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An inexpensive organic dye, eosin Y, catalyzes coupling of Boc-protected potassium \u03b1-aminomethyltrifluoroborates with a variety of substituted alkenyl sulfones through an \u03b1-aminomethyl radical addition\u2013elimination pathway. Allylic and homoallylic amines were formed in moderate yields with high E\/Z selectivity. The mechanistic approach was extended using tosyl cyanide as a radical trap, enabling the conversion of alkyltrifluoroborates to nitriles via a Fukuzumi acridinium-catalyzed process.<\/jats:p>","DOI":"10.1021\/acs.joc.6b01207","type":"journal-article","created":{"date-parts":[[2016,6,23]],"date-time":"2016-06-23T11:59:29Z","timestamp":1466683169000},"page":"7308-7313","source":"Crossref","is-referenced-by-count":132,"title":["Visible-Light-Mediated\nAlkenylation, Allylation, and\nCyanation of Potassium Alkyltrifluoroborates with Organic Photoredox\nCatalysts"],"prefix":"10.1021","volume":"81","author":[{"given":"Drew R.","family":"Heitz","sequence":"first","affiliation":[{"name":"University of Pennsylvania , , 231 South 34th Street , , ,","place":["Philadelphia, Pennsylvania, United States, 19104-6323"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Komal","family":"Rizwan","sequence":"additional","affiliation":[{"name":"University of Pennsylvania , , 231 South 34th Street , , ,","place":["Philadelphia, Pennsylvania, United States, 19104-6323"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gary A.","family":"Molander","sequence":"additional","affiliation":[{"name":"University of Pennsylvania , , 231 South 34th Street , , ,","place":["Philadelphia, Pennsylvania, United States, 19104-6323"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2016,6,23]]},"reference":[{"key":"2026090115015362900_cit1","doi-asserted-by":"publisher","first-page":"102","DOI":"10.1039\/B913880N","volume":"40","author":"Narayanam","year":"2011","journal-title":"Chem. 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