp":1752710400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Org. Chem."],"published-print":{"date-parts":[[2025,8,1]]},"DOI":"10.1021\/acs.joc.5c00719","type":"journal-article","created":{"date-parts":[[2025,7,17]],"date-time":"2025-07-17T17:02:58Z","timestamp":1752771778000},"page":"10919-10926","source":"Crossref","is-referenced-by-count":3,"title":["Controlled Switching from Spirobi[pyrrolo[1,2-\n                    <i>c<\/i>\n                    ]thiazoles] to Pyrrolo[1,2-\n                    <i>c<\/i>\n                    ]thiazole-3-thiones during the Cyclization of 2-Acylethynylpyrroles with Carbon Disulfide"],"prefix":"10.1021","volume":"90","author":[{"given":"Denis N.","family":"Tomilin","sequence":"first","affiliation":[{"name":"A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Science, 1 Favorsky Str., 664033 Irkutsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sophia A.","family":"Stepanova","sequence":"additional","affiliation":[{"name":"A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Science, 1 Favorsky Str., 664033 Irkutsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Igor A.","family":"Ushakov","sequence":"additional","affiliation":[{"name":"A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Science, 1 Favorsky Str., 664033 Irkutsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander V.","family":"Vashchenko","sequence":"additional","affiliation":[{"name":"A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Science, 1 Favorsky Str., 664033 Irkutsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0430-3215","authenticated-orcid":true,"given":"Boris A.","family":"Trofimov","sequence":"additional","affiliation":[{"name":"A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Science, 1 Favorsky Str., 664033 Irkutsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,7,17]]},"reference":[{"key":"ref1\/cit1a","first-page":"92","volume-title":"Targets Heterocycl. Syst.","volume":"13","author":"Trofimov B. A.","year":"2009"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1070\/RC2014v083n06ABEH004418"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.3390\/molecules25112490"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2004.06.114"},{"key":"ref3\/cit3","doi-asserted-by":"crossref","first-page":"211","DOI":"10.1007\/978-981-97-4308-7_7","volume-title":"S-Heterocycles: Synthesis and Biological Evaluation","author":"Teli P.","year":"2024"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1039\/D4MD00076E"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2012.11.036"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2014.04.008"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2012.03.030"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1111\/j.2042-7158.1996.tb03984.x"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1248\/cpb.43.1125"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/jm9803121"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/jo01314a046"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(00)00956-X"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/jo010807p"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201403407"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1055\/s-0032-1317115"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1055\/s-2004-836069"},{"key":"ref17\/cit17a","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2016.10.017"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.1023\/A:1014863511588"},{"key":"ref17\/cit17c","doi-asserted-by":"publisher","DOI":"10.1080\/02786110212862"},{"key":"ref17\/cit17d","doi-asserted-by":"publisher","DOI":"10.1021\/cr020100i"},{"key":"ref18\/cit18a","doi-asserted-by":"publisher","DOI":"10.1055\/s-2001-10819"},{"key":"ref18\/cit18b","doi-asserted-by":"publisher","DOI":"10.1023\/A:1012438104138"},{"key":"ref19\/cit19a","doi-asserted-by":"publisher","DOI":"10.3390\/molecules24224165"},{"key":"ref19\/cit19b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.0c01473"},{"key":"ref19\/cit19c","doi-asserted-by":"publisher","DOI":"10.3390\/molecules28145420"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2008.01.093"},{"key":"ref21\/cit21a","doi-asserted-by":"crossref","first-page":"83","DOI":"10.1007\/12_074","volume-title":"Emissive Materials Nanomaterials","author":"Pudzich R.","year":"2006"},{"key":"ref21\/cit21b","doi-asserted-by":"publisher","DOI":"10.1021\/cr0501341"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/jm00301a054"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1016\/j.bioorg.2017.01.018"},{"key":"ref24\/cit24","first-page":"800","volume":"3","author":"Vodela S.","year":"2014","journal-title":"World J. Pharm. Pharm. Sci."},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1016\/0223-5234(87)90175-9"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1002\/slct.201904941"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1080\/10426500802705164"},{"key":"ref28\/cit28a","doi-asserted-by":"publisher","DOI":"10.1016\/j.mencom.2024.06.037"},{"key":"ref28\/cit28b","doi-asserted-by":"publisher","DOI":"10.1016\/j.tchem.2023.100055"},{"key":"ref28\/cit28c","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-02801-9"},{"key":"ref28\/cit28d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b02498"},{"key":"ref29\/cit29a","doi-asserted-by":"publisher","DOI":"10.1107\/S0108270188010728"},{"key":"ref29\/cit29b","doi-asserted-by":"publisher","DOI":"10.1016\/S0166-1280(96)05023-3"},{"key":"ref30\/cit30a","doi-asserted-by":"crossref","first-page":"383","DOI":"10.1016\/B978-0-08-095843-9.00009-4","volume-title":"Handbook of Heterocyclic Chemistry","author":"Katritzky A. R.","year":"2010","edition":"3"},{"key":"ref30\/cit30b","doi-asserted-by":"crossref","DOI":"10.1002\/9781118380208","volume-title":"Heterocyclic Chemistry at a Glance","author":"Joule J. A.","year":"2012"},{"key":"ref30\/cit30c","doi-asserted-by":"crossref","DOI":"10.1201\/b17510","volume-title":"Chemistry of Pyrroles.","author":"Trofimov B. A.","year":"2014"},{"key":"ref31\/cit31","unstructured":"Dickstein, J. I.; Miller, S. I.In\n                      The Chemistry of the Carbon-Carbon Triple Bond\n                      ; Patai, S., Ed. Wiley: New York, 1978; Vol. 2, pp 813\u2013955."}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.5c00719","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.5c00719","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,8,1]],"date-time":"2025-08-01T08:13:23Z","timestamp":1754036003000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.joc.5c00719"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,17]]},"references-count":46,"journal-issue":{"issue":"30","published-print":{"date-parts":[[2025,8,1]]}},"alternative-id":["10.1021\/acs.joc.5c00719"],"URL":"https:\/\/doi.org\/10.1021\/acs.joc.5c00719","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,17]]}}}