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Furthermore, the integration of radical cascades with Truce\u2013Smiles rearrangement for simultaneous skeleton construction and remote functional-group migration is rare. To address these challenges, we developed a visible-light photoredox-catalyzed desulfurization strategy that combines radical cyclization relay, Truce\u2013Smiles rearrangement, and desulfurization-driven rearomatization to access oxindoles efficiently. The reaction proceeds through a radical 1,4-cyano migration-triggered cyclization\/desulfurization cascade under mild conditions using readily available, bench-stable substrates. Notably, the protocol is not restricted to alkyl bromodifluoroacetates and is compatible with a broad range of bromoesters.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01118","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:20:54Z","timestamp":1785849654000},"page":"10954-10966","source":"Crossref","is-referenced-by-count":1,"title":["Radical-Mediated\nTandem Functional Group Transfer,\nDesulfonylation, and Cyclization Reactions: Synthesis of Oxindoles"],"prefix":"10.1021","volume":"91","author":[{"given":"Syed Anis Ali","family":"Shah","sequence":"first","affiliation":[{"name":"Soochow University , , ,","place":["Suzhou, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo-Xi","family":"Liu","sequence":"additional","affiliation":[{"name":"Soochow University , , ,","place":["Suzhou, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing-Han","family":"Peng","sequence":"additional","affiliation":[{"name":"Soochow University , , ,","place":["Suzhou, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi-Xin","family":"Xing","sequence":"additional","affiliation":[{"name":"Soochow University , , ,","place":["Suzhou, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6088-7278","authenticated-orcid":true,"given":"Weidong","family":"Rao","sequence":"additional","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shu-Su","family":"Shen","sequence":"additional","affiliation":[{"name":"Suzhou University of Science and Technology, Soochow University , , ,","place":["Suzhou, P. 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