{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,15]],"date-time":"2026-06-15T19:29:57Z","timestamp":1781551797448,"version":"3.54.5"},"reference-count":65,"publisher":"American Chemical Society (ACS)","issue":"47","license":[{"start":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T00:00:00Z","timestamp":1763337600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T00:00:00Z","timestamp":1763337600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T00:00:00Z","timestamp":1763337600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Org. Chem."],"published-print":{"date-parts":[[2025,11,28]]},"DOI":"10.1021\/acs.joc.5c01816","type":"journal-article","created":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T17:15:58Z","timestamp":1763399758000},"page":"16720-16729","source":"Crossref","is-referenced-by-count":2,"title":["Manganese-Catalyzed \u03b1-Alkylation of Ketones with Unactivated Secondary Alcohols: A Sustainable Route to \u03b2-Branched Ketones"],"prefix":"10.1021","volume":"90","author":[{"given":"Anjima","family":"T. L.","sequence":"first","affiliation":[{"name":"Main Group Organometallics Optoelectronic Materials and Catalysis Lab, Department of Chemistry","place":["Calicut, India"]},{"name":"National Institute of Technology","place":["Calicut, India"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7875-9517","authenticated-orcid":true,"given":"Chinna Ayya Swamy","family":"Pothulapadu","sequence":"additional","affiliation":[{"name":"Main Group Organometallics Optoelectronic Materials and Catalysis Lab, Department of Chemistry","place":["Calicut, India"]},{"name":"National Institute of Technology","place":["Calicut, India"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,11,17]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201800004"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1039\/C9OB02754H"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00101B"},{"key":"ref1\/cit1d","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202300542"},{"key":"ref1\/cit1e","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201701241"},{"key":"ref1\/cit1f","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2017.03.022"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1002\/open.202000175"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200400666"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507521"},{"key":"ref2\/cit2d","doi-asserted-by":"publisher","DOI":"10.1021\/cr100280d"},{"key":"ref2\/cit2e","doi-asserted-by":"publisher","DOI":"10.1021\/cr300095f"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202200474"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201601176"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00340"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200603794"},{"key":"ref4\/cit4c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.2c00520"},{"key":"ref4\/cit4d","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2016.10.002"},{"key":"ref4\/cit4e","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00496E"},{"key":"ref4\/cit4f","doi-asserted-by":"publisher","DOI":"10.1021\/cs400066q"},{"key":"ref4\/cit4g","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201705848"},{"key":"ref4\/cit4h","doi-asserted-by":"publisher","DOI":"10.1039\/B813383B"},{"key":"ref4\/cit4i","doi-asserted-by":"publisher","DOI":"10.1021\/cr9002159"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.2c03200"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c04098"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b01351"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.8b00013"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2005.06.043"},{"key":"ref6\/cit6d","doi-asserted-by":"publisher","DOI":"10.1021\/cs4005375"},{"key":"ref6\/cit6e","doi-asserted-by":"publisher","DOI":"10.1021\/jo502051d"},{"key":"ref6\/cit6f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.8b00043"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201506698"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201607072"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b00106"},{"key":"ref7\/cit7d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b02256"},{"key":"ref7\/cit7e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.8b02609"},{"key":"ref7\/cit7f","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201900438"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2006.10.042"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.9b01600"},{"key":"ref8\/cit8c","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b04013"},{"key":"ref8\/cit8d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c02787"},{"key":"ref8\/cit8e","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202200522"},{"key":"ref8\/cit8f","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2021.132051"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1021\/ja302710v"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC01708D"},{"key":"ref9\/cit9c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c00782"},{"key":"ref9\/cit9d","doi-asserted-by":"publisher","DOI":"10.1039\/D2CY00759B"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12840"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201900990"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c00549"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC08010K"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c05889"},{"key":"ref13\/cit13c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b01327"},{"key":"ref13\/cit13d","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.9b01246"},{"key":"ref13\/cit13e","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC03969K"},{"key":"ref13\/cit13f","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402575"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202501104"},{"key":"ref15\/cit15a","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b03720"},{"key":"ref15\/cit15b","doi-asserted-by":"publisher","DOI":"10.1039\/D3DT04321E"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC01460E"},{"key":"ref17\/cit17a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.4c00145"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202401841"},{"key":"ref17\/cit17c","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202502889"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202401986"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1039\/dt9880002927"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1039\/D4OB00351A"}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.5c01816","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.5c01816","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,28]],"date-time":"2025-11-28T09:11:32Z","timestamp":1764321092000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.joc.5c01816"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11,17]]},"references-count":65,"journal-issue":{"issue":"47","published-print":{"date-parts":[[2025,11,28]]}},"alternative-id":["10.1021\/acs.joc.5c01816"],"URL":"https:\/\/doi.org\/10.1021\/acs.joc.5c01816","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,11,17]]}}}