{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T15:27:17Z","timestamp":1787412437380,"version":"build-2736575974"},"reference-count":49,"publisher":"American Chemical Society (ACS)","issue":"33","license":[{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100007101","name":"Liaocheng University","doi-asserted-by":"publisher","award":["31805403"],"award-info":[{"award-number":["31805403"]}],"id":[{"id":"10.13039\/501100007101","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["ZR2023MB018"],"award-info":[{"award-number":["ZR2023MB018"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>In this study, we disclose a Cu(OTf)2-catalyzed regioselective nucleophilic amination of quinones to synthesize 3,5-, 3,6-, and mixed diaminoquinones under air. The regioselectivity, controlled by the catalyst coordination and the steric hindrance of amines, follows different patterns: the reactions with anilines afforded the 3,6-diaminoquinones; the coupling with aliphatic primary amines led to the formation of a mixture of 3,6- and 3,5-isomers; and the use of sterically hindered secondary amines delivered the 3,5-isomers. Furthermore, we found that the synthesized diaminoquinones exhibited stable and strong photocurrent responses, suggesting potential applications in optoelectronic materials.<\/jats:p>","DOI":"10.1021\/acs.joc.6c00684","type":"journal-article","created":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T15:02:21Z","timestamp":1786460541000},"page":"11260-11273","source":"Crossref","is-referenced-by-count":0,"title":["Regioselective Nucleophilic\nDiamination of Quinones\nEnabling Access to 3,5-, 3,6-, and Mixed Diamino Derivatives:\nSynthesis and Photocurrent Characterization"],"prefix":"10.1021","volume":"91","author":[{"given":"Wenjing","family":"Lu","sequence":"first","affiliation":[{"name":"Liaocheng University , , 1 Hunan Avenue , , ,","place":["Liaocheng, Shandong, P. R. 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China, 318000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0631-1913","authenticated-orcid":true,"given":"Guodong","family":"Shen","sequence":"additional","affiliation":[{"name":"Liaocheng University , , 1 Hunan Avenue , , ,","place":["Liaocheng, Shandong, P. R. China, 252000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,11]]},"reference":[{"key":"2026082211140264500_cit1a","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202500184","article-title":"Recent\nGreen and Sustainable Pd-Catalyzed Aminations","volume":"18","author":"Saunders","year":"2025","journal-title":"ChemSusChem"},{"key":"2026082211140264500_cit1b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202420312","article-title":"Universal Reagent for Mild and Stereospecific\nNucleophilic Substitution of Alcohols with Amines","volume":"64","author":"Bechara","year":"2025","journal-title":"Angew. 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