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N-Allylation represents a powerful strategy for enriching the structural diversity of sulfoximines, while fluorine incorporation can effectively enhance the lipophilicity and metabolic stability of functional molecules. Herein, we disclose an efficient Pd-catalyzed N-fluoroallylation of sulfoximines using gem-difluorinated cyclopropylamines. This transformation is enabled by sequential C\u2013C bond activation and C\u2013F bond cleavage, affording a series of N-fluoroallylic sulfoximines bearing monofluoroalkene motifs with excellent Z-stereoselectivity. This protocol features mild reaction conditions and broad substrate compatibility, providing a novel and practical platform for the construction of fluorinated sulfoximine derivatives.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01379","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T01:03:32Z","timestamp":1788397412000},"page":"12269-12274","source":"Crossref","is-referenced-by-count":0,"title":["Palladium-Catalyzed\n                    <i>N<\/i>\n                    -Fluoroallylation\nof Sulfoximines and Benzophenone Imine with\n                    <i>gem<\/i>\n                    -Difluorinated\nCyclopropanes"],"prefix":"10.1021","volume":"91","author":[{"given":"Ebrahim-Alkhalil M. 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