{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,17]],"date-time":"2026-06-17T23:06:08Z","timestamp":1781737568487,"version":"3.54.5"},"reference-count":59,"publisher":"American Chemical Society (ACS)","issue":"25","license":[{"start":{"date-parts":[[2025,6,16]],"date-time":"2025-06-16T00:00:00Z","timestamp":1750032000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,6,16]],"date-time":"2025-06-16T00:00:00Z","timestamp":1750032000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,6,16]],"date-time":"2025-06-16T00:00:00Z","timestamp":1750032000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22203023"],"award-info":[{"award-number":["22203023"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22403028"],"award-info":[{"award-number":["22403028"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003453","name":"Natural Science Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2022A1515011859"],"award-info":[{"award-number":["2022A1515011859"]}],"id":[{"id":"10.13039\/501100003453","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100017127","name":"Shenzhen Government","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100017127","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Org. Chem."],"published-print":{"date-parts":[[2025,6,27]]},"DOI":"10.1021\/acs.joc.5c00745","type":"journal-article","created":{"date-parts":[[2025,6,16]],"date-time":"2025-06-16T20:31:42Z","timestamp":1750105902000},"page":"8665-8673","source":"Crossref","is-referenced-by-count":3,"title":["Binuclear Copper-Catalyzed Enantioselective C,N-Dipolar (3 + 2) Cycloadditions: Mechanistic Insights and Selectivity Control via DFT Analysis"],"prefix":"10.1021","volume":"90","author":[{"given":"Yu","family":"Wang","sequence":"first","affiliation":[{"name":"School of Science","place":["Shenzhen, China"]},{"name":"Harbin Institute of Technology (Shenzhen)","place":["Shenzhen, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linxing","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering","place":["Wuhan, China"]},{"name":"Hubei University","place":["Wuhan, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5418-5141","authenticated-orcid":true,"given":"Jia","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Science","place":["Shenzhen, China"]},{"name":"Harbin Institute of Technology (Shenzhen)","place":["Shenzhen, China"]},{"name":"School of Chemistry and Chemical Engineering","place":["Harbin, China"]},{"name":"Harbin Institute of Technology","place":["Harbin, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2349-642X","authenticated-orcid":true,"given":"Lijuan","family":"Song","sequence":"additional","affiliation":[{"name":"School of Science","place":["Shenzhen, China"]},{"name":"Harbin Institute of Technology (Shenzhen)","place":["Shenzhen, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,6,16]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2020.131422"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-46523-1"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-023-00416-1"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202303643"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1039\/C9RA02839K"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202300296"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1039\/D4OB00246F"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1039\/D4OB00607K"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/cr5007182"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202304471"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1515\/zna-1987-0717"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202301188"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c13412"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1126\/science.aau4821"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c02401"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05762"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2023.133435"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900693"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2022.09.010"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1039\/C7OB02476B"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c04388"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-024-07555-1"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202011825"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/ic980137e"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202400283"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c00723"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-022-00150-0"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423405"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217051"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202002672"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/ja312459b"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC02901G"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b00004"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2023.09.006"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201800100"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202003115"},{"key":"ref37\/cit37","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.; Nakatsuji, H.; Li, X.; Caricato, M.; Marenich, A. V.; Bloino, J.; Janesko, B. G.; Gomperts, R.; Mennucci, B.; Hratchian, H. P.; Ortiz, J. V.; Izmaylov, A. F.; Sonnenberg, J. L.; Williams; Ding, F.; Lipparini, F.; Egidi, F.; Goings, J.; Peng, B.; Petrone, A.; Henderson, T.; Ranasinghe, D.; Zakrzewski, V. G.; Gao, J.; Rega, N.; Zheng, G.; Liang, W.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Throssell, K.; Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M. J.; Heyd, J. J.; Brothers, E. N.; Kudin, K. N.; Staroverov, V. N.; Keith, T. A.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A. P.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Millam, J. M.; Klene, M.; Adamo, C.; Cammi, R.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Farkas, O.; Foresman, J. B.; Fox, D. J. Gaussian 16 Rev. C.01; Wallingford, CT, 2016."},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344"},{"key":"ref39\/cit39a","doi-asserted-by":"publisher","DOI":"10.1063\/1.448799"},{"key":"ref39\/cit39b","doi-asserted-by":"publisher","DOI":"10.1063\/1.448975"},{"key":"ref39\/cit39c","doi-asserted-by":"publisher","DOI":"10.1063\/1.448800"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.2c00530"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1039\/D3CY01309J"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1021\/jp810292n"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c08382"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2021.122233"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202208185"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c14150"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1021\/ja056207f"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.3c04374"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1016\/0263-7855(96)00018-5"},{"key":"ref50\/cit50","unstructured":"Legault, C. Y. CYLview 1.0b, Visualization and Analysis Software for Computational Chemistry. Universit\u00e9 de Sherbrooke, 2009, http:\/\/www.cylview.org (accessed January 16, 2023)."},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jctc.8b01176"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jctc.0c00549"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1021\/jo060502g"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1002\/poc.1320"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1021\/jp012603i"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1142\/S0219633612500113"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c09739"}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.5c00745","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.5c00745","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,6,27]],"date-time":"2025-06-27T08:12:34Z","timestamp":1751011954000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.joc.5c00745"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,16]]},"references-count":59,"journal-issue":{"issue":"25","published-print":{"date-parts":[[2025,6,27]]}},"alternative-id":["10.1021\/acs.joc.5c00745"],"URL":"https:\/\/doi.org\/10.1021\/acs.joc.5c00745","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,6,16]]}}}