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This external photocatalyst-free approach proceeds via direct excitation of the in situ-formed Ni-BINAM complex. The reactions with aliphatic amines do not require the ligand BINAM, and the amine plays a dual role as a coupling partner and as a ligand to the Ni catalyst. Comprehensive HRMS and UV\u2013vis studies provided insights into the structural features of the Ni-complex.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01352","type":"journal-article","created":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T05:02:35Z","timestamp":1789707755000},"page":"13333-13337","source":"Crossref","is-referenced-by-count":0,"title":["Visible-Light-Mediated\nC\u2013N Cross-Coupling through\nDirect Sensitization of the Ni\u2013BINAM Complex"],"prefix":"10.1021","volume":"91","author":[{"given":"Balasubramanian","family":"Devi Bala","sequence":"first","affiliation":[{"name":"Indian Institute of Technology Madras , , ,","place":["Chennai, India, 600036"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Janarthanan","family":"Ramya","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Madras , , ,","place":["Chennai, India, 600036"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shivasankar","family":"Krishnamoorthy","sequence":"additional","affiliation":[{"name":"IIT Madras Research Park, Phase-II , , ,","place":["Chennai, India, 600113"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sureshpandian","family":"Pandi","sequence":"additional","affiliation":[{"name":"IIT Madras Research Park, Phase-II , , ,","place":["Chennai, India, 600113"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6185-5825","authenticated-orcid":true,"given":"Ramesh L.","family":"Gardas","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Madras , , ,","place":["Chennai, India, 600036"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2294-0485","authenticated-orcid":true,"given":"Govindasamy","family":"Sekar","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Madras , , ,","place":["Chennai, India, 600036"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,18]]},"reference":[{"key":"2026100208062665600_cit1a","doi-asserted-by":"publisher","first-page":"10257","DOI":"10.1021\/jm501100b","article-title":"Analysis\nof the Structural Diversity, Substitution Patterns, and Frequency\nof Nitrogen Heterocycles among U.S. FDA Approved Pharmaceuticals","volume":"57","author":"Vitaku","year":"2014","journal-title":"J. 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