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The reaction proceeds efficiently, with palladium playing a dual role by mediating C\u2013C bond formation and promoting subsequent intramolecular cyclization through nucleophilic addition of the boronic ester to the carbonyl. Furthermore, a Lewis acid-promoted regioselective approach to 2-substituted indenols and methoxyindenes from terminal 1,2-diborylalkenes via Suzuki\u2013Miyaura coupling is disclosed under mild conditions.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01214","type":"journal-article","created":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T21:01:44Z","timestamp":1792098104000},"page":"14017-14028","source":"Crossref","is-referenced-by-count":0,"title":["From 1,2-Diborylalkenes to Functionalized Indenols: Tandem Suzuki Coupling\u2013Intramolecular Cyclization"],"prefix":"10.1021","volume":"91","author":[{"given":"Malavath","family":"Sravani","sequence":"first","affiliation":[{"name":"CSIR-Indian Institute of Chemical Technology , , ,","place":["Hyderabad, India, 500 007"]},{"name":"Academy of Scientific and Innovative Research (AcSIR) , ,","place":["Ghaziabad, India, 201 002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kummari Kunta","family":"Harshitha","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Chemical Technology , , ,","place":["Hyderabad, India, 500 007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0419-6525","authenticated-orcid":true,"given":"Jayaram","family":"Vankudoth","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Chemical Technology , , ,","place":["Hyderabad, India, 500 007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maruti","family":"Mali","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Chemical Technology , , ,","place":["Hyderabad, India, 500 007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jagadeesh Babu","family":"Nanubolu","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Chemical Technology , , ,","place":["Hyderabad, India, 500007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sharmistha","family":"Karmakar","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Chemical Technology , , ,","place":["Hyderabad, India, 500 007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-2144-7044","authenticated-orcid":true,"given":"Malavath","family":"Ratanlal","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Chemical Technology , , ,","place":["Hyderabad, India, 500 007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Subhash","family":"Ghosh","sequence":"additional","affiliation":[{"name":"CSIR-Indian Institute of Chemical Technology , , ,","place":["Hyderabad, India, 500 007"]},{"name":"Academy of Scientific and Innovative Research (AcSIR) , ,","place":["Ghaziabad, India, 201 002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1811-0585","authenticated-orcid":true,"given":"Fabienne","family":"Berr\u00e9e","sequence":"additional","affiliation":[{"name":"Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) , ,","place":["Rennes, France, F-35000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,15]]},"reference":[{"key":"2026103005072461200_cit1a","doi-asserted-by":"publisher","first-page":"5056","DOI":"10.1002\/chem.201503933","article-title":"Recent Advances in the Synthesis of Indanes and Indenes","volume":"22","author":"Gabriele","year":"2016","journal-title":"Chem. \u2013 Eur. 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