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This method requires no external photocatalysts or oxidants and offers a straightforward and efficient route to these compounds bearing quaternary carbon centers and arylthio groups. Mechanistic studies indicate that the sulfur radicals are mainly generated through an energy transfer (EnT) pathway, underscoring the distinctive feature of this approach.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01253","type":"journal-article","created":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T08:18:11Z","timestamp":1785140291000},"page":"10709-10714","source":"Crossref","is-referenced-by-count":0,"title":["Photoinduced Synthesis\nof \u03b1-Aryl-\u03b2-arylthiopropanamide\nfrom\n                    <i>N<\/i>\n                    -(Arylsulfonyl)methacrylamide\n                    <i>via<\/i>\n                    Smiles Rearrangement"],"prefix":"10.1021","volume":"91","author":[{"given":"Litao","family":"Liu","sequence":"first","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Wang","sequence":"additional","affiliation":[{"name":"Zhejiang Changhong Biological Materials Co., Ltd , ,","place":["Shaoxing, China, 312000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingcai","family":"Teng","sequence":"additional","affiliation":[{"name":"Zhejiang Changhong Biological Materials Co., Ltd , ,","place":["Shaoxing, China, 312000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiao","family":"Xie","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meichao","family":"Li","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3699-1198","authenticated-orcid":true,"given":"Zhenlu","family":"Shen","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]},{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,27]]},"reference":[{"key":"2026080708081476400_cit1a","doi-asserted-by":"publisher","first-page":"2832","DOI":"10.1021\/jm401375q","article-title":"Data-Mining\nfor Sulfur and Fluorine: An Evaluation of Pharmaceuticals To Reveal\nOpportunities for Drug Design and Discovery","volume":"57","author":"Ilardi","year":"2014","journal-title":"J. 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