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Their structures and properties were investigated by spectroscopic, crystallographic, and computational methods. Changing the meso-substituent from 3,5-di-tert-butylphenyl (1) to 2,4,6-trimethylphenyl (2) significantly affects their photophysical properties. Notably, 2 exhibits large Stokes shifts (3471\u20133739 cm\u22121) and moderate fluorescence quantum yields (31\u201344%) in different organic solvents.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01131","type":"journal-article","created":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T20:02:38Z","timestamp":1792008158000},"page":"14680-14686","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and Properties of Phenanthrene-Containing Expanded Porphyrin-Based BODIPY Derivatives"],"prefix":"10.1021","volume":"91","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-6061-3076","authenticated-orcid":true,"given":"Hao","family":"Chen","sequence":"first","affiliation":[{"name":"Suzhou University of Technology , , ,","place":["Changshu, China, 215500"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-6928-0831","authenticated-orcid":true,"given":"Cun","family":"Yang","sequence":"additional","affiliation":[{"name":"Shanghai University , , ,","place":["Shanghai, P. 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