{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T15:27:03Z","timestamp":1787412423337,"version":"build-2736575974"},"reference-count":36,"publisher":"American Chemical Society (ACS)","issue":"33","license":[{"start":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T00:00:00Z","timestamp":1786320000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T00:00:00Z","timestamp":1786320000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T00:00:00Z","timestamp":1786320000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100003382","name":"Core Research for Evolutional Science and Technology","doi-asserted-by":"publisher","award":["JPMJCR21L1"],"award-info":[{"award-number":["JPMJCR21L1"]}],"id":[{"id":"10.13039\/501100003382","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>We report the copper-catalyzed acylsilylation of allenes using acyl fluorides. Under CuOAc\/PCy3 catalysis, a broad range of aromatic acyl fluorides, allenes, and silylboranes undergo efficient three-component coupling to furnish \u03b2-silyl-\u03b2,\u03b3-unsaturated ketones bearing sterically congested quaternary carbon centers. Control experiments indicate that acyl fluorides play a crucial role in promoting productive coupling, whereas less reactive acyl derivatives favor competing silaboration pathways.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01368","type":"journal-article","created":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T22:02:12Z","timestamp":1786399332000},"page":"11480-11485","source":"Crossref","is-referenced-by-count":0,"title":["Regioselective Copper-Catalyzed\nAcylsilylation of\nAllenes Using Acyl Fluorides"],"prefix":"10.1021","volume":"91","author":[{"given":"Seishu","family":"Ochiai","sequence":"first","affiliation":[{"name":"Nagoya Institute of Technology , , Gokiso , Showa-Ku, ,","place":["Nagoya, Japan, 466-8555"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengyu","family":"Zhao","sequence":"additional","affiliation":[{"name":"Nagoya Institute of Technology , , Gokiso , Showa-Ku, ,","place":["Nagoya, Japan, 466-8555"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiroto","family":"Iwasaki","sequence":"additional","affiliation":[{"name":"Nagoya Institute of Technology , , Gokiso , Showa-Ku, ,","place":["Nagoya, Japan, 466-8555"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3742-4064","authenticated-orcid":true,"given":"Norio","family":"Shibata","sequence":"additional","affiliation":[{"name":"Nagoya Institute of Technology , , Gokiso , Showa-Ku, ,","place":["Nagoya, Japan, 466-8555"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,10]]},"reference":[{"key":"2026082211133374800_cit1a","doi-asserted-by":"publisher","first-page":"1095","DOI":"10.1039\/B608235C","article-title":"Multi-component syntheses of heterocycles by transition-metal\ncatalysis","volume":"36","author":"D\u2019Souza","year":"2007","journal-title":"Chem. 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Au"}],"container-title":["The Journal\nof Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.6c01368","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/joceah\/article-pdf\/91\/33\/11480\/66481584\/acs.joc.6c01368.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/joceah\/article-pdf\/91\/33\/11480\/66481584\/acs.joc.6c01368.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T15:15:17Z","timestamp":1787411717000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/joceah\/article\/91\/33\/11480\/5251733\/Regioselective-Copper-Catalyzed-Acylsilylation-of"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,10]]},"references-count":36,"journal-issue":{"issue":"33","published-online":{"date-parts":[[2026,8,10]]},"published-print":{"date-parts":[[2026,8,21]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.joc.6c01368","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,10]]}}}