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Utilizing germanes and structurally diverse enynes or dienes as substrates, this protocol employs a synergistic dual catalytic system combining photoredox catalysis with hydrogen atom transfer (HAT). This strategy enables a radical-mediated hydrogermylation\/cyclization cascade under mild conditions, featuring high reactivity and a broad substrate scope. Notably, this method not only allows for the synthesis of five-membered carbagermanes but also provides efficient access to nitrogen-containing (e.g., pyrrolidine) and oxygen-containing (e.g., tetrahydrofurans) organogermanium heterocycles in good yields.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01239","type":"journal-article","created":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T16:01:56Z","timestamp":1786464116000},"page":"11409-11417","source":"Crossref","is-referenced-by-count":0,"title":["Germyl Radical Cyclization\nof Enynes and Dienes under\nVisible-Light Irradiation"],"prefix":"10.1021","volume":"91","author":[{"given":"Ling","family":"Jin","sequence":"first","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuoshuo","family":"Zhang","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanjun","family":"Wu","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Zhang","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junhao","family":"Chen","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingliang","family":"Nie","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaolei","family":"Huang","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,11]]},"reference":[{"key":"2026082211143846700_cit1a","doi-asserted-by":"publisher","first-page":"1237","DOI":"10.1021\/cr00006a006","article-title":"Radical reactions\nin natural product synthesis","volume":"91","author":"Jasperse","year":"1991","journal-title":"Chem. 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