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This green method avoids metals and toxic additives, accommodates 35 examples including chromone-fused pyrroles and polycyclic indoles, and scales well. Mechanistic investigations confirm the EDA complex pathway upon light irradiation, showcasing EDA chemistry as a sustainable tool for bioactive heterocycle construction.<\/jats:p>","DOI":"10.1021\/acs.joc.6c00984","type":"journal-article","created":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T15:02:32Z","timestamp":1787238152000},"page":"11941-11951","source":"Crossref","is-referenced-by-count":1,"title":["Visible-Light-Promoted\nEDA Complex Activation for\nSynthesis of 3-Cyano-4,5-Dihydropyrroles Under Open-Air Conditions"],"prefix":"10.1021","volume":"91","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-3152-364X","authenticated-orcid":true,"given":"Gui-Ting","family":"Song","sequence":"first","affiliation":[{"name":"Chongqing University of Arts and Sciences , , ,","place":["Chongqing, China, 402160"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen-Bin","family":"Zong","sequence":"additional","affiliation":[{"name":"Chongqing University of Arts and Sciences , , ,","place":["Chongqing, China, 402160"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao-Jin","family":"Xiao","sequence":"additional","affiliation":[{"name":"Chongqing University of Arts and Sciences , , ,","place":["Chongqing, China, 402160"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li-Sha","family":"Zheng","sequence":"additional","affiliation":[{"name":"Chongqing University of Arts and Sciences , , ,","place":["Chongqing, China, 402160"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia-Yi","family":"Chen","sequence":"additional","affiliation":[{"name":"Chongqing University of Arts and Sciences , , ,","place":["Chongqing, China, 402160"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Liu","sequence":"additional","affiliation":[{"name":"Chongqing University of Arts and Sciences , , ,","place":["Chongqing, China, 402160"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng-Lian","family":"Qin","sequence":"additional","affiliation":[{"name":"Chongqing University of Arts and Sciences , , ,","place":["Chongqing, China, 402160"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3821-3963","authenticated-orcid":true,"given":"Chuan-Hua","family":"Qu","sequence":"additional","affiliation":[{"name":"Chongqing University of Arts and Sciences , , ,","place":["Chongqing, China, 402160"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,20]]},"reference":[{"key":"2026090408095988900_cit1a","volume-title":"Modern Alkaloids:\nStructure, Isolation, Synthesis and Biology","author":"Fattorusso","year":"2008"},{"key":"2026090408095988900_cit1b","doi-asserted-by":"publisher","first-page":"2087","DOI":"10.1016\/S0040-4020(01)96119-8","article-title":"Mirabimides A\u2013D, New N-Acylpyrrolinones from the Blue-Green Alga Scytonema Mirabile","volume":"47","author":"Carmeli","year":"1991","journal-title":"Tetrahedron"},{"key":"2026090408095988900_cit1c","doi-asserted-by":"publisher","first-page":"4909","DOI":"10.1021\/jf020281p","article-title":"New Sources of Dietary\nMyosmine Uptake from Cereals, Fruits, Vegetables, and Milk","volume":"50","author":"Tyroller","year":"2002","journal-title":"J. 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