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Distinct from conventional deoxygenative approaches that retain the parent scaffold, this protocol proceeds via a deconstructive mechanism involving the \u03b2-fragmentation of alkoxy radicals. This strategy enables the synthesis of diverse \u03b1-alkyl ketones from a wide range of substrates, including primary, secondary, and tertiary alcohols, as well as various styrenes. Notably, the method facilitates the late-stage modification of complex natural scaffolds, such as sclareolide and \u03b2-pinene. 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