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This method provides efficient access to a broad array of C3-brominated heteroarenes, including quinoxalin-2(1H)-ones, cinnolin-4(1H)-ones, coumarins, and oxazinone derivatives, in moderate to good yields (38 examples). Notably, this approach is applicable to both the late-stage functionalization of complex pharmaceutical agents and gram-scale synthesis. Mechanistic studies indicate that trifluoroacetic acid plays a crucial role in the reaction.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01075","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T14:02:15Z","timestamp":1785852135000},"page":"10905-10916","source":"Crossref","is-referenced-by-count":2,"title":["K2S2O8\u2013Promoted\nC3-Bromination of Heteroarenes with Sodium Bromide"],"prefix":"10.1021","volume":"91","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2203-4039","authenticated-orcid":true,"given":"Yucai","family":"Tang","sequence":"first","affiliation":[{"name":"Hunan University of Arts and Science , , ,","place":["Changde, China, 415000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiale","family":"Liu","sequence":"additional","affiliation":[{"name":"Hunan University of Arts and Science , , ,","place":["Changde, China, 415000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaming","family":"Huang","sequence":"additional","affiliation":[{"name":"Hunan University of Arts and Science , , ,","place":["Changde, China, 415000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Duan","sequence":"additional","affiliation":[{"name":"Hunan University of Arts and Science , , ,","place":["Changde, China, 415000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiming","family":"Xia","sequence":"additional","affiliation":[{"name":"Hunan University of Arts and Science , , ,","place":["Changde, China, 415000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Na","family":"Long","sequence":"additional","affiliation":[{"name":"Hunan University of Arts and Science , , ,","place":["Changde, China, 415000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kairui","family":"Zhang","sequence":"additional","affiliation":[{"name":"Hunan University of Arts and Science , , ,","place":["Changde, China, 415000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8377-118X","authenticated-orcid":true,"given":"Zi","family":"Yang","sequence":"additional","affiliation":[{"name":"Changsha Medical University , , ,","place":["Changsha, China, 410219"]},{"name":"Nanjing Forestry University , , ,","place":["Nanjing, China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9481-6697","authenticated-orcid":true,"given":"Wei-Min","family":"He","sequence":"additional","affiliation":[{"name":"University of South China , , ,","place":["Hengyang, China, 421001"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,30]]},"reference":[{"key":"2026081410100029300_cit1a","doi-asserted-by":"publisher","first-page":"392","DOI":"10.2174\/1389557517666171101111134","article-title":"Quinoxalinone as a Privileged Platform\nin Drug Development","volume":"18","author":"Shi","year":"2018","journal-title":"Mini-Rev. 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