{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T09:05:12Z","timestamp":1785143112862,"version":"3.55.0"},"reference-count":72,"publisher":"American Chemical Society (ACS)","issue":"29","license":[{"start":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T00:00:00Z","timestamp":1783728000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T00:00:00Z","timestamp":1783728000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T00:00:00Z","timestamp":1783728000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100007063","name":"University of Delhi","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100007063","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research, India","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Org. Chem."],"published-print":{"date-parts":[[2026,7,24]]},"DOI":"10.1021\/acs.joc.6c00873","type":"journal-article","created":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T13:30:02Z","timestamp":1783776602000},"page":"10072-10087","source":"Crossref","is-referenced-by-count":0,"title":["Broadening the Steroidal Toolkit by Late-Stage \u03b3-C(sp\n                    <b>\n                      <sup>3<\/sup>\n                    <\/b>\n                    )-H (Hetero)arylation of Homologously Dissected Deoxycholic Acid"],"prefix":"10.1021","volume":"91","author":[{"given":"Somnath Arjun","family":"Borade","sequence":"first","affiliation":[{"name":"Department of Chemistry","place":["Pilani, India"]},{"name":"Birla Institute of Technology and Science","place":["Pilani, India"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Disha Harsukhbhai","family":"Tank","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Pilani, India"]},{"name":"Birla Institute of Technology and Science","place":["Pilani, India"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sonia","family":"Guha","sequence":"additional","affiliation":[{"name":"Department of Pharmacy","place":["Pilani, India"]},{"name":"Birla Institute of Technology and Science","place":["Pilani, India"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4483-4747","authenticated-orcid":true,"given":"Kiran","family":"Bajaj","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Amity Institute of Applied Sciences","place":["Noida, India"]},{"name":"Amity University","place":["Noida, India"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3668-104X","authenticated-orcid":true,"given":"Siva S.","family":"Panda","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry","place":["Augusta, United States"]},{"name":"Augusta University","place":["Augusta, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4174-7664","authenticated-orcid":true,"given":"Deepak","family":"Chitkara","sequence":"additional","affiliation":[{"name":"Department of Pharmacy","place":["Pilani, India"]},{"name":"Birla Institute of Technology and Science","place":["Pilani, India"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9284-9137","authenticated-orcid":true,"given":"Rajeev","family":"Sakhuja","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Pilani, India"]},{"name":"Birla Institute of Technology and Science","place":["Pilani, India"]},{"name":"Department of Chemistry","place":["Delhi, India"]},{"name":"University of Delhi","place":["Delhi, India"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,11]]},"reference":[{"key":"ref1\/cit1a","first-page":"42","volume":"1","author":"Rajput J. M.","year":"2023","journal-title":"Int. J. Pharm. Res. Allied Sci."},{"issue":"7","key":"ref1\/cit1b","first-page":"3121","volume":"11","author":"Saini A.","year":"2020","journal-title":"Int. J. Pharm. Sci. Res."},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.57238\/jbb.2025.7432.1141"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1016\/j.cancergen.2024.06.002"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.3747\/co.27.5223"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1186\/s43556-025-00321-3"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.3389\/fphar.2018.00939"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.3389\/fphar.2018.01283"},{"key":"ref3\/cit3d","doi-asserted-by":"publisher","DOI":"10.3390\/ijms22041780"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1002\/j.2040-4603.2013.tb00517.x"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.3390\/ijms19071875"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4039(93)89021-H"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1021\/bc300664k"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1039\/D1BM00031D"},{"key":"ref5\/cit5d","doi-asserted-by":"publisher","DOI":"10.3390\/molecules26010025"},{"key":"ref5\/cit5e","doi-asserted-by":"publisher","DOI":"10.1016\/j.bioorg.2022.106036"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.steroids.2017.01.008"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1007\/s11033-023-09106-9"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.3389\/fphar.2024.1362382"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.3389\/fonc.2022.813745"},{"key":"ref7\/cit7d","doi-asserted-by":"publisher","DOI":"10.3390\/nu14142964"},{"key":"ref7\/cit7e","doi-asserted-by":"publisher","DOI":"10.1039\/D2MD00220E"},{"key":"ref7\/cit7f","doi-asserted-by":"publisher","DOI":"10.3389\/fonc.2021.778258"},{"key":"ref7\/cit7g","doi-asserted-by":"publisher","DOI":"10.2174\/156800906779010236"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.2298\/HEMIND0904313K"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1016\/j.bbabio.2018.04.002"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1016\/j.steroids.2015.12.022"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1016\/j.steroids.2018.09.006"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1007\/s11030-017-9797-9"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.3390\/molecules26195741"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00888"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00064B"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00519"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202516620"},{"key":"ref15\/cit15a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00622"},{"key":"ref15\/cit15b","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00201K"},{"key":"ref15\/cit15c","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00408F"},{"key":"ref15\/cit15d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00220"},{"key":"ref15\/cit15e","doi-asserted-by":"publisher","DOI":"10.1039\/c0cy00076k"},{"key":"ref15\/cit15f","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201900532"},{"key":"ref15\/cit15g","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201301451"},{"key":"ref16\/cit16a","doi-asserted-by":"publisher","DOI":"10.1021\/ja910900p"},{"key":"ref16\/cit16b","doi-asserted-by":"publisher","DOI":"10.1021\/ja054549f"},{"key":"ref17\/cit17a","doi-asserted-by":"publisher","DOI":"10.1021\/ar5004626"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00495"},{"key":"ref17\/cit17c","doi-asserted-by":"publisher","DOI":"10.1016\/j.trechm.2023.05.003"},{"key":"ref18\/cit18a","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2022.04.018"},{"key":"ref18\/cit18b","doi-asserted-by":"publisher","DOI":"10.1360\/SSC-2022-0253"},{"key":"ref18\/cit18c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.7b00582"},{"key":"ref18\/cit18d","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.202200589"},{"key":"ref18\/cit18e","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.202200311"},{"key":"ref18\/cit18f","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.202000284"},{"key":"ref18\/cit18g","doi-asserted-by":"publisher","DOI":"10.1055\/a-1830-3962"},{"key":"ref18\/cit18h","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214255"},{"key":"ref18\/cit18i","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201907262"},{"key":"ref18\/cit18j","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC03144E"},{"key":"ref18\/cit18k","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c02790"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1038\/nature10785"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/ja801355s"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2326"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5c00476"},{"key":"ref23\/cit23a","doi-asserted-by":"publisher","DOI":"10.1021\/ja046831c"},{"key":"ref23\/cit23b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201710330"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/ja206002m"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1039\/D3OB00916E"},{"key":"ref26\/cit26a","doi-asserted-by":"publisher","DOI":"10.1021\/ar300083h"},{"key":"ref26\/cit26b","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2007.09.023"},{"key":"ref26\/cit26c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200390319"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-2275(20)38445-5"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2024.109783"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1039\/D2QO00478J"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.4c04390"}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.6c00873","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/joceah\/article-pdf\/91\/29\/10072\/65882504\/acs.joc.6c00873.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.6c00873","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T08:20:03Z","timestamp":1785140403000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.joc.6c00873"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,11]]},"references-count":72,"journal-issue":{"issue":"29","published-print":{"date-parts":[[2026,7,24]]}},"alternative-id":["10.1021\/acs.joc.6c00873"],"URL":"https:\/\/doi.org\/10.1021\/acs.joc.6c00873","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,11]]}}}