{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T15:28:30Z","timestamp":1786721310008,"version":"build-2736575974"},"reference-count":36,"publisher":"American Chemical Society (ACS)","issue":"32","license":[{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100006606","name":"Natural Science Foundation of Tianjin Municipality","doi-asserted-by":"publisher","award":["25JCZDJC00880"],"award-info":[{"award-number":["25JCZDJC00880"]}],"id":[{"id":"10.13039\/501100006606","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["63263130"],"award-info":[{"award-number":["63263130"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22271163"],"award-info":[{"award-number":["22271163"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Tianjin Major Science and Technology Project for National Key Laboratories","award":["25ZXZSSS00370"],"award-info":[{"award-number":["25ZXZSSS00370"]}]},{"name":"Haihe Laboratory of Sustainable Chemical Transformations"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>We report a two-step procedure for the synthesis of 1,2-cisC-vinyl furanosides from unprotected carbohydrates via an arylamine-mediated Petasis reaction and Br\u00f8nsted acid-catalyzed deaminative cyclization. The method shows broad scope and high stereoselectivity. Its utility is demonstrated in a concise synthesis of Jaspine B, enabling the rapid assembly of the all-cis THF core. The late-stage amino installation is achieved via a radical-mediated C\u2013H amidation reaction. The procedure provides practical access to bioactive THF-containing molecules.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01109","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:22:47Z","timestamp":1785849767000},"page":"11209-11213","source":"Crossref","is-referenced-by-count":0,"title":["Arylamine-Mediated\nConstruction of 1,2-\n                    <i>cis<\/i>\n                    <i>C<\/i>\n                    -Vinyl\nFuranosides and Application in the\nSynthesis of Jaspine B"],"prefix":"10.1021","volume":"91","author":[{"given":"Jiaxin","family":"Tong","sequence":"first","affiliation":[{"name":"Kashi University , , ,","place":["Kashi, China, 844000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongyang","family":"Sun","sequence":"additional","affiliation":[{"name":"Nankai University , , ,","place":["Tianjin, China, 300071"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9064-3418","authenticated-orcid":true,"given":"Gang","family":"He","sequence":"additional","affiliation":[{"name":"Kashi University , , ,","place":["Kashi, China, 844000"]},{"name":"Nankai University , , ,","place":["Tianjin, China, 300071"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,30]]},"reference":[{"key":"2026081410105307500_cit1a","doi-asserted-by":"publisher","first-page":"1505","DOI":"10.1021\/np010659y","article-title":"Pachastrissamine, a\nCytotoxic Anhydrophytosphingosine from a Marine Sponge, Pachastrissa sp","volume":"65","author":"Kuroda","year":"2002","journal-title":"J. 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Soc."},{"key":"2026081410105307500_cit12","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416036","article-title":"Structure Revision of Halisphingosine A via Total Synthesis\nand Bioactivity Studies","volume":"63","author":"Sauer","year":"2024","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026081410105307500_cit13","doi-asserted-by":"publisher","first-page":"1284","DOI":"10.1248\/cpb.55.1284","article-title":"Enantioselective\nSynthesis of Pachastrissamine\n(Jaspin B) Using Dirhodium(II)-Catalyzed C\u2013H Amination and\nAsymmetric Dihydroxylation as Key Steps","volume":"55","author":"Yakura","year":"2007","journal-title":"Chem.\nPharm. Bull."},{"key":"2026081410105307500_cit14","doi-asserted-by":"publisher","first-page":"515","DOI":"10.1039\/C7CC08897C","article-title":"Radical-mediated Intramolecular\n\u03b2-C(sp3)-H Amidation of Alkylimidates: Facile Synthesis\nof 1,2-amino Alcohols","volume":"54","author":"Mou","year":"2018","journal-title":"Chem. Commun."}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.6c01109","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/joceah\/article-pdf\/91\/32\/11209\/66341203\/acs.joc.6c01109.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/joceah\/article-pdf\/91\/32\/11209\/66341203\/acs.joc.6c01109.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T14:33:11Z","timestamp":1786717991000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/joceah\/article\/91\/32\/11209\/5237377\/Arylamine-Mediated-Construction-of-1-2-cisC-Vinyl"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,30]]},"references-count":36,"journal-issue":{"issue":"32","published-online":{"date-parts":[[2026,7,30]]},"published-print":{"date-parts":[[2026,8,14]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.joc.6c01109","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,30]]}}}